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What's New in 2002 R. Eisenberg pp 1 - 1; DOI: 10.1021/ic011105l |
New Crown-Shaped Polyoxovanadium(V) Cluster Cation with a  6-Sulfato Anion and Zwitterionic -( -Alanine): Crystal Structure of [V6O12(OH)3(O2CCH2CH2NH3)3(SO4)][Na][SO4]·13H2OChew Hee Ng, Chai Wei Lim, Siang Guan Teoh, Hoong-Kun Fun, Anwar Usman, and Seik Weng Ng pp 2 - 3; DOI: 10.1021/ic015574z |
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Kinetics, Mechanism, and Spectroscopy of the Reversible Binding of Nitric Oxide to Aquated Iron(II). An Undergraduate Text Book Reaction Revisited Alicja Wanat, Thorsten Schneppensieper, Gra  yna Stochel, Rudi van Eldik, Eckhard Bill, and Karl Wieghardtpp 4 - 10; DOI: 10.1021/ic010628q |
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Photochemistry of Trimethyltin Iodide in Polar Media: Orbital Parentage and Observed Reactivity Jinquan Dong, P. Sujatha Devi, D. Sunil, Edgar Mendoza, and Harry D. Gafney pp 11 - 18; DOI: 10.1021/ic010051c |
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Syntheses and Solid State Structures of Tris(pyrazolyl)methane Complexes of Sodium, Potassium, Calcium, and Strontium: Comparison of Structures with Analogous Complexes of Lead(II) Daniel L. Reger, Christine A. Little, Mark D. Smith, Arnold L. Rheingold, Louise M. Liable-Sands, Glen P. A. Yap, and Ilia A. Guzei pp 19 - 27; DOI: 10.1021/ic010690n |
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Trivalent Lanthanide Compounds with Fluorinated Thiolate Ligands: Ln-F Dative Interactions Vary with Ln and Solvent Jonathan H. Melman, Christa Rohde, Thomas J. Emge, and John G. Brennan pp 28 - 33; DOI: 10.1021/ic0104813 |
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Syntheses and Crystal Structures of Two Topologically Related Modifications of Cs2[(UO2)2(MoO4)3] S. V. Krivovichev, C. L. Cahill, and P. C. Burns pp 34 - 39; DOI: 10.1021/ic010345y |
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Synthesis, Characterization, Photophysical Properties, and Biological Labeling Studies of a Series of Luminescent Rhenium(I) Polypyridine Maleimide Complexes Kenneth Kam-Wing Lo, Wai-Ki Hui, Dominic Chun-Ming Ng, and Kung-Kai Cheung pp 40 - 46; DOI: 10.1021/ic010602z |
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Molybdenum Complexes with Linked Cycloheptatrienyl-Phenolate Ligands Matthias Tamm, Thomas Bannenberg, Bernd Dressel, Roland Fröhlich, and Christiane Holst pp 47 - 59; DOI: 10.1021/ic010902g |
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N-(Ferrocenylmethyl)-N-methylaminocyclotriphosphazenes Charles N. Myer and Christopher W. Allen pp 60 - 66; DOI: 10.1021/ic011049o |
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Formation of Metallaboranes from the Group IV Transition Metals and Pentaborane(9): Crystal and Molecular Structure of [(Cp2Zr)2B5H8][B11H14] Rhodri Ll. Thomas, Nigam P. Rath, and Lawrence Barton pp 67 - 75; DOI: 10.1021/ic010665h |
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Synthesis and Structural Characterization of the {[Rh5(CO)14]-(H2N(CH2)4NH2)-[Rh5(CO)14])}2- and [Rh5(CO)13(H2N(CH2)2NH2)]- Anions (as [PPh4]+ Salts): An Unprecedented Example of Carbonyl Substitution by Alkylamines in a Homoleptic Metal Carbonyl Cluster Anion Alessandro Fumagalli, Maria Carlotta Malatesta, Anna Tentori, Diego Monti, Piero Macchi, and Angelo Sironi pp 76 - 85; DOI: 10.1021/ic0107936 |
Syntheses, Crystal Structures, and Density Functional Theory Calculations of the closo-[1-M(CO)3( 4-E9)]4- (E = Sn, Pb; M = Mo, W) Cluster Anions and Solution NMR Spectroscopic Characterization of [1-M(CO)3(4-Sn9)]4- (M = Cr, Mo, W)Janette Campbell, Hélène P. A. Mercier, Holger Franke, David P. Santry, David A. Dixon, and Gary J. Schrobilgen pp 86 - 107; DOI: 10.1021/ic010695k |
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Bromite Ion Catalysis of the Disproportionation of Chlorine Dioxide with Nucleophile Assistance of Electron-Transfer Reactions between ClO2 and BrO2 in Basic Solution Lu Wang, Jeffrey S. Nicoson, Kara E. Huff Hartz, Joseph S. Francisco, and Dale W. Margerum pp 108 - 113; DOI: 10.1021/ic010849w |
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Kinetics and Mechanism of Ligand Interchange in Pentacyano-L-osmate(II) Complexes (L = H2O, NH3, N-Heterocyclic Ligands) Leonardo D. Slep, Pablo Alborés, Luis M. Baraldo, and José A. Olabe pp 114 - 120; DOI: 10.1021/ic010923a |
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Chalcogen Rich Lanthanide Clusters from Halide Starting Materials (II): Selenido Compounds Anna Kornienko, J. H. Melman, G. Hall, T. J. Emge, and John G. Brennan pp 121 - 126; DOI: 10.1021/ic010740o |
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Ferrocene Bis(phosphonite)s: Synthesis and Characterization of a Novel Class of Sterically Congested Ligands Sai P. Shum, Stephen D. Pastor, and Grety Rihs pp 127 - 131; DOI: 10.1021/ic010750p |
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Photophysical and Photochemical Properties of W(0) and Re(I) Carbonyl Complexes Incorporating Ferrocenyl-Substituted Pyridine Ligands Shih-Sheng Sun, Dat T. Tran, Onduru S. Odongo, and Alistair J. Lees pp 132 - 135; DOI: 10.1021/ic010713y |
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Electrochemistry of Cycloaddition Products of Olefins with Nickel Dithiolenes: A Reinvestigation of the Reduction of the 1:1 Adduct between Ni(S2C2(CF3)2)2 and Norbornadiene William E. Geiger pp 136 - 139; DOI: 10.1021/ic010968b |
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Hydrothermal Synthesis and Crystal Structure of a Novel Two-Dimensional Vanadium Oxide Complex with a 6,14-Net Sinusoidal Ruffling Anionic Layer: [Ni(phen)2V4O11] (phen = 1,10-Phenanthroline) Cai-Ming Liu, Yang-Long Hou, Jing Zhang, and Song Gao pp 140 - 143; DOI: 10.1021/ic010735k |
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Synthesis and Characterization of Cs5P[Mo4O14(OH)]2·2H2O: A New Molybdophosphate Cluster with Face-Sharing MoO6 Octahedra Eddy Dumas and Slavi C. Sevov pp 144 - 146; DOI: 10.1021/ic010900w |
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Coupling of Edge-Sharing Bioctahedral Dirhenium(II) Units through the Agency of [N(CN)2]-, [C(CN)3]-, and [Ni(CN)4]2- Linkages Shan-Ming Kuang, Phillip E. Fanwick, and Richard A. Walton pp 147 - 151; DOI: 10.1021/ic0110070 |
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Can Semiempirical Quantum Mechanics Be Used To Predict the Spin State of Transition Metal Complexes? An Application of De Novo Prediction David M. Ball, Corneliu Buda, Aaron M. Gillespie, David P. White, and Thomas R. Cundari pp 152 - 156; DOI: 10.1021/ic0108437 |
Issue 2
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fac-[FeII(CN)3(CO)3]- and cis-[FeII(CN)4(CO)2]2-: New Members of the Class of [FeII(CN)x(CO)y] Compounds Jianfeng Jiang and Stephen A. Koch pp 158 - 160; DOI: 10.1021/ic015604y |
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Modeling the Catalytic Site of Vanadium Bromoperoxidase: Synthesis and Structural Characterization of Intramolecularly H-bonded Vanadium(V) Oxoperoxo Complexes, [VO(O2)(NH2pyg2)]K and [VO(O2)(BrNH2pyg2)]K Clare Kimblin, Xianhui Bu, and Alison Butler pp 161 - 163; DOI: 10.1021/ic010892j |
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Formation of Trithiocyanate in the Oxidation of Aqueous Thiocyanate Jon J. Barnett and David M. Stanbury pp 164 - 166; DOI: 10.1021/ic015597d |
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Lanthanide Contraction over the 4f Series Follows a Quadratic Decay Elsje Alessandra Quadrelli pp 167 - 169; DOI: 10.1021/ic015580v |
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Experimental and Theoretical Characterization of Cationic, Neutral, and Anionic Binary Arsenic and Antimony Azide Species Konstantin Karaghiosoff, Thomas M. Klapötke, Burkhard Krumm, Heinrich Nöth, Thomas Schütt, and Max Suter pp 170 - 179; DOI: 10.1021/ic010463l |
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NaCeP2Se6, Cu0.4Ce1.2P2Se6, Ce4(P2Se6)3, and the Incommensurately Modulated AgCeP2Se6: New Selenophosphates Featuring the Ethane-Like [P2Se6]4- Anion Jennifer A. Aitken, Michel Evain, Lykourgos Iordanidis, and Mercouri G. Kanatzidis pp 180 - 191; DOI: 10.1021/ic010618p |
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Structure of the Solvated Thallium(I) Ion in Aqueous, Dimethyl Sulfoxide, N,N'-Dimethylpropyleneurea, and N,N-Dimethylthioformamide Solution Ingmar Persson, Farideh Jalilehvand, and Magnus Sandström pp 192 - 197; DOI: 10.1021/ic010587y |
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Solution Multi-NMR and Raman Spectroscopic Studies of Thermodynamically Unstable XeO4. The First 131Xe NMR Study of a Chemically Bound Xenon Species Michael Gerken and Gary J. Schrobilgen pp 198 - 204; DOI: 10.1021/ic010627y |
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Coupled Redox Potentials in Manganese and Iron Superoxide Dismutases from Reaction Kinetics and Density Functional/Electrostatics Calculations Wen-Ge Han, Timothy Lovell, and Louis Noodleman pp 205 - 218; DOI: 10.1021/ic010355z |
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Activation of Organonitriles toward -Electrophilic Attack. Synthesis and Characterization of Methyleneamide (Azavinylidene) Complexes of Rhenium M. Fátima C. Guedes da Silva, João J. R. Fraústo da Silva, and Armando J. L. Pombeiro pp 219 - 228; DOI: 10.1021/ic010841m |
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Dynamic Behavior of the Jahn-Teller Distorted Cu(H2O)62+ Ion in Cu2+ Doped Cs2[Zn(H2O)6](ZrF6)2 and the Crystal Structure of the Host Lattice Michael A. Hitchman, Yurii V. Yablokov, Vladimir E. Petrashen, Maria A. Augustyniak-Jab  okov, Horst Stratemeier, Mark J. Riley, Kazimierz  ukaszewicz, Pawe E. Tomaszewski, and Adam Pietraszkopp 229 - 238; DOI: 10.1021/ic010464d |
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New Monomeric Cobalt(II) and Zinc(II) Complexes of a Mixed N,S(alkylthiolate) Ligand: Model Complexes of (His)(His)(Cys) Metalloprotein Active Sites SeChin Chang, Vivek V. Karambelkar, Roger D. Sommer, Arnold L. Rheingold, and David P. Goldberg pp 239 - 248; DOI: 10.1021/ic010321r |
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XAFS Investigation of the Structure of Aqueous Thorium(IV) Species, Colloids, and Solid Thorium(IV) Oxide/Hydroxide J. Rothe, M. A. Denecke, V. Neck, R. Müller, and J. I. Kim pp 249 - 258; DOI: 10.1021/ic010579h |
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The OsO3F+ and -F(OsO3F)2+ Cations: Their Syntheses and Study by Raman and 19F NMR Spectroscopy and Electron Structure Calculations and X-ray Crystal Structures of [OsO3F][PnF6] (Pn = As, Sb), [OsO3F][HF]2[AsF6], [OsO3F][HF][SbF6], and [OsO3F][Sb3F16] Michael Gerken, David A. Dixon, and Gary J. Schrobilgen pp 259 - 277; DOI: 10.1021/ic0107680 |
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Halide-Templated Assembly of Polynuclear Lanthanide-Hydroxo Complexes Ruiyao Wang, Hugh D. Selby, Hui Liu, Michael D. Carducci, Tianzhu Jin, Zhiping Zheng, Jeffery W. Anthis, and Richard J. Staples pp 278 - 286; DOI: 10.1021/ic010859x |
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Intercalation of Alcohols in Ag Sulfonates: Topotactic Behavior Despite Flexible Layers Adrien P. Côté, Michael J. Ferguson, Kashif A. Khan, Gary D. Enright, Angela D. Kulynych, Sean A. Dalrymple, and George K. H. Shimizu pp 287 - 292; DOI: 10.1021/ic010800q |
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Criteria for Liquid Crystal Formation in 5-Alkoxy-, 5-Alkylamino-, and 5-Alkanoyl-tropolone Complexes of Transition Metals (CuII, ZnII, NiII, CoII, UO2VI, VOIV). The First Uranium Metallomesogen. Crystal Structure of Bis(5-hexadecyloxytropolonato)copper(II) James M. Elliott, John R. Chipperfield, Stephen Clark, Simon J. Teat, and Ekkehard Sinn pp 293 - 299; DOI: 10.1021/ic0101026 |
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Activation Barriers to meso-Aryl Group Rotation in Titanyl Tetraaryltetrapyrroles. An Investigation of the Out-of-Plane Flexibility of Hydroporphyrins Alan M. Stolzenberg and G. Scott Haymond pp 300 - 308; DOI: 10.1021/ic010936o |
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Methanolysis of Nitrocefin Catalyzed by One and Two Zn2+ Ions. A Simplified Model for Class B -Lactamases Pedro J. Montoya-Pelaez and R. S. Brown pp 309 - 316; DOI: 10.1021/ic011005f |
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The First Oxidation of a Cr24+ Paddlewheel Complex to an Isostructural Stable Product F. Albert Cotton, Lee M. Daniels, Penglin Huang, and Carlos A. Murillo pp 317 - 320; DOI: 10.1021/ic010925v |
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3,3'-Bis(triphenylsilyl)biphenoxide as a Sterically Hindered Ligand on Fe(II), Fe(III), and Cr(II) Ajay Kayal and Sonny C. Lee pp 321 - 330; DOI: 10.1021/ic010909y |
Strongly Coupled Porphyrin Arrays Featuring Both  -Cofacial and Linear--Conjugative InteractionsJames T. Fletcher and Michael J. Therien pp 331 - 341; DOI: 10.1021/ic010871p |
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Kinetics and Mechanisms of Aqueous Chlorine Reactions with Chlorite Ion in the Presence of Chloride Ion and Acetic Acid/Acetate Buffer Jeffrey S. Nicoson and Dale W. Margerum pp 342 - 347; DOI: 10.1021/ic010762a |
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Synthetic and Structural Studies of Lithium Complexes of Selenophosphorus Ligands Robert P. Davies and M. Giovanna Martinelli pp 348 - 352; DOI: 10.1021/ic010835q |
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Photochemically-Induced Radical Reactions of Zinc Phthalocyanine Steven P. Keizer, Wenjun Han, and Martin J. Stillman pp 353 - 358; DOI: 10.1021/ic010688w |
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Photophysics of Re(I) and Ru(II) Diimine Complexes Covalently Linked to Pyrene: Contributions from Intra-Ligand Charge Transfer States André Del Guerzo, Stéphanie Leroy, Frédéric Fages, and Russell H. Schmehl pp 359 - 366; DOI: 10.1021/ic010522v |
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Novel Ruthenium Sensitizers Containing Functionalized Hybrid Tetradentate Ligands: Synthesis, Characterization, and INDO/S Analysis T. Renouard, R.-A. Fallahpour, Md. K. Nazeeruddin, R. Humphry-Baker, S. I. Gorelsky, A. B. P. Lever, and M. Grätzel pp 367 - 378; DOI: 10.1021/ic010512u |
A Ruthenium(II) Tris(bipyridyl) Amino Acid: Synthesis and Direct Incorporation into an  -Helical Peptide by Solid-Phase SynthesisKenneth J. Kise, Jr. and Bruce E. Bowler pp 379 - 386; DOI: 10.1021/ic010617x |
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Sonochemical Synthesis and Mechanistic Study of Copper Selenides Cu2-xSe, -CuSe, and Cu3Se2 Yi Xie, Xiuwen Zheng, Xuchuan Jiang, Jun Lu, and Liying Zhu pp 387 - 392; DOI: 10.1021/ic010108v |
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Synthesis and Characterization of Chlorinated Alkenylcobaloximes To Probe the Mechanism of Vitamin B12-Catalyzed Dechlorination of Priority Pollutants Kevin M. McCauley, Scott R. Wilson, and Wilfred A. van der Donk pp 393 - 404; DOI: 10.1021/ic011023x |
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Unsymmetrical Dirhenium Complexes That Contain [Re2]6+ and [Re2]5+ Cores Complexed by Tridentate Ligands with P2O and P2N Donor Sets Shan-Ming Kuang, Phillip E. Fanwick, and Richard A. Walton pp 405 - 412; DOI: 10.1021/ic010983g |
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Novel Five-Connected Lanthanide(III)-Bis(sulfinyl) Coordination Polymers Forming a Unique Two-Dimensional ( Xian-He Bu, Wei Weng, Jian-Rong Li, Wei Chen, and Ruo-Hua Zhang pp 413 - 415; DOI: 10.1021/ic010605b |
High-Vacuum Pyrolysis of Zr(2,3,7,8,12,13,17,18-Octaethylporphyrin)(PhC CPh) as a Route to Novel Zr Species: X-ray Structure of a Hetero-Triply Bridged Species, [(OEP)Zr(-Cl)]2(-O)James P. Collman, Roman Boulatov, Geoffrey B. Jameson, and Vipin Narang pp 416 - 420; DOI: 10.1021/ic0108078 |
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A 3-D Polymer, Mn(NITpPy)2(tp)(H2O)2: Crystal Structure and Magnetic Properties Licun Li, Daizheng Liao, Zonghui Jiang, and Shiping Yan pp 421 - 424; DOI: 10.1021/ic0107476 |
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Three-Center, Two-Electron M···H-B Bonds in Complexes of Ni, Co, and Fe and the Dihydrobis(3-tert-butylpyrazolyl)borate Ligand Tomás R. Belderraín, Margarita Paneque, Ernesto Carmona, Enrique Gutiérrez-Puebla, M. Angeles Monge, and Caridad Ruiz-Valero pp 425 - 428; DOI: 10.1021/ic010598r |
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Hydrothermal Synthesis and Structural Characterization of a Two-Dimensional Polymeric Copper(II) Complex Containing an Unusual Bridged H2edta2- Ligand Chih-Chieh Wang, Cheng-Han Yang, Chia-Hwa Lee, and Gene-Hsiang Lee pp 429 - 432; DOI: 10.1021/ic010873+ |
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Reactivity Studies of Anticancer Active Dirhodium Complexes with 2-Aminothiophenol Karn Sorasaenee, José Ramón Galán-Mascarós, and Kim R. Dunbar pp 433 - 436; DOI: 10.1021/ic010799v |
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Chiral Noninterpenetrated (10,3)-a Net in the Crystal Structure of Ag(I) and Bisthioether Xian-He Bu, Wei Chen, Miao Du, Kumar Biradha, Wen-Zhen Wang, and Ruo-Hua Zhang pp 437 - 439; DOI: 10.1021/ic0107734 |
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Oxidation of Rhodium(I) by Hydroxamic Acids. Synthesis, Structure, and Electrochemical Properties of Bis(hydroxamate) Complexes of Rhodium(III) Anindya Das, Falguni Basuli, Shie-Ming Peng, and Samaresh Bhattacharya pp 440 - 443; DOI: 10.1021/ic0106930 |
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Synthesis and Coordination Properties of 1-(Diphenylphosphine oxide)-1-(2'-pyridyl N-oxide)-3-(diphenylphosphine oxide)propane Robert T. Paine, Evelyn M. Bond, S. Parveen, Nathan Donhart, Eileen N. Duesler, Karen Ann Smith, and Heinrich Nöth pp 444 - 448; DOI: 10.1021/ic0109041 |
Issue 3
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Synthesis and Structure of [PPh4]3[Cr(Te4)3]·DMF: The First Tris(tetratelluride) Complex Perumal Sekar and James A. Ibers pp 450 - 451; DOI: 10.1021/ic015585s |
Novel Acetate Polyoxomolybdate "Host" Accommodating a Zigzag-Chainlike "Guest" of Five Edge-Shared Sodium Cations: Na21{[Na5(H2O)14] [Mo46O134(OH)10(-CH3COO)4]}·CH3COONa· 95H2OWenbin Yang, Canzhong Lu, Xiang Lin, and Honghui Zhuang pp 452 - 454; DOI: 10.1021/ic010267e |
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Growth of Sb2E3 (E = S, Se) Polygonal Tubular Crystals via a Novel Solvent-Relief-Self-Seeding Process Xiuwen Zheng, Yi Xie, Liying Zhu, Xuchuan Jiang, Yunbo Jia, Wenhai Song, and Yuping Sun pp 455 - 461; DOI: 10.1021/ic0107072 |
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Polar Effects in Nitride Coupling Reactions Sean B. Seymore and Seth N. Brown pp 462 - 469; DOI: 10.1021/ic010844z |
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X-ray Structures of the First Platinum Complexes with Z Configuration Iminoether Ligands: trans-Dichlorobis(1-imino-1-methoxy-2,2'-dimethylpropane)platinum(II) and trans-Tetrachlorobis(1-imino-1-methoxy-2,2'-dimethylpropane)platinum(IV) Ana M. Gonzalez, Renzo Cini, Francesco P. Intini, Concetta Pacifico, and Giovanni Natile pp 470 - 478; DOI: 10.1021/ic010850v |
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Dicopper(II) Complexes of H-BPMP-Type Ligands: pH-Induced Changes of Redox, Spectroscopic (19F NMR Studies of Fluorinated Complexes), Structural Properties, and Catecholase Activities C. Belle, C. Beguin, I. Gautier-Luneau, S. Hamman, C. Philouze, J. L. Pierre, F. Thomas, S. Torelli, E. Saint-Aman, and M. Bonin pp 479 - 491; DOI: 10.1021/ic010534g |
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Chalcogen-Rich Lanthanide Clusters: Compounds with Te2-, (TeTe)2-, TePh, TeTePh, (TeTeTe(Ph)TeTe)5-, and [(TeTe)4TePh]9- Ligands; Single Source Precursors to Solid-State Lanthanide Tellurides Deborah Freedman, Thomas J. Emge, and John G. Brennan pp 492 - 500; DOI: 10.1021/ic010981w |
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A Coordination Polymer of Cobalt(II)-Glutarate: Two-Dimensional Interlocking Structure by Dicarboxylate Ligands with Two Different Conformations EunWon Lee, YooJin Kim, and Duk-Young Jung pp 501 - 506; DOI: 10.1021/ic010861o |
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Syntheses, Structures, and Properties of Trinuclear Complexes [M(bpca)2{M'(hfac)2}2], Constructed with the Complexed Bridging Ligand [M(bpca)2] [M, M' = Ni(II), Mn(II); Cu(II), Mn(II); Fe(II), Mn(II); Ni(II), Fe(II); and Fe(II), Fe(II); Hbpca = Bis(2-pyridylcarbonyl)amine, Hhfac = Hexafluoroacetylacetone] Asako Kamiyama, Tomoko Noguchi, Takashi Kajiwara, and Tasuku Ito pp 507 - 512; DOI: 10.1021/ic010731f |
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Trithiotungsten(VI) Complexes Having Phosphine-Thiolate Hybrid Ligands: Synthesis and Cluster Forming Reactions with CuBr, FeCl2, and [Fe(CH3CN)6](ClO4)2 Yasuhiro Arikawa, Hiroyuki Kawaguchi, Kazuo Kashiwabara, and Kazuyuki Tatsumi pp 513 - 520; DOI: 10.1021/ic010921q |
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Sterically Hindered Carboxylate Ligands Support Water-Bridged Dimetallic Centers That Model Features of Metallohydrolase Active Sites Dongwhan Lee, Pei-Lin Hung, Bernhard Spingler, and Stephen J. Lippard pp 521 - 531; DOI: 10.1021/ic0107431 |
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On the Resonance Energy in New All-Metal Aromatic Molecules Alexander I. Boldyrev and Aleksey E. Kuznetsov pp 532 - 537; DOI: 10.1021/ic010840u |
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Zr11Sb18: A New Binary Antimonide Exhibiting an Unusual Sb Atom Network with Nonclassical Sb-Sb Bonding Ingrid Elder, Chi-Shen Lee, and Holger Kleinke pp 538 - 545; DOI: 10.1021/ic0108235 |
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Modification of Second-Sphere Communication, Leading to an Unusually High Abundance of the Head-to-Head Conformer of Cisplatin Cross-Link Retro Models Jamil S. Saad, Tommaso Scarcia, Kazuo Shinozuka, Giovanni Natile, and Luigi G. Marzilli pp 546 - 557; DOI: 10.1021/ic010758z |
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Ligand-Tetrahydrofuran Coupling in Chelated Aluminum Phosphinates Y. Wang, S. Parkin, and D. Atwood pp 558 - 565; DOI: 10.1021/ic0110326 |
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Synthesis, Excited-State Dynamics, and Reactivity of a Directly-Linked Pyromellitimide-(Porphinato)zinc(II) Complex Naomi P. Redmore, Igor V. Rubtsov, and Michael J. Therien pp 566 - 570; DOI: 10.1021/ic0108641 |
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Transition-Metal Complexes of a Bifunctional Tetradentate Gallium Alkoxide Ligand Stephen J. Obrey, Simon G. Bott, and Andrew R. Barron pp 571 - 576; DOI: 10.1021/ic0106773 |
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Synthesis, Structure, and Theoretical Study of the Nonclassical [CuTe7]3- Anion Perumal Sekar, Frederick P. Arnold, Jr., and James A. Ibers pp 577 - 581; DOI: 10.1021/ic011092b |
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Coordination-Position Isomeric MIICuII and CuIIMII (M = Co, Ni, Zn) Complexes Derived from Macrocyclic Compartmental Ligands Masami Yonemura, Keisuke Arimura, Koji Inoue, Naoki Usuki, Masaaki Ohba, and Hisashi  kawapp 582 - 589; DOI: 10.1021/ic010499d |
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Synthesis and Thermolysis of Alkyl- and Phenylamido Diphenylgallium, [Ph2GaN(H)R]2. Isolation and Structural Characterization of (PhGaNMe)7 and (PhGaNPh)4 Bing Luo and Wayne L. Gladfelter pp 590 - 597; DOI: 10.1021/ic010877e |
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Synthesis and Characterization of the "Sulfur-Rich" Bis(perthiobenzoato)(dithiobenzoato)technetium(III) Heterocomplex Franck Mévellec, Francesco Tisato, Fiorenzo Refosco, Alain Roucoux, Nicolas Noiret, Henri Patin, and Giuliano Bandoli pp 598 - 601; DOI: 10.1021/ic0107577 |
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Preferential C-Binding versus N-Binding in Imidazole Depends on the Metal Fragment Involved Gjergji Sini, Odile Eisenstein, and Robert H. Crabtree pp 602 - 604; DOI: 10.1021/ic010714q |
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A Study on the Novel d-f Heterodinuclear Gd(III)-Ni(II) Cryptate: Synthesis, Crystal Structure, and Magnetic Behavior Qiu-Yun Chen, Qin-Hui Luo, Li-Min Zheng, Zhi-Lin Wang, and Jiu-Tong Chen pp 605 - 609; DOI: 10.1021/ic010270y |
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Oxidative Addition of N-H Bonds to a Metal Center: Synthesis, Characterization, and Crystal Structure of New Rhodium(III) Hydrido-Pyrazolate Complexes G. Attilio Ardizzoia, Stefano Brenna, Girolamo LaMonica, Angelo Maspero, Norberto Masciocchi, and Massimo Moret pp 610 - 614; DOI: 10.1021/ic010852f |
Issue 4
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Reactivity of Hydroperoxide Bound to a Mononuclear Non-Heme Iron Site Akira Wada, Seiji Ogo, Shigenori Nagatomo, Teizo Kitagawa, Yoshihito Watanabe, Koichiro Jitsukawa, and Hideki Masuda pp 616 - 618; DOI: 10.1021/ic001058h |
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Synthesis, Characterization, and Preliminary Intramolecular Energy Transfer Studies of Rigid, Emissive, Rhenium-Linked Porphyrin Dimers Kathryn E. Splan, Melinda H. Keefe, Aaron M. Massari, Keith A. Walters, and Joseph T. Hupp pp 619 - 621; DOI: 10.1021/ic010992p |
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New Method to Prepare Polycrystalline Meta-thioboric Acid, (HBS2)3 Annamalai Karthikeyan, Chad A. Martindale, and Steve W. Martin pp 622 - 624; DOI: 10.1021/ic0155737 |
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Reactivity of the B-H Bond in Tris(pyrazolyl)hydroborato Zinc Complexes: Unexpected Example of Zinc Hydride Formation in a Protic Solvent and Its Relevance towards Hydrogen Transfer to NAD+ Mimics by Tris(pyrazolyl)hydroborato Zinc Complexes in Alcoholic Media Catherine Bergquist, Lawrence Koutcher, Amanda L. Vaught, and Gerard Parkin pp 625 - 627; DOI: 10.1021/ic011136g |
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Carboranes as Ligands for the Preparation of Organometallic Tc and Re Radiopharmaceuticals. Synthesis of [M(CO)3(5-2,3-C2B9H11)]- and rac-[M(CO)3(5-2-R-2,3-C2B9H10)]- (M = Re, 99Tc; R = CH2CH2CO2H) from [M(CO)3Br3]2- John F. Valliant, Pierre Morel, Paul Schaffer, and John H. Kaldis pp 628 - 630; DOI: 10.1021/ic0156285 |
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1,3,5-Triazine Templated Self-Assembly of a Hexameric Copper(I) Chloride Triphenyl Phosphite Core Robert D. Pike, Brian D. Borne, Jonathan T. Maeyer, and Arnold L. Rheingold pp 631 - 633; DOI: 10.1021/ic015605q |
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A Luminescent Heterometallic Dirhodium-Silver Chain Alan F. Heyduk, David J. Krodel, Emily E. Meyer, and Daniel G. Nocera pp 634 - 636; DOI: 10.1021/ic015562d |
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Sonochemical Preparation of GaSb Nanoparticles Hong-Liang Li, Ying-Chun Zhu, Oleg Palchik, Yuri Koltypin, Aharon Gedanken, Valery Palchik, Michael Slifkin, and Aryeh Weiss pp 637 - 639; DOI: 10.1021/ic015616j |
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Solvothermal Synthesis and Structure of a New Selenium-Rich Selenophosphate K3PSe4·2Se6 Christine A. Dickerson, Mary J. Fisher, Richard E. Sykora, Thomas E. Albrecht-Schmitt, and Jason A. Cody pp 640 - 642; DOI: 10.1021/ic015602d |
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A Half-Century of Nonclassical Organometallic Chemistry: A Personal Perspective F. Albert Cotton pp 643 - 658; DOI: 10.1021/ic010972n |
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Unprecedented 1-Pbasal Coordination of P4X3 Molecules (X = S, Se). An Experimental and Theoretical Study of the Apical vs Basal Complexation Dichotomy Elisabetta Guidoboni, Isaac de los Rios, Andrea Ienco, Lorenza Marvelli, Carlo Mealli, Antonio Romerosa, Roberto Rossi, and Maurizio Peruzzini pp 659 - 668; DOI: 10.1021/ic010559f |
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Triisopropyltriazacyclononane Copper(II): An Efficient Phosphodiester Hydrolysis Catalyst and DNA Cleavage Agent Kathryn M. Deck, T. Andrew Tseng, and Judith N. Burstyn pp 669 - 677; DOI: 10.1021/ic0107025 |
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Control of Charge-Transfer-Induced Spin Transition Temperature on Cobalt-Iron Prussian Blue Analogues Naonobu Shimamoto, Shin-ichi Ohkoshi, Osamu Sato, and Kazuhito Hashimoto pp 678 - 684; DOI: 10.1021/ic010915u |
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Synthesis and Solution Studies of the Complexes of Trivalent Lanthanides with the Tetraazamacrocycle TETA-(PO)2 Bin Song, Tim Storr, Shuang Liu, and Chris Orvig pp 685 - 692; DOI: 10.1021/ic010716a |
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AsCl3: From the Crystalline to the Liquid State. XRD (176 < T (K) < 250) and WAXS (295 K) Studies Jean Galy, Renée Enjalbert, Pierre Lecante, and Andrzej Burian pp 693 - 698; DOI: 10.1021/ic0102788 |
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Oxidative Addition of Phosphine-Tethered Thiols to Iron Carbonyl: Binuclear Phosphinothiolate Complexes, (-SCH2CH2PPh2)2Fe2(CO)4, and Hydride Derivatives Xuan Zhao, Yui-May Hsiao, Chia-Huei Lai, Joseph H. Reibenspies, and Marcetta Y. Darensbourg pp 699 - 708; DOI: 10.1021/ic010741g |
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X-ray Single-Crystal Structure and Magnetic Properties of Fe[CH3PO3)]·H2O: A Layered Weak Ferromagnet Carlo Bellitto, Fulvio Federici, Marcello Colapietro, Gustavo Portalone, and Daniela Caschera pp 709 - 714; DOI: 10.1021/ic0107126 |
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Synthesis and Structural Studies of 1,1'-Bis-Amino-Functionalized Ferrocenes, Ferrocene Salts, and Ferrocenium Salts Sam Bradley, Kenneth D. Camm, Xiaoming Liu, Patrick C. McGowan, Raheela Mumtaz, Karrie A. Oughton, Thomas J. Podesta, and Mark Thornton-Pett pp 715 - 726; DOI: 10.1021/ic010821k |
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Carbamoylphosphine Oxide Complexes of Trivalent Lanthanide Cations: Role of Counterions, Ligand Binding Mode, and Protonation Investigated by Quantum Mechanical Calculations C. Boehme and G. Wipff pp 727 - 737; DOI: 10.1021/ic010658t |
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Ring, Chain, and Cluster Compounds in the Cl-Ga-N-H System Alexey Y. Timoshkin, Holger F. Bettinger, and Henry F. Schaefer, III pp 738 - 747; DOI: 10.1021/ic010931r |
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29Si NMR Shifts and Relative Stabilities Calculated for Hypercoordinated Silicon-Polyalcohol Complexes: Role in Sol-Gel and Biogenic Silica Synthesis Nita Sahai and John A. Tossell pp 748 - 756; DOI: 10.1021/ic010246k |
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Cation-Independent Electron Transfer between Ferricyanide and Ferrocyanide Ions in Aqueous Solution Achim Zahl, Rudi van Eldik, and Thomas W. Swaddle pp 757 - 764; DOI: 10.1021/ic010957i |
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Redox Induced Reversible Structural Transformations of Dimeric and Polymeric Phenanthroline-Based Copper Chelates Stefan Bernhard, Kazutake Takada, David Jenkins, and Héctor D. Abruña pp 765 - 772; DOI: 10.1021/ic010608o |
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Donor Properties of the Vanadyl Ion: Reactions of Vanadyl Salicylaldimine -Ketimine and Acetylacetonato Complexes with Groups 14 and 15 Lewis Acids B. Cashin, D. Cunningham, P. Daly, P. McArdle, M. Munroe, and N. Ní Chonchubhair pp 773 - 782; DOI: 10.1021/ic010366s |
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Synthesis and Characterization of Iron(III)-Substituted, Dimeric Polyoxotungstates, [Fe4(H2O)10(-XW9O33)2]n- (n = 6, X = AsIII, SbIII; n = 4, X = SeIV, TeIV) Ulrich Kortz, Masha G. Savelieff, Bassem S. Bassil, Bineta Keita, and Louis Nadjo pp 783 - 789; DOI: 10.1021/ic010855s |
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o-Iminobenzosemiquinonato Complexes of Mn(III) and Mn(IV). Synthesis and Characterization of [MnIII(LISQ)2(LAP)] (St = 1) and [MnIV(LISQ)2(LAP-H)] (St = 1/2) Hyungphil Chun, Phalguni Chaudhuri, Thomas Weyhermüller, and Karl Wieghardt pp 790 - 795; DOI: 10.1021/ic010860w |
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Electronic Structures of Electron-Rich Octahedrally Condensed Transition-Metal Chalcogenide Clusters Régis Gautier, Eric Furet, Jean-François Halet, Zhenyang Lin, Jean-Yves Saillard, and Zhitao Xu pp 796 - 804; DOI: 10.1021/ic010812b |
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Bridging Nitrate Groups in [Mn4O3(NO3)(O2CMe)3(R2dbm)3] (R = H, Et) and [Mn4O2(NO3)(O2CEt)6(bpy)2](ClO4): Acidolysis Routes to Tetranuclear Manganese Carboxylate Complexes Guillem Aromí, Sumit Bhaduri, Pau Artús, Kirsten Folting, and George Christou pp 805 - 817; DOI: 10.1021/ic0105617 |
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[Fe(bipy)(CN)4]- as a Versatile Building Block for the Design of Heterometallic Systems: Synthesis, Crystal Structure, and Magnetic Properties of PPh4[FeIII(bipy)(CN)4]·H2O, [{FeIII(bipy)(CN)4}2MII(H2O)4]·4H2O, and [{FeIII(bipy)(CN)4}2ZnII]·2H2O [bipy = 2,2'-Bipyridine; M = Mn and Zn] Rodrigue Lescouëzec, Francesc Lloret, Miguel Julve, Jacqueline Vaissermann, and Michel Verdaguer pp 818 - 826; DOI: 10.1021/ic0107882 |
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Synthetic Analogue of the {Fe2(-OH)2(-O2CR)}3+ Core of Soluble Methane Monooxygenase Hydroxylase via Synthesis and Dioxygen Reactivity of Carboxylate-Bridged Diiron(II) Complexes Dongwhan Lee and Stephen J. Lippard pp 827 - 837; DOI: 10.1021/ic011008s |
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Cation Control of Pore and Channel Size in Cage-Based Metal-Organic Porous Materials Roger G. Harrison, O. Danny Fox, Mark O. Meng, N. Kent Dalley, and Leonard J. Barbour pp 838 - 843; DOI: 10.1021/ic011135o |
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Bis{(2-diphenylphosphino)phenyl}mercury: A P-Donor Ligand and Precursor to Mixed Metal-Mercury (d8-d10) Cyclometalated Complexes Containing 2-C6H4PPh2 Martin A. Bennett, Maria Contel, David C. R. Hockless, Lee L. Welling, and Anthony C. Willis pp 844 - 855; DOI: 10.1021/ic010890z |
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Optical Investigations of Alkali Metal Thiomanganates(II) Containing Isolated Complexes as Well as Chain and Planar Compounds Ulrike Rosellen and Hans-Herbert Schmidtke pp 856 - 863; DOI: 10.1021/ic010333c |
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Formation of Molecular Ladder Elements with Macrocyclic Platforms via Linear Bifunctional Ligands Wei Huang, Shaohua Gou, Dahua Hu, Suchada Chantrapromma, Hoong-Kun Fun, and Qingjin Meng pp 864 - 868; DOI: 10.1021/ic010407k |
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Structure-Directing Coordination Template Effect of Ethylenediamine in Formations of ZnS and ZnSe Nanocrystallites via Solvothermal Route Zhao-Xiang Deng, Cheng Wang, Xiao-Ming Sun, and Ya-Dong Li pp 869 - 873; DOI: 10.1021/ic0103502 |
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Photochemistry and Photophysics of Cr(III) Macrocyclic Complexes G. Irwin, A. D. Kirk, I. Mackay, and J. Nera pp 874 - 883; DOI: 10.1021/ic010236j |
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Formation Constants of Copper(I)-Olefin Complexes in Aqueous Solution Patrick Kamau and R. B. Jordan pp 884 - 891; DOI: 10.1021/ic010872h |
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DFT Analysis of the Activation and Breaking of the Mo-N Bond in a (-Nitrido)dimolybdenum Complex: Is Molybdenum Tris(thiolate) an Elusive Intermediate? Marie-Madeleine Rohmer and Marc Bénard pp 892 - 900; DOI: 10.1021/ic010543p |
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Nitrous Acid as a Source of NO and NO2 in the Reaction with a Macrocyclic Superoxorhodium(III) Complex Oleg Pestovsky and Andreja Bakac pp 901 - 905; DOI: 10.1021/ic011018t |
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Tetrazolylpentazoles: Nitrogen-Rich Compounds Anton Hammerl and Thomas M. Klapötke pp 906 - 912; DOI: 10.1021/ic0108134 |
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DNA Hydrolytic Cleavage by the Diiron(III) Complex Fe2(DTPB)(-O)(-Ac)Cl(BF4)2: Comparison with Other Binuclear Transition Metal Complexes Changlin Liu, Siwang Yu, Dongfeng Li, Zhanru Liao, Xiaohui Sun, and Huibi Xu pp 913 - 922; DOI: 10.1021/ic010302h |
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Nickel(II) Complexes with Tetra- and Pentadentate Aminopyridine Ligands: Synthesis, Structure, Electrochemistry, and Reduction to Nickel(I) Species Sergey V. Kryatov, B. Sharmila Mohanraj, Vladislav V. Tarasov, Olga P. Kryatova, Elena V. Rybak-Akimova, Bharathi Nuthakki, James F. Rusling, Richard J. Staples, and Alexander Y. Nazarenko pp 923 - 930; DOI: 10.1021/ic010397n |
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SrInGe and EuInGe: New Zintl Phases with an Unusual Anionic Network Derived from the ThSi2 Structure Jiang-Gao Mao, Joanna Goodey, and Arnold M. Guloy pp 931 - 937; DOI: 10.1021/ic0102891 |
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Novel DNA Sensor for Guanine Content André Del Guerzo and Andrée Kirsch-De Mesmaeker pp 938 - 945; DOI: 10.1021/ic0108944 |
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From Clusters to Ionic Complexes: Structurally Characterized Thallium Titanium Double Alkoxides Timothy J. Boyle, Cecilia A. Zechmann, Todd M. Alam, Mark A. Rodriguez, Cybele A. Hijar, and Brian L. Scott pp 946 - 957; DOI: 10.1021/ic0110833 |
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Heterometal Cubane-Type MFe3S4 Clusters (M = Mo, V) Trigonally Symmetrized with Hydrotris(pyrazolyl)borate(1-) and Tris(pyrazolyl)methanesulfonate(1-) Capping Ligands Dmitry V. Fomitchev, Craig C. McLauchlan, and R. H. Holm pp 958 - 966; DOI: 10.1021/ic011106d |
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Gas-Phase Photofragmentation of Tris(methyl vinyl ketone) Tungsten(0) and the Relationship to Laser-Assisted CVD of Tungsten Oxide Thin Films Theodore W. Bitner and Jeffrey I. Zink pp 967 - 972; DOI: 10.1021/ic0107532 |
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Solid-State Structures of Zinc(II) Benzoate Complexes. Catalyst Precursors for the Coupling of Carbon Dioxide and Epoxides Donald J. Darensbourg, Jacob R. Wildeson, and Jason C. Yarbrough pp 973 - 980; DOI: 10.1021/ic0107983 |
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Synthesis and Characterization of a Novel Cyclic Aluminophosphinate: Structure and Solid-State NMR Study Thierry Azaïs, Laure Bonhomme-Coury, Jacqueline Vaissermann, Philippe Bertani, Jérôme Hirschinger, Jocelyne Maquet, and Christian Bonhomme pp 981 - 988; DOI: 10.1021/ic010700k |
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meso Substituent Effects on the Geometric and Electronic Structures of High-Spin and Low-Spin Iron(III) Complexes of Mono-meso-Substituted Octaethylporphyrins Heather Kalish, Jason E. Camp, Marcin St  pie , Lechosaw Latos-Grayski, Marilyn M. Olmstead, and Alan L. Balchpp 989 - 997; DOI: 10.1021/ic011034q |
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Synthesis and Characterization of Novel Mononuclear Cadmium Thiolate Complexes in a Sulfur-Rich Environment Selma Bakbak, Christopher D. Incarvito, Arnold L. Rheingold, and Daniel Rabinovich pp 998 - 1001; DOI: 10.1021/ic0109243 |
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Pyramidal Inversion Isomers in the Solid-State Structure of the Tricyclic Antimony-Tellurium Imido Complex TeSb2Cl2(NtBu)4 Tristram Chivers and Gabriele Schatte pp 1002 - 1006; DOI: 10.1021/ic0109694 |
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Novel Lanthanide(III) Coordination Polymers with 1,4-Bis(phenyl-sulfinyl)butane Forming Unique Lamellar Square Array: Syntheses, Crystal Structures, and Properties Xian-He Bu, Wei Weng, Miao Du, Wei Chen, Jian-Rong Li, Ruo-Hua Zhang, and Li-Juan Zhao pp 1007 - 1010; DOI: 10.1021/ic010932j |
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Reactivity of Iron Verdohemes with Phenylmagnesium Bromide. Formation of Paramagnetic Iron-Phenyl Complexes Pamela A. Lord, Lechos aw Latos-Grayski, and Alan L. Balchpp 1011 - 1014; DOI: 10.1021/ic010948+ |
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Synthesis and Structural Characterization of [Na2M(C5O5)2(H2O)2]·4H2O (M = NiII, CuII) Chih-Chieh Wang, Cheng-Han Yang, and Gene-Hsiang Lee pp 1015 - 1018; DOI: 10.1021/ic0108538 |
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Ferromagnetic Coupling in a Ladder-Type Copper(II) Complex with Single End-to-End Azido Bridges Licun Li, Daizheng Liao, Zonghui Jiang, and Shiping Yan pp 1019 - 1021; DOI: 10.1021/ic010953d |
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Lightest Member of the Basic Carboxylate Structural Pattern: [Al3(3-O)(-O2CCF3)6(THF)3][(Me3Si)3CAl(O2CCF3)3]·C7H8 Hagen Hatop, Marilena Ferbinteanu, Herbert W. Roesky, Fanica Cimpoesu, Marcus Schiefer, Hans-Georg Schmidt, and Mathias Noltemeyer pp 1022 - 1025; DOI: 10.1021/ic010880y |
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Kinetics of the Oxidation of Triphenylphosphine by Nitric Oxide Mark D. Lim, Ivan M. Lorkovic, and Peter C. Ford pp 1026 - 1028; DOI: 10.1021/ic0108585 |
Issue 5
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New Structural Forms in Molecular Metal Phosphonates: Novel Tri- and Hexanuclear Zinc(II) Cages Containing Phosphonate and Pyrazole Ligands Vadapalli Chandrasekhar, Savariraj Kingsley, Brian Rhatigan, Matthew K. Lam, and Arnold L. Rheingold pp 1030 - 1032; DOI: 10.1021/ic011154y |
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New Rigid Angular Dicarboxylic Acid for the Construction of Nanoscopic Supramolecules: From a Molecular Rectangle to a 1-D Coordination Polymer Yong Cui, Helen L. Ngo, and Wenbin Lin pp 1033 - 1035; DOI: 10.1021/ic015627c |
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A New Type of Tweezer Complex Involving a Rhenium-Rhenium Multiple Bond That Enforces an Unusual Structure in a Dipalladium(II) Unit Shan-Ming Kuang, Phillip E. Fanwick, and Richard A. Walton pp 1036 - 1038; DOI: 10.1021/ic0112084 |
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First {Fe-NO}6 Complex with an N2S3Fe-NO Core as a Model of NO-Inactivated Iron-Containing Nitrile Hydratase. Are Thiolates and Thioethers Equivalent Donors in Low-Spin Iron Complexes? Craig A. Grapperhaus, Apurba K. Patra, and Mark S. Mashuta pp 1039 - 1041; DOI: 10.1021/ic015629x |
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Beyond Bragg Scattering: The Structure of AgCN Determined from Total Neutron Diffraction Simon J. Hibble, Simon M. Cheyne, Alex C. Hannon, and Sharon G. Eversfield pp 1042 - 1044; DOI: 10.1021/ic015610u |
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Potentiometric Investigations of Carbonate Ion Stability in Molten Cesium and Sodium Iodides Victor L. Cherginets, Olga V. Demirskaya, and Tatyana P. Rebrova pp 1045 - 1047; DOI: 10.1021/ic015525m |
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High-Resolution Optical Spectroscopy of Na3[Ln(dpa)3]·13H2O with Ln = Er3+, Tm3+, Yb3+ Christine Reinhard and Hans U. Güdel pp 1048 - 1055; DOI: 10.1021/ic0108484 |
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Synthesis, Structure, and Photophysical Studies of Luminescent Two- and Three-Dimensional Gold-Thallium Supramolecular Arrays Eduardo J. Fernández, Peter G. Jones, Antonio Laguna, José M. López-de-Luzuriaga, Miguel Monge, Javier Pérez, and M. Elena Olmos pp 1056 - 1063; DOI: 10.1021/ic010961u |
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Anomeric and Mesomeric Effects in Methoxycarbonylsulfenyl Chloride, CH3OC(O)SCl: An Experimental and Theoretical Study Mauricio F. Erben, Carlos O. Della Védova, Rosana M. Romano, Roland Boese, Heinz Oberhammer, Helge Willner, and Oswaldo Sala pp 1064 - 1071; DOI: 10.1021/ic010748y |
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Electrochemical, Spectroscopic, Structural, and Magnetic Characterization of the Reduced and Protonated -Dawson Anions in [Fe(5-C5Me5)2]5[HS2Mo18O62]·3HCONMe2·2Et2O and [NBu4]5[HS2Mo18O62]·2H2O Suzy Juraja, Truc Vu, Peter J. S. Richardt, Alan M. Bond, Terence J. Cardwell, John D. Cashion, Gary D. Fallon, Georgii Lazarev, Boujemaa Moubaraki, Keith S. Murray, and Anthony G. Wedd pp 1072 - 1078; DOI: 10.1021/ic010780s |
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Molybdenum and Tungsten Complexes of Sulfene (Thioformaldehyde S,S-Dioxide) Wolfdieter A. Schenk, Katja Nielsen, Nicolai I. Burzlaff, and Michael Hagel pp 1079 - 1085; DOI: 10.1021/ic010963e |
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High-Spin Metal Complexes Containing a Ferromagnetically Coupled Tris(semiquinone) Ligand Andrea Caneschi, Andrea Dei, Christopher P. Mussari, David A. Shultz, Lorenzo Sorace, and Kira E. Vostrikova pp 1086 - 1092; DOI: 10.1021/ic0106322 |
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Metal Ion-Dependent Molecular Inclusion Chemistry: Inclusion of Aromatic Anions by Coordinated 1,4,7,10-Tetrakis((S)-2-hydroxy-3-phenoxypropyl)-1,4,7,10-tetraazacyclododecane Christopher B. Smith, Ashley K. W. Stephens, Kia S. Wallwork, Stephen F. Lincoln, Max R. Taylor, and Kevin P. Wainwright pp 1093 - 1100; DOI: 10.1021/ic010694s |
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Kinetic and Equilibria Studies of the Aquation of the Trinuclear Platinum Phase II Anticancer Agent [{trans-PtCl(NH3)2}2{-trans-Pt(NH3)2(NH2(CH2)6NH2)2}]4+ (BBR3464) Murray S. Davies, Donald S. Thomas, Alexander Hegmans, Susan J. Berners-Price, and Nicholas Farrell pp 1101 - 1109; DOI: 10.1021/ic010851n |
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New Diamide-Diamine Ligands and their Zirconium and Hafnium Dichloride and Bis(dimethylamide) Complexes Michael E. G. Skinner, Yahong Li, and Philip Mountford pp 1110 - 1119; DOI: 10.1021/ic011043z |
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Synthesis, Structure, and Preparative Transamination of Tetrazinc Carbamato Complexes Having the Basic Zinc Carboxylate Structure C. Shawn McCowan, Thomas L. Groy, and M. Tyler Caudle pp 1120 - 1127; DOI: 10.1021/ic010885v |
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Kinetic Evidence for Intramolecular Proton Transfer Between Nickel and Coordinated Thiolate William Clegg and Richard A Henderson pp 1128 - 1135; DOI: 10.1021/ic0104306 |
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Preparation and Properties of the Aqua Ions [W4S4(H2O)12]n+ (n = 5, 6) and Crystal Structure of (Me2NH2)6[W4S4(NCS)12]·0.5H2O Maxim N. Sokolov, Danil N. Dybtsev, Alexander V. Virovets, Vladimir P. Fedin, Pedro Esparza, Rita Hernandez-Molina, Dieter Fenske, and A. Geoffrey Sykes pp 1136 - 1139; DOI: 10.1021/ic010830t |
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Carboxylate and Alkyl Carbonate Coordination at the Hydrophobic Binding Site of Redox-Active Dicobalt Amine Thiophenolate Complexes Berthold Kersting and Gunther Steinfeld pp 1140 - 1150; DOI: 10.1021/ic011004n |
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First Structurally Characterized Silver(I) Derivatives with Nonfluorinated -Diketones Augusto Cingolani, Effendy, Fabio Marchetti, Claudio Pettinari, Riccardo Pettinari, Brian W. Skelton, and Allan H. White pp 1151 - 1161; DOI: 10.1021/ic0109391 |
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Photophysical Effect of the Coordination of Water by Ruthenium(II) Bipyridyl Complexes Containing Hemilabile Phosphine-Ether Ligands Cerrie W. Rogers, Yan Zhang, Brian O. Patrick, Wayne E. Jones, Jr., and Michael O. Wolf pp 1162 - 1169; DOI: 10.1021/ic010827+ |
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Synthesis, Properties, and Crystal Structure of a Novel Anthracene-Bridged Molybdenum-Zinc Porphyrin Dimer Tetsuaki Fujihara, Kiyoshi Tsuge, Yoichi Sasaki, Yasuhiro Kaminaga, and Taira Imamura pp 1170 - 1176; DOI: 10.1021/ic010323b |
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Hydrothermal Syntheses, Structures, and Properties of the New Uranyl Selenites Ag2(UO2)(SeO3)2, M[(UO2)(HSeO3)(SeO3)] (M = K, Rb, Cs, Tl), and Pb(UO2)(SeO3)2 Philip M. Almond and Thomas E. Albrecht-Schmitt pp 1177 - 1183; DOI: 10.1021/ic0110732 |
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Novel Organotellurium(IV) Diazides and Triazides Thomas M. Klapötke, Burkhard Krumm, Peter Mayer, Holger Piotrowski, Oliver P. Ruscitti, and Alexander Schiller pp 1184 - 1193; DOI: 10.1021/ic011026+ |
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Metal Scrambling in the Trinuclear {Pt2Se2M} (M = Pt, Pd, Au) System Using an Electrospray Mass Spectrometry (ESMS) Directed Synthetic Methodology; Isolation and Crystallographic Characterization of {Pt2(3-Se)2(PPh3)4[Pt(cod)]}{PF6}2 and {Pt(3-Se)2(PPh3)2[Pt(cod)]2}{PF6}2 (cod = Cyclo-octa-1,5-diene) Jeremy S. L. Yeo, Jagadese J. Vittal, William Henderson, and T. S. Andy Hor pp 1194 - 1198; DOI: 10.1021/ic010905t |
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Tuning of Optical Band Gaps: Syntheses, Structures, Magnetic Properties, and Optical Properties of CsLnZnSe3 (Ln = Sm, Tb, Dy, Ho, Er, Tm, Yb, and Y) Kwasi Mitchell, Christy L. Haynes, Adam D. McFarland, Richard P. Van Duyne, and James A. Ibers pp 1199 - 1204; DOI: 10.1021/ic011200u |
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Coordination Chemistry of Silver(I) with the Nitrogen-Bridged Ligands (C6H5)2PN(H)P(C6H5)2 and (C6H5)2PN(CH3)P(C6H5)2: The Effect of Alkylating the Nitrogen Bridge on Ligand Bridging versus Chelating Behavior E. J. Sekabunga, Michele L. Smith, T. R. Webb, and W. E. Hill pp 1205 - 1214; DOI: 10.1021/ic010661c |
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Photochemical or Thermal Chelate Exchange in the Ruthenium Coordination Sphere of Complexes of the Ru(phen)2L Family (L = Diimine or Dinitrile Ligands) Etienne Baranoff, Jean-Paul Collin, Junko Furusho, Yoshio Furusho, Anne-Chantal Laemmel, and Jean-Pierre Sauvage pp 1215 - 1222; DOI: 10.1021/ic011014o |
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Structural Investigations of Palladium(II) and Platinum(II) Complexes of Salicylhydroxamic Acid Matthew D. Hall, Timothy W. Failes, David E. Hibbs, and Trevor W. Hambley pp 1223 - 1228; DOI: 10.1021/ic010760q |
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Electronic Energy Self-Exchange with Macrocyclic Chromium(III) Complexes Paul S. Wagenknecht, Noel A. P. Kane-Maguire, David G. Speece, and Nancy Helwic pp 1229 - 1235; DOI: 10.1021/ic010779t |
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Microwave Spectra, Geometries, and Hyperfine Constants of OCAgX (X = F, Cl, Br) Nicholas R. Walker and Michael C. L. Gerry pp 1236 - 1244; DOI: 10.1021/ic010997m |
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Syntheses and Structures of P-Anilino-P-chalcogeno- and P-Anilino-P-iminodiazasilaphosphetidines and Their Group 12 and 13 Metal Compounds Dana C. Haagenson, Daniel F. Moser, Lothar Stahl, and Richard J. Staples pp 1245 - 1253; DOI: 10.1021/ic010973f |
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Charge-Transfer Studies of Iron Cyano Compounds Bound to Nanocrystalline TiO2 Surfaces Mei Yang, David W. Thompson, and Gerald J. Meyer pp 1254 - 1262; DOI: 10.1021/ic011069q |
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Trinuclear Pyrazine-Bridged Ruthenium Complexes: Syntheses, Electrochemistry, NIR-Vis Spectra, and Their Interpretation in Terms of a 5-Orbital-3-Parameter Model Milena Sommovigo, Alessandro Ferretti, Margherita Venturi, Paola Ceroni, Cecilia Giardi, and Gianfranco Denti pp 1263 - 1271; DOI: 10.1021/ic010869y |
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Oxorhenium(V) Dithiolates Catalyze the Oxidation by tert-Butyl Hydroperoxide of Sulfoxides and Sulfides, Including 4,6-Dimethyldibenzothiophene Ying Wang, Gábor Lente, and James H. Espenson pp 1272 - 1280; DOI: 10.1021/ic011091j |
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Synthesis, Characterization, Electrochemistry, Electronic Structure, and Isomerization of Mononuclear Oxo-Molybdenum(V) Complexes: The Serine Gate Hypothesis in the Function of DMSO Reductases Brian Kail, Victor N. Nemykin, Scott R. Davie, Carl J. Carrano, Brian Hammes, and Partha Basu pp 1281 - 1291; DOI: 10.1021/ic011169w |
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Nanoscale Characterization of Redox and Acid Properties of Keggin-Type Heteropolyacids by Scanning Tunneling Microscopy and Tunneling Spectroscopy: Effect of Heteroatom Substitution In K. Song, Russell B. Shnitser, Jennifer J. Cowan, Craig L. Hill, and Mark A. Barteau pp 1292 - 1298; DOI: 10.1021/ic010832d |
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Density Functional Theory Study of Anionic and Neutral Per-Substituted 12-Vertex Boron Cage Systems, B12X12n- (n = 2, 1, 0) Michael L. McKee pp 1299 - 1305; DOI: 10.1021/ic011021c |
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Ligand Substitution Kinetics of the Iron(III) Hydroxo Dimer with Simple Inorganic Ligands Gábor Lente and István Fábián pp 1306 - 1314; DOI: 10.1021/ic011013w |
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Coordination of the Neptunyl Ion with Carbonate Ions and Water: A Theoretical Study Laura Gagliardi and Björn O. Roos pp 1315 - 1319; DOI: 10.1021/ic011076e |
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Effects of First-Row Substituents on Silicon-Phosphorus Triple Bonds Chin-Hung Lai, Ming-Der Su, and San-Yan Chu pp 1320 - 1322; DOI: 10.1021/ic0104252 |
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Pentanuclear Octacyanotungstate(V)-Based Molecule with a High Spin Ground State S = 13/2 Robert Podgajny, Cédric Desplanches, Barbara Sieklucka, Roberta Sessoli, Vincent Villar, Carley Paulsen, Wolfgang Wernsdorfer, Yves Dromzée, and Michel Verdaguer pp 1323 - 1327; DOI: 10.1021/ic010679n |
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Structural Model for the CuB Site of Dopamine -Hydroxylase: Crystal Structure of a Copper(II) Complex Showing N3OS Coordination with an Axial Sulfur Ligation Bidyut K. Santra, Pattubala A. N. Reddy, Munirathinam Nethaji, and Akhil R. Chakravarty pp 1328 - 1332; DOI: 10.1021/ic010926n |
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First Cubane-like Polysulfidomolybdate: Synthesis and Crystal Structure of Cs6[Mo4S23.6] Yuri V. Mironov, Anna S. Gardberg, and James A. Ibers pp 1333 - 1334; DOI: 10.1021/ic011020k |
Issue 6
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Molecular Metal Sulfide Cluster Model for Substrate Binding to Oil-Refinery Hydrodesulfurization Catalysts Konrad Herbst, Magda Monari, and Michael Brorson pp 1336 - 1338; DOI: 10.1021/ic011108y |
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A Simultaneous Reduction, Substitution, and Self-Assembly Reaction under Hydrothermal Conditions Afforded the First Diiodopyridine Copper(I) Coordination Polymer Jack Y. Lu and Amy M. Babb pp 1339 - 1341; DOI: 10.1021/ic015589x |
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Oxidative Degradation of -Diketiminate Ligand in Copper(II) and Zinc(II) Complexes Seiji Yokota, Yoshimitsu Tachi, and Shinobu Itoh pp 1342 - 1344; DOI: 10.1021/ic0156238 |
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Evidence of Desulfurization in the Oxidative Cyclization of Thiosemicarbazones. Conversion to 1,3,4-Oxadiazole Derivatives Patricia Gómez-Saiz, Javier García-Tojal, Miguel A. Maestro, Francisco J. Arnaiz, and Teófilo Rojo pp 1345 - 1347; DOI: 10.1021/ic015625s |
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Pressure-Controlled Plasticity of Cu(H2O)62+ Complex and Phase Transition in Cs2Cu(ZrF6)2·6H2O Maria A. Augustyniak-Jab okow, Aldona Krupska, Marcin Krupski, and Yurii V. Yablokovpp 1348 - 1350; DOI: 10.1021/ic0156137 |
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Modulating the Reduction Potential of Mononuclear Cobalt(II) Complexes via Selective Deprotonation of Tris[(2-benzimidazolyl)methyl]amine Brian S. Hammes, Matthew T. Kieber-Emmons, Roger Sommer, and Arnold L. Rheingold pp 1351 - 1353; DOI: 10.1021/ic0155885 |
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The First Designed Syntheses of Bis-dimetal Molecules in Which the Bridges Are Diamidate Ligands F. Albert Cotton, Lee M. Daniels, James P. Donahue, Chun Y. Liu, and Carlos A. Murillo pp 1354 - 1356; DOI: 10.1021/ic025503f |
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Reduction of [VO2(ma)2]- and [VO2(ema)2]- by Ascorbic Acid and Glutathione: Kinetic Studies of Pro-Drugs for the Enhancement of Insulin Action Bin Song, Nicolas Aebischer, and Chris Orvig pp 1357 - 1364; DOI: 10.1021/ic0111684 |
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Ruthenium Complexes of Analogues of the Antitumor Antibiotic Streptonigrin Pia I. Anderberg, Margaret M. Harding, Ian J. Luck, and Peter Turner pp 1365 - 1371; DOI: 10.1021/ic010876m |
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Reactivity of the Heterometallic Clusters [HMCo3(CO)12] and [Et4N][MCo3(CO)12] (M = Fe, Ru) toward Phosphine Selenides, Including Selenium Transfer. Crystal Structures of [HRuCo3(CO)7(-CO)3(-dppy)], [MCo2(3-Se)(CO)7(-dppy)], and [RuCo2(3-Se)(CO)7(-dppm)] [dppy = Ph2(2-C5H4N)P, dppm = Ph2PCH2PPh2] Pierre Braunstein, Claudia Graiff, Chiara Massera, Giovanni Predieri, Jacky Rosé, and Antonio Tiripicchio pp 1372 - 1382; DOI: 10.1021/ic010824x |
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Nickel Complexes of Bidentate [S2] and [SN] Borato Ligands Pinghua Ge, Arnold L. Rheingold, and Charles G. Riordan pp 1383 - 1390; DOI: 10.1021/ic010966r |
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Synthesis, Structure, and Fluorescence of the Novel Cadmium(II)-Trimesate Coordination Polymers with Different Coordination Architectures Jing-Cao Dai, Xin-Tao Wu, Zhi-Yong Fu, Chuan-Peng Cui, Sheng-Min Hu, Wen-Xin Du, Li-Ming Wu, Han-Hui Zhang, and Rui-Qing Sun pp 1391 - 1396; DOI: 10.1021/ic010794y |
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(5-Pentamethylcyclopentadienyl)rhodium and -iridium Complexes with Weakly and Strongly Coordinating Anions: Isolation and First X-ray Molecular Structures of the Tris(solvent) Complexes [(C5Me5)M(acetone)2(H2O)][BF4]2 (M = Rh, Ir) Hani Amouri, Carine Guyard-Duhayon, Jacqueline Vaissermann, and Marie Noelle Rager pp 1397 - 1403; DOI: 10.1021/ic010772b |
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Two New Terpyridine Dimanganese Complexes: A Manganese(III,III) Complex with a Single Unsupported Oxo Bridge and a Manganese(III,IV) Complex with a Dioxo Bridge. Synthesis, Structure, and Redox Properties Carole Baffert, Marie-Noëlle Collomb, Alain Deronzier, Jacques Pécaut, Julian Limburg, Robert H. Crabtree, and Gary W. Brudvig pp 1404 - 1411; DOI: 10.1021/ic0107375 |
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Pyrazolyl-Bridged Iridium Dimers. 18.1 Influence of Metal-Metal Bonding on the Geometry of Diiridium(II) Adducts and Hydrido-diiridium Complexes Formed from the Diiridium(I) Prototype [Ir(-pz)(PPh3)(CO)]2 (pzH = Pyrazole) by Dihydrogen Addition or Protonation Ron D. Brost, Gordon W. Bushnell, Daryll G. Harrison, and Stephen R. Stobart pp 1412 - 1420; DOI: 10.1021/ic010448g |
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DFT Investigation of Structural, Electronic, and Catalytic Properties of Diiron Complexes Related to the [2Fe]H Subcluster of Fe-Only Hydrogenases Maurizio Bruschi, Piercarlo Fantucci, and Luca De Gioia pp 1421 - 1429; DOI: 10.1021/ic010770r |
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Preparation and Structural Characterization of (Me3SiNSN)2Se, a New Synthon for Sulfur-Selenium Nitrides Jari Konu, Arto Maaninen, Katja Paananen, Petri Ingman, Risto S. Laitinen, Tristram Chivers, and Jussi Valkonen pp 1430 - 1435; DOI: 10.1021/ic011045j |
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Analysis of Paramagnetic NMR Spectra of Triple-Helical Lanthanide Complexes with 2,6-Dipicolinic Acid Revisited: A New Assignment of Structural Changes and Crystal-Field Effects 25 Years Later Nadjet Ouali, Bernard Bocquet, Stéphane Rigault, Pierre-Yves Morgantini, Jacques Weber, and Claude Piguet pp 1436 - 1445; DOI: 10.1021/ic010801i |
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Synthesis and Structural Characterization of 2,6-Dimesitylphenyl Complexes of Scandium, Ytterbium, and Yttrium Gerd W. Rabe, Christian D. Bérubé, Glenn P. A. Yap, Kin-Chung Lam, Thomas E. Concolino, and Arnold L. Rheingold pp 1446 - 1453; DOI: 10.1021/ic0109492 |
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Quantitative Reactivity Model for the Hydration of Carbon Dioxide by Biomimetic Zinc Complexes Michael Bräuer, J. Luis Pérez-Lustres, Jennie Weston, and Ernst Anders pp 1454 - 1463; DOI: 10.1021/ic0010510 |
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Thermodynamics, Kinetics, and Mechanism of the Stepwise Dissociation and Formation of Tris(L-lysinehydroxamato)iron(III) in Aqueous Acid Joseph I. Wirgau, Ivan Spasojevi  , Hakim Boukhalfa, Ines Batini-Haberle, and Alvin L. Crumblisspp 1464 - 1473; DOI: 10.1021/ic0109795 |
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Tribromohydroxyphosphonium Hexafluorometalate: Synthesis, Spectroscopic Characterization, and Crystal Structure of Br3POH+AsF6- Rolf Minkwitz and Markus Dzyk pp 1474 - 1477; DOI: 10.1021/ic0109039 |
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Synthesis, Structure, and Magnetic Properties of Tetranuclear Cubane-like and Chain-like Iron(II) Complexes Based on the N4O Pentadentate Dinucleating Ligand 1,5-Bis[(2-pyridylmethyl)amino]pentan-3-ol Juan M. Clemente-Juan, Christine Mackiewicz, Marc Verelst, Françoise Dahan, Azzedine Bousseksou, Yiannis Sanakis, and Jean-Pierre Tuchagues pp 1478 - 1491; DOI: 10.1021/ic010787+ |
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Formation of Double Cubanes [Sn7(NR)8] in the Reactions of Pyridyl and Pyrimidinyl Amines with Sn(NMe2)2: A Synthetic and Theoretical Study David R. Armstrong, Francesca Benevelli, Andrew D. Bond, Neil Feeder, Eilis A. Harron, Alexander D. Hopkins, Mary McPartlin, David Moncrieff, David Sáez, Elsje A. Quadrelli, Anthony D. Woods, and Dominic S. Wright pp 1492 - 1501; DOI: 10.1021/ic011090r |
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Characteristics and Properties of Metal-to-Ligand Charge-Transfer Excited States in 2,3-Bis(2-pyridyl)pyrazine and 2,2'-Bypyridine Ruthenium Complexes. Perturbation-Theory-Based Correlations of Optical Absorption and Emission Parameters with Electrochemistry and Thermal Kinetics and Related Ab Initio Calculations Dhehinie S. Seneviratne, Md. Jamal Uddin, V. Swayambunathan, H. Bernhard Schlegel, and John F. Endicott pp 1502 - 1517; DOI: 10.1021/ic010172c |
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Structure and Dynamics of the Lincomycin-Copper(II) Complex in Water Solution by 1H and 13C NMR Studies Elena Gaggelli, Nicola Gaggelli, Daniela Valensin, Gianni Valensin, Ma gorzata Jeowska-Bojczuk, and Henryk Kozowskipp 1518 - 1522; DOI: 10.1021/ic010388e |
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Homologous Series of Redox-Active, Dinuclear Cations [M2(O2CCH3)2(pynp)2]2+ (M = Mo, Ru, Rh) with the Bridging Ligand 2-(2-Pyridyl)-1,8-naphthyridine (pynp) Cristian Saul Campos-Fernández, Lisa M. Thomson, José Ramón Galán-Mascarós, Xiang Ouyang, and Kim R. Dunbar pp 1523 - 1533; DOI: 10.1021/ic010996u |
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Ruthenium-Manganese Complexes for Artificial Photosynthesis: Factors Controlling Intramolecular Electron Transfer and Excited-State Quenching Reactions Malin L. A. Abrahamsson, Helena Berglund Baudin, Anh Tran, Christian Philouze, Katja E. Berg, Mary Katherine Raymond-Johansson, Licheng Sun, Bjorn Akermark, Stenbjorn Styring, and Leif Hammarstrom pp 1534 - 1544; DOI: 10.1021/ic0107227 |
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Chiral Monomeric and Homochiral Dimeric Copper(II) Complexes of a New Chiral Ligand, N-(1,2-Bis(2-pyridyl)ethyl)pyridine-2-carboxamide: An Example of Molecular Self-Recognition John M. Rowland, Marilyn M. Olmstead, and Pradip K. Mascharak pp 1545 - 1549; DOI: 10.1021/ic0109905 |
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Metal-Induced Cyclization of Thiosemicarbazones Derived from -Keto Amides and -Keto Esters: Open-Chain and Cyclized Ligands in Zinc(II) Complexes José S. Casas, María V. Castaño, Eduardo E. Castellano, Javier Ellena, María S. García-Tasende, Ángeles Gato, Agustín Sánchez, Luisa M. Sanjuán, and José Sordo pp 1550 - 1557; DOI: 10.1021/ic0111942 |
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Anisole Hydrogenation with Well-Characterized Polyoxoanion- and Tetrabutylammonium-Stabilized Rh(0) Nanoclusters: Effects of Added Water and Acid, Plus Enhanced Catalytic Rate, Lifetime, and Partial Hydrogenation Selectivity Jason A. Widegren and Richard G. Finke pp 1558 - 1572; DOI: 10.1021/ic0109750 |
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Quantifying the Electronic Effect of Substituted Phosphine Ligands via Molecular Electrostatic Potential C. H. Suresh and Nobuaki Koga pp 1573 - 1578; DOI: 10.1021/ic0109400 |
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Mechanistic Information from Pressure Acceleration of Hydride Formation via Proton Binding to a Cobalt(I) Macrocycle Etsuko Fujita, James F. Wishart, and Rudi van Eldik pp 1579 - 1583; DOI: 10.1021/ic011109q |
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Thermodynamic Studies on the Recognition of Flexible Peptides by Transition-Metal Complexes Shuguang Sun, Md. Abul Fazal, Bidhan C. Roy, Binita Chandra, and Sanku Mallik pp 1584 - 1590; DOI: 10.1021/ic0108742 |
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Chelated Hydrazido(3-)rhenium(V) Complexes: On the Way to the Nitrido-M(V) Core (M = Tc, Re) Franck Mévellec, Nicolas Lepareur, Alain Roucoux, Nicolas Noiret, Henri Patin, Giuliano Bandoli, Marina Porchia, and Francesco Tisato pp 1591 - 1597; DOI: 10.1021/ic0110979 |
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Synthesis, Structures, and Magnetic Properties of Heterodimetal Bis(-hydroxo)chromium(III)nickel(II) Complexes with Tpa Derivatives Having Sterically Bulky Substituents Kazushi Shiren, Shuhei Fujinami, Masatatsu Suzuki, and Akira Uehara pp 1598 - 1605; DOI: 10.1021/ic010568o |
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In Situ Formation of Ruthenium Catalysts for the Homogeneous Hydrogenation of Carbon Dioxide Chih-Cheng Tai, Justine Pitts, John C. Linehan, A. Denise Main, Pradip Munshi, and Philip G. Jessop pp 1606 - 1614; DOI: 10.1021/ic010866l |
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Single- and Double-Cubane Clusters in the Multiple Oxidation States [VFe3S4]3+,2+,1+ Christina Hauser, Eckhard Bill, and R. H. Holm pp 1615 - 1624; DOI: 10.1021/ic011011b |
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Nanoclusters in Catalysis: A Comparison of CS2 Catalyst Poisoning of Polyoxoanion- and Tetrabutylammonium-Stabilized 40 ± 6 Å Rh(0) Nanoclusters to 5 Rh/Al2O3, Including an Analysis of the Literature Related to the CS2 to Metal Stoichiometry Issue Brooks J. Hornstein, John D. Aiken, III, and Richard G. Finke pp 1625 - 1638; DOI: 10.1021/ic010920y |
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Filling a Void: Isolation and Characterization of Tetracarboxylato Dimolybdenum Cations F. Albert Cotton, Lee M. Daniels, Elizabeth A. Hillard, and Carlos A. Murillo pp 1639 - 1644; DOI: 10.1021/ic011079r |
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P-O Donor Action from Carboxylate Anions with Phosphorus in the Presence of Hydrogen Bonding. A Model for Phosphoryl-Transfer Enzymes A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes pp 1645 - 1651; DOI: 10.1021/ic0111435 |
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Structures of Sb(OC6H3Me2-2,6)3 and Sb(OEt)5·NH3: The First Authenticated Monomeric Sb(OR)n (n = 3, 5) Graeme A. Horley, Mary F. Mahon, Kieran C. Molloy, Monica M. Venter, Peter W. Haycock, and Christopher P. Myers pp 1652 - 1657; DOI: 10.1021/ic0106726 |
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Insertion of a Bis(phosphine)platinum Group into the S-S Bond of Mn2(CO)7(-S2) Richard D. Adams, O-Sung Kwon, and Mark D. Smith pp 1658 - 1661; DOI: 10.1021/ic0110023 |
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Rhenium Bipyridine Complexes for the Recognition of Glucose Douglas R. Cary, Natasha P. Zaitseva, Kelsey Gray, Kira E. O'Day, Christopher B. Darrow, Stephen M. Lane, Thomas A. Peyser, Joe H. Satcher, Jr., William P. Van Antwerp, A. J. Nelson, and John G. Reynolds pp 1662 - 1669; DOI: 10.1021/ic010202b |
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Preparative and Structural Studies on the Carbonyl Cyanides of Iron, Manganese, and Ruthenium: Fundamentals Relevant to the Hydrogenases Stephen M. Contakes, Sodio C. N. Hsu, Thomas B. Rauchfuss, and Scott R. Wilson pp 1670 - 1678; DOI: 10.1021/ic011030l |
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Redox-Related Chemical Shift Perturbations on Backbone Nuclei of High-Potential Iron-Sulfur Proteins Teresa Lehmann, Claudio Luchinat, and Mario Piccioli pp 1679 - 1683; DOI: 10.1021/ic010761i |
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Valence Delocalization in a Mixed-Oxidation Divanadium (IV, V) Complex Electrogenerated from Its Structurally Characterized Divanadium (V) Analogue with a Tridentate (ONO) Ligand Rupam Dinda, Parbati Sengupta, Saktiprosad Ghosh, and Thomas C. W. Mak pp 1684 - 1688; DOI: 10.1021/ic010865t |
Issue 7
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A New High-Yield Synthesis of Cl3P=NSiMe3, a Monomeric Precursor for the Controlled Preparation of High Molecular Weight Polyphosphazenes Bin Wang, Eric Rivard, and Ian Manners pp 1690 - 1691; DOI: 10.1021/ic011125n |
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Precipitation of a Dioxouranium(VI) Species from a Room Temperature Ionic Liquid Medium Antonia E. Bradley, Justine E. Hatter, Mark Nieuwenhuyzen, William R. Pitner, Kenneth R. Seddon, and Robert C. Thied pp 1692 - 1694; DOI: 10.1021/ic015619w |
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Selective Cleavage of P-N Bonds and the Conversion of Rhodium N-Pyrrolyl Phosphine Complexes into Diphosphoxane-Bridged Dimers Andrew D. Burrows, Mary F. Mahon, Mark T. Palmer, and Maurizio Varrone pp 1695 - 1697; DOI: 10.1021/ic0108989 |
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Observation of the Structural Consequences of a Reversible S = 3/2 and S = 1/2 Spin Crossover in the Single Crystal Yoshiki Ohgo, Takahisa Ikeue, and Mikio Nakamura pp 1698 - 1700; DOI: 10.1021/ic015620v |
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CrCp*Tp: A High-Spin Cr(II) Sandwich Complex with a Large Structural Distortion Tim J. Brunker, Jennifer C. Green, and Dermot O'Hare pp 1701 - 1703; DOI: 10.1021/ic0255151 |
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Synthesis of Ln(III) Chloride Tetraphenylporphyrin Complexes Timothy J. Foley, Khalil A. Abboud, and James M. Boncella pp 1704 - 1706; DOI: 10.1021/ic015612e |
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Enhanced Selectivity for Actinides over Lanthanides with CMPO Ligands Secured to a C3-Symmetric Triphenoxymethane Platform Matthew W. Peters, Eric J. Werner, and Michael J. Scott pp 1707 - 1716; DOI: 10.1021/ic011144x |
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Mechanistic Diversity Covering 15 Orders of Magnitude in Rates: Cyanide Exchange on [M(CN)4]2- (M = Ni, Pd, and Pt) Florence J. Monlien, Lothar Helm, Amira Abou-Hamdan, and André E. Merbach pp 1717 - 1727; DOI: 10.1021/ic010917e |
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Two-Electron Transfer for Tl(aq)3+/Tl(aq)+ Revisited. Common Virtual [TlII-TlII]4+ Intermediate for Homogeneous (Superexchange) and Electrode (Sequential) Mechanisms Dimitri E. Khoshtariya, Tina D. Dolidze, Leonid D. Zusman, Göran Lindbergh, and Julius Glaser pp 1728 - 1738; DOI: 10.1021/ic0100525 |
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Bonding Behavior of Co(CO)3L (L = CO, PPh3) Building Blocks in Platinum-Cobalt Carbonyl Clusters Robert Bender, Pierre Braunstein, Salah-Eddine Bouaoud, Djamil Rouag, Pierre D. Harvey, Stéphane Golhen, and Lahcène Ouahab pp 1739 - 1746; DOI: 10.1021/ic010739p |
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Substitution Reactions on Cyclometalated Pt(IV) Complexes. Associative Tuning by Fluoro Ligands and Fluorinated Substituents Paul V. Bernhardt, Carlos Gallego, Manuel Martinez, and Teodor Parella pp 1747 - 1754; DOI: 10.1021/ic0108179 |
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Excited-State Distortions Determined from Structured Luminescence of Nitridorhenium(V) Complexes Susan E. Bailey, Rebecca A. Eikey, Mahdi M. Abu-Omar, and Jeffrey I. Zink pp 1755 - 1760; DOI: 10.1021/ic010680m |
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Structure and Bonding in [M6O19]n- Isopolyanions Adam J. Bridgeman and Germán Cavigliasso pp 1761 - 1770; DOI: 10.1021/ic011086f |
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Structural, Spectral, and Magnetic Properties of End-to-End Di--thiocyanato-Bridged Polymeric Complexes of Ni(II) and Co(II). X-ray Crystal Structure of Di--thiocyanatobis(imidazole)nickel(II) Bogumi a  urowska, Jerzy Mroziski, Miguel Julve, Francisco Lloret, Anna Maslejova, and Wanda Sawka-Dobrowolskapp 1771 - 1777; DOI: 10.1021/ic010792d |
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Synthesis and Structural Characterization of Integrally Oxidized, Metal-Free Phthalocyanine Compounds: [H2(pc)][IBr2] and [H2(pc)]2[IBr2]Br·C10H7Br Anna S. Gardberg, Syaulan Yang, Brian M. Hoffman, and James A. Ibers pp 1778 - 1781; DOI: 10.1021/ic010994+ |
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Pairwise Exchanges of Oxo and Imido Groups in Rhenium(VII) Compounds Wei-Dong Wang and James H. Espenson pp 1782 - 1787; DOI: 10.1021/ic011070p |
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Catecholase Activity of a Series of Dicopper(II) Complexes with Variable Cu-OH(phenol) Moieties Ademir Neves, Liane M. Rossi, Adailton J. Bortoluzzi, Bruno Szpoganicz, Clayton Wiezbicki, Erineu Schwingel, Wolfgang Haase, and Sergei Ostrovsky pp 1788 - 1794; DOI: 10.1021/ic010708u |
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A Dinuclear Manganese(II) Complex with the {Mn2(-O2CCH3)3}+ Core: Synthesis, Structure, Characterization, Electroinduced Transformation, and Catalase-like Activity Isabel Romero, Lionel Dubois, Marie-Noëlle Collomb, Alain Deronzier, Jean-Marc Latour, and Jacques Pécaut pp 1795 - 1806; DOI: 10.1021/ic010721e |
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Carboxyester Hydrolysis Catalyzed by a Novel Dicopper(II) Complex with an Alcohol-Pendant Macrocycle Shu-An Li, Jiang Xia, De-Xi Yang, Yan Xu, Dong-Feng Li, Mei-Fang Wu, and Wen-Xia Tang pp 1807 - 1815; DOI: 10.1021/ic011019l |
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Magnetically Isolated CuIIGdIII Pairs in the Series [Cu(acacen)Gd(pta)3], [Cu(acacen)Gd(hfa)3], [Cu(salen)Gd(pta)3], and [Cu(salen)Gd(hfa)3], [acacen = N,N'-Ethylenebis(acetylacetoniminate(-)), salen = N,N'-Ethylenebis(salicylideniminate(-)), hfa = 1,1,1,5,5,5-Hexafluoropentane-2,4-dionate(-), pta = 1,1,1-Trifluoro-5,5-dimethylhexane-2,4-dionate(-)] M. Ryazanov, V. Nikiforov, F. Lloret, M. Julve, N. Kuzmina, and A. Gleizes pp 1816 - 1823; DOI: 10.1021/ic0110777 |
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N-Centered Hexazirconium Chloride Clusters: Excision and Redox Chemistry Xiaobing Xie and Timothy Hughbanks pp 1824 - 1830; DOI: 10.1021/ic0107678 |
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Effect of Asymmetry on the Electronic Delocalization in Diiron and Iron-Cobalt Mixed Valence Metallocenic Compounds Y. Portilla, I. Chávez, V. Arancibia, B. Loeb, J. M. Manríquez, A. Roig, and E. Molins pp 1831 - 1836; DOI: 10.1021/ic011175s |
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Unique Reactivity of a Tetradentate N2S2 Complex of Nickel: Intermediates in the Production of Sulfur Oxygenates Vincent E. Kaasjager, Elisabeth Bouwman, S. Gorter, Jan Reedijk, Craig A. Grapperhaus, Joseph H. Reibenspies, Jason J. Smee, Marcetta Y. Darensbourg, Agnes Derecskei-Kovacs, and Lisa M. Thomson pp 1837 - 1844; DOI: 10.1021/ic010784x |
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Geometric Hydration Shells for Anionic Platinum Group Metal Chloro Complexes Kevin J. Naidoo, Günter Klatt, Klaus R. Koch, and David J. Robinson pp 1845 - 1849; DOI: 10.1021/ic010719n |
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Mild Benzene-Thermal Route to GaP Nanorods and Nanospheres Shanmin Gao, Yi Xie, Jun Lu, Guoan Du, Wei He, Deliang Cui, Baibiao Huang, and Minhua Jiang pp 1850 - 1854; DOI: 10.1021/ic010431y |
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New Mononuclear, Cyclic Tetranuclear, and 1-D Helical-Chain Cu(II) Complexes Formed by Metal-Assisted Hydrolysis of 3,6-Di-2-pyridyl-1,2,4,5-tetrazine (DPTZ): Crystal Structures and Magnetic Properties Xian-He Bu, He Liu, Miao Du, Lei Zhang, Ya-Mei Guo, Mitsuhiko Shionoya, and Joan Ribas pp 1855 - 1861; DOI: 10.1021/ic010955y |
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Self-Assembly of Transition-Metal-Based Macrocycles Linked by Photoisomerizable Ligands: Examples of Photoinduced Conversion of Tetranuclear-Dinuclear Squares Shih-Sheng Sun, Jason A. Anspach, and Alistair J. Lees pp 1862 - 1869; DOI: 10.1021/ic010998e |
Synthesis of Tris- and Tetrakis(pyrazol-1-yl)borate Gold(III) Complexes. Crystal Structures of [Au{ 2-N,N'-BH(Pz)3}Cl2] (pz = Pyrazol-1-yl) and [Au{2-N,N'-B(Pz)4}(2-C,N-C6H4CH2NMe2-2)]ClO4·CHCl3José Vicente, María Teresa Chicote, Rita Guerrero, Ulrich Herber, and Delia Bautista pp 1870 - 1875; DOI: 10.1021/ic011031d |
Pentagon Stability: Cyclic Delocalization of Lone Pairs through  Conjugation and Design of PolycyclophosphanesJing Ma, Atsushi Hozaki, and Satoshi Inagaki pp 1876 - 1882; DOI: 10.1021/ic0107835 |
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A DFT Study of the Electronic Spectrum of the -Keggin Anion [CoIIW12O40]6- Joan Miquel Maestre, Xavier Lopez, Carles Bo, Josep-M. Poblet, and Claude Daul pp 1883 - 1888; DOI: 10.1021/ic0110676 |
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Coordination Chemistry of Novel Scorpionate Ligands Based on 3-Cyclohexylpyrazole and 3-Cyclohexyl-4-bromopyrazole Swiatoslaw Trofimenko, Arnold L. Rheingold, and Louise M. Liable Sands pp 1889 - 1896; DOI: 10.1021/ic011186l |
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Synthesis and Resolution of (R*,R*)-(±)-1,1,4,7,10,10-Hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New Ligand for the Stereoselective Self-Assembly of Dicopper(I), Disilver(I), and Digold(I) Helicates Vernon C. Cook, Anthony C. Willis, Johann Zank, and S. Bruce Wild pp 1897 - 1906; DOI: 10.1021/ic010988d |
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The Synthesis and Characterization of Compounds of the Type Hg{1-C6H4-2-C(H)=NC6H5-nRn}2 Kevin R. Flower, Victoria J. Howard, Shakil Naguthney, Robin G. Pritchard, John E. Warren, and Alan T. McGown pp 1907 - 1912; DOI: 10.1021/ic010881q |
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Layered Zirconium Phosphate Chloride Dimethyl Sulfoxide as a Two-Dimensional Exchanger of Anionic Ligands. Part I. Substitution of Chloride with Inorganic Monodentate Ligands Giulio Alberti, Silvia Masci, and Riccardo Vivani pp 1913 - 1919; DOI: 10.1021/ic010643v |
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Effect of Metal-Oxygen Covalent Bonding on the Competition between Jahn-Teller Distortion and Charge Disproportionation in the Perovskites of High-Spin d4 Metal Ions LaMnO3 and CaFeO3 M.-H. Whangbo, H.-J. Koo, A. Villesuzanne, and M. Pouchard pp 1920 - 1929; DOI: 10.1021/ic0110427 |
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Metallonitrosyl Fragment as Electron Acceptor: Intramolecular Charge Transfer, Long Range Electronic Coupling, and Electrophilic Reactivity in the trans-[NCRu(py)4(CN)Ru(py)4NO]3+ Ion Federico Roncaroli, Luis M. Baraldo, Leonardo D. Slep, and José A. Olabe pp 1930 - 1939; DOI: 10.1021/ic0109896 |
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Synthesis and Structural Comparison of Triaryl(sulfonylimino)pnictoranes Yoshihiro Matano, Hazumi Nomura, and Hitomi Suzuki pp 1940 - 1948; DOI: 10.1021/ic0110575 |
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Lowering Melting Points in Asymmetrically Substituted Salen-Copper(II) Complexes Exhibiting Mesomorphic Behavior. Structure of the Mesogen Cu(5-hexyloxySalen) Reinhard Paschke, Dörte Balkow, and E. Sinn pp 1949 - 1953; DOI: 10.1021/ic010875u |
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Oxygen Transfer Reactions. 4. Reaction of High Valent Oxoruthenium Compounds with Sulfides Sheng Lai, Carmela Jackson Lepage, and Donald G. Lee pp 1954 - 1957; DOI: 10.1021/ic0108336 |
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Redox Chemistry of Tellurium Bis(tert-butylamido)cyclodiphosph(V)azane Disulfide and Diselenide Systems: A Spectroscopic and Structural Study Glen G. Briand, Tristram Chivers, and Gabriele Schatte pp 1958 - 1965; DOI: 10.1021/ic011151l |
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Oxidative Damage by Ruthenium Complexes Containing the Dipyridophenazine Ligand or Its Derivatives: A Focus on Intercalation Sarah Delaney, Matthias Pascaly, Pratip K. Bhattacharya, Koun Han, and Jacqueline K. Barton pp 1966 - 1974; DOI: 10.1021/ic0111738 |
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Third-Order Nonlinear Optical Properties of Complexes with MM Triple and Quadruple Bonds (M = Mo, W) at 1064 nm by Degenerate Four-Wave Mixing Brian D. Pate, Jonathan R. G. Thorne, Damon R. Click, Malcolm H. Chisholm, and Robert G. Denning pp 1975 - 1978; DOI: 10.1021/ic0112138 |
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Five-Coordinate Iron(III) Porphycenes: 1H NMR, Magnetic, and Structural Studies Krystyna Rachlewicz, Lechos aw Latos-Grayski, Emanuel Vogel, Zbigniew Ciunik, and Lucjan B. Jerzykiewiczpp 1979 - 1988; DOI: 10.1021/ic010725j |
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New Hydrogen Bond-Supported 3-D Molecular Assembly from Polyoxovanadate and Tetramethylbiimidazole Hitoshi Kumagai, Masashi Arishima, Susumu Kitagawa, Koichi Ymada, Satoshi Kawata, and Sumio Kaizaki pp 1989 - 1992; DOI: 10.1021/ic010599j |
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29Si NMR Shifts and Relative Stabilities Calculated for Hypercoordinated Silicon-Polyalcohol Complexes: Role in Sol-Gel and Biogenic Silica Synthesis Nita Sahai and John A. Tossell: pp 1993 - 1994; DOI: 10.1021/ic020151y |
Issue 8
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Reviewing Crystallographic Data-Sifting CIFs Richard Eisenberg pp 1995 - 1995; DOI: 10.1021/ic0202007 |
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Iron Pentacarbonyl as a Precursor for Molecule-Based Magnets: Formation of Fe[TCNE]2 (Tc = 100 K) and Fe[TCNQ]2 (Tc = 35 K) Magnets Konstantyn I. Pokhodnya, Nate Petersen, and Joel S. Miller pp 1996 - 1997; DOI: 10.1021/ic011288b |
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Tuning of Electronic Structures of Quasi-One-Dimensional Bromo-Bridged Ni(III) Complexes with Strong Electron-Correlation by Doping of Co(III) Ions, [Ni1-xCox(Chxn)2Br]Br2 M. Yamashita, K. Yokoyama, S. Furukawa, T. Manabe, T. Ono, K. Nakata, C. Kachi-Terajima, F. Iwahori, T. Ishii, H. Miyasaka, K. Sugiura, H. Matsuzaki, H. Kishida, H. Okamoto, H. Tanaka, Y. Hasegawa, K. Marumoto, H. Ito, and S. Kuroda pp 1998 - 2000; DOI: 10.1021/ic011326r |
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Heterolytic Activation of Hydrogen as a Trigger for Iridium Complex Promoted Activation of Carbon-Fluorine Bonds Paul J. Albietz, Jr., James F. Houlis, and Richard Eisenberg pp 2001 - 2003; DOI: 10.1021/ic025563l |
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New Class of Ruthenium Sulfide Clusters: Ru4S6(PPh3)4, Ru5S6(PPh3)5, and Ru6S8(PPh3)6 Amanda L. Eckermann, Markus Wunder, Dieter Fenske, Thomas B. Rauchfuss, and Scott R. Wilson pp 2004 - 2006; DOI: 10.1021/ic0255104 |
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Novel Chiral Three-Dimensional Iron(III) Compound Exhibiting Magnetic Ordering at Tc = 40 K Donatella Armentano, Giovanni De Munno, Francesc Lloret, Andrei V. Palii, and Miguel Julve pp 2007 - 2013; DOI: 10.1021/ic011100o |
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Lithium Fluoroarylamidinates: Syntheses, Structures, and Reactions Carsten Knapp, Enno Lork, Paul G. Watson, and Rüdiger Mews pp 2014 - 2025; DOI: 10.1021/ic011099t |
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A Density Functional Study of Oxygen Activation by Unsaturated Complexes [M(bipy)2]2+, M = Cr and Fe Peter R. Howe, John E. McGrady, and Christine J. McKenzie pp 2026 - 2031; DOI: 10.1021/ic010782c |
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Weakly Coordinating Anions: Crystallographic and NQR Studies of Halogen-Metal Bonding in Silver, Thallium, Sodium, and Potassium Halomethanesulfonates Gary Wulfsberg, Katherine D. Parks, Richard Rutherford, Debra Jones Jackson, Frank E. Jones, Dana Derrick, William Ilsley, Steven H. Strauss, Susie M. Miller, Oren P. Anderson, T. A. Babushkina, S. I. Gushchin, E. A. Kravchenko, and V. G. Morgunov pp 2032 - 2040; DOI: 10.1021/ic010715i |
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Direct Addition of Alcohols to Organonitriles Activated by Ligation to a Platinum(IV) Center Nadezhda A. Bokach, Vadim Yu. Kukushkin, Maxim L. Kuznetsov, Dmitrii A. Garnovskii, Giovanni Natile, and Armando J. L. Pombeiro pp 2041 - 2053; DOI: 10.1021/ic011025h |
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Electronic Excited States of [Au2(dmpm)3](ClO4)2 (dmpm= bis(dimethylphosphine)methane) King Hung Leung, David Lee Phillips, Zhong Mao, Chi-Ming Che, Vincent M. Miskowski, and Chi-Keung Chan pp 2054 - 2059; DOI: 10.1021/ic011084v |
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De Novo Structural Prediction of Transition Metal Complexes: Application to Technetium Corneliu Buda, Stanley K. Burt, Thomas R. Cundari, and Peter S. Shenkin pp 2060 - 2069; DOI: 10.1021/ic0109748 |
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Arsenic(III) Halide Complexes with Acyclic and Macrocyclic Thio- and Selenoether Coligands: Synthesis and Structural Properties Nicholas J. Hill, William Levason, and Gillian Reid pp 2070 - 2076; DOI: 10.1021/ic011139t |
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Metal Complexes of Tetrapodal Ligands: Synthesis, Spectroscopic and Thermal Studies, and X-ray Crystal Structure Studies of Na(I), Ca(II), Sr(II), and Ba(II) Complexes of Tetrapodal Ligands N,N,N',N'-Tetrakis(2-hydroxypropyl)ethylenediamine and N,N,N',N'-Tetrakis(2-hydroxyethyl)ethylenediamine Geeta Hundal, Maninder Singh Hundal, Sangeeta Obrai, N. S. Poonia, and Subodh Kumar pp 2077 - 2086; DOI: 10.1021/ic0100727 |
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Syntheses and Characterizations of Three-Dimensional Channel-like Polymeric Lanthanide Complexes Constructed by 1,2,4,5-Benzenetetracarboxylic Acid Rong Cao, Daofeng Sun, Yucang Liang, Maochun Hong, Kazuyuki Tatsumi, and Qian Shi pp 2087 - 2094; DOI: 10.1021/ic0110124 |
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Cationic Complexes of Iridium: Diiodobenzene Chelation, Electrophilic Behavior with Olefins, and Fluxionality of an Ir(I) Ethylene Complex Paul J. Albietz, Jr., Brian P. Cleary, Witold Paw, and Richard Eisenberg pp 2095 - 2108; DOI: 10.1021/ic025506s |
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Organic-Inorganic Hybrid Materials: Hydrothermal Syntheses and Structural Characterization of Bimetallic Organophosphonate Oxides of the Type Mo/Cu/O/RPO32-/Organoimine Robert C. Finn, Randy S. Rarig, Jr., and Jon Zubieta pp 2109 - 2123; DOI: 10.1021/ic011124v |
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Ligand Influences on Copper Molybdate Networks: The Structures and Magnetism of [Cu(3,4'-bpy)MoO4], [Cu(3,3'-bpy)0.5MoO4], and [Cu(4,4'-bpy)0.5MoO4]·1.5H2O Randy S. Rarig, Jr., Robert Lam, Peter Y. Zavalij, J. Katana Ngala, Robert L. LaDuca, Jr., John E. Greedan, and Jon Zubieta pp 2124 - 2133; DOI: 10.1021/ic0111536 |
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Intercalated Organic-Inorganic Perovskites Stabilized by Fluoroaryl-Aryl Interactions David B. Mitzi, David R. Medeiros, and Patrick R. L. Malenfant pp 2134 - 2145; DOI: 10.1021/ic011190x |
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Synthesis, Structure, and Bonding of Sc6MTe2 (M = Ag, Cu, Cd): Heterometal-Induced Polymerization of Metal Chains in Sc2Te Ling Chen and John D. Corbett pp 2146 - 2150; DOI: 10.1021/ic0112544 |
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A Hybrid Consisting of Coordination Polymer and Noncovalent Organic Networks: A Highly Ordered 2-D Phenol Network Assembled by Edge-to-Face - Interactions Jung Woo Ko, Kil Sik Min, and Myunghyun Paik Suh pp 2151 - 2157; DOI: 10.1021/ic011281u |
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Pulse Radiolysis Studies on Galactose Oxidase Christopher D. Borman, Craig Wright, Mark B. Twitchett, G. Arthur Salmon, and A. Geoffrey Sykes pp 2158 - 2163; DOI: 10.1021/ic0109344 |
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Chemical Bonding in Hypervalent Molecules: Is the Octet Rule Relevant? Stéphane Noury, Bernard Silvi, and Ronald J. Gillespie pp 2164 - 2172; DOI: 10.1021/ic011003v |
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Structure of the Deoxymyoglobin Model [Fe(TPP)(2-MeHIm)] Reveals Unusual Porphyrin Core Distortions Mary K. Ellison, Charles E. Schulz, and W. Robert Scheidt pp 2173 - 2181; DOI: 10.1021/ic020012g |
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Peripherally Metalated Secoporphyrazines: A New Generation of Photoactive Pigments Efstathia G. Sakellariou, Antonio Garrido Montalban, Hubert G. Meunier, Garry Rumbles, David Phillips, Richard B. Ostler, Klaus Suhling, Anthony G. M. Barrett, and Brian M. Hoffman pp 2182 - 2187; DOI: 10.1021/ic0111583 |
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Synthesis, Crystal Structure, and Magnetic Properties of the First Nonanuclear Lanthanide(III)-Copper(II) Complexes of Macrocyclic Oxamide [NaLn2Cu6] (Macrocyclic Oxamide = 1,4,8,11-Tetraazacyclotradecanne-2,3-dione, Ln = Pr, Nd) Jin-Kui Tang, Yi-Zhi Li, Qing-Lun Wang, En-Qing Gao, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, Peng Cheng, Liu-Fang Wang, and Geng-Lin Wang pp 2188 - 2192; DOI: 10.1021/ic010674q |
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Theoretical Investigation of the Spin Exchange Interactions and Magnetic Properties of the Homometallic Ludwigite Fe3O2BO3 M.-H. Whangbo, H.-J. Koo, J. Dumas, and M. A. Continentino pp 2193 - 2201; DOI: 10.1021/ic010956q |
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Discontinuum between a Thiolate and a Thiol Ligand Danny G. McGuire, Masood A. Khan, and Michael T. Ashby pp 2202 - 2208; DOI: 10.1021/ic011096g |
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A Bis-Acetonitrile Two-Coordinate Copper(I) Complex: Synthesis and Characterization of Highly Soluble B(C6F5)4- Salts of [Cu(MeCN)2]+ and [Cu(MeCN)4]+ Hong-Chang Liang, Eunsuk Kim, Christopher D. Incarvito, Arnold L. Rheingold, and Kenneth D. Karlin pp 2209 - 2212; DOI: 10.1021/ic010816g |
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Design and Analysis of Chain and Network Structures from Organic Derivatives of Polyoxometalate Clusters Bret J. S. Johnson, Rick C. Schroden, Changcheng Zhu, Victor G. Young, Jr., and Andreas Stein pp 2213 - 2218; DOI: 10.1021/ic010820s |
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Synthesis and Structural Characterization of Trinuclear CuII-Pyrazolato Complexes Containing 3-OH, 3-O, and 3-Cl Ligands. Magnetic Susceptibility Study of [PPN]2[(3-O)Cu3(-pz)3Cl3] Panagiotis A. Angaridis, Peter Baran, R. Bo  a, Francisco Cervantes-Lee, W. Haase, Gellert Mezei, Raphael G. Raptis, and R. Wernerpp 2219 - 2228; DOI: 10.1021/ic010670l |
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Synthesis, Characterization, and Chiral Behavior of S-Bridged CoIIIPtIICoIII Trinuclear Complexes Composed of Bis(thiolato)-Type Octahedral Units cis(S)-[Co(aet)2(en)]+ and/or trans(N)-[Co(D-pen- N,O,S)2]- (aet = 2-Aminoethanethiolate, D-PEN = D-Penicillaminate) Hirokazu Honda, Takashi Yoshimura, Masakazu Hirotsu, Tatsuya Kawamoto, and Takumi Konno pp 2229 - 2237; DOI: 10.1021/ic010696c |
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Distribution and Dynamics of Hydrogen in the Low-Temperature Phase of Mg2NiH4 Studied by Solid-State NMR Shigenobu Hayashi pp 2238 - 2242; DOI: 10.1021/ic0106367 |
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Mononuclear and Mixed-Valence Binuclear Oxovanadium Complexes with Benzimidazole-Derived Chelating Agents Shyamali Ghosh, Kausik K. Nanda, Anthony W. Addison, and Raymond J. Butcher pp 2243 - 2249; DOI: 10.1021/ic010945x |
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RuII Electron Transfer Systems Containing S-Donor Ligands Cordélia S. Araújo, Michael G. B. Drew, Vítor Félix, Lorna Jack, João Madureira, Mike Newell, Sue Roche, Teresa M. Santos, Jim A. Thomas, and Lesley Yellowlees pp 2250 - 2259; DOI: 10.1021/ic010882i |
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Stabilization of the P(CF3)2- Ion as a Reversible CS2 Adduct, [P(CF3)2CS2]-, and Its Potential Use as a Nucleophilic P(CF3)2- Source: Synthesis and Structure of [18-Crown-6-K][P(C6F5)2CS2] Berthold Hoge, Christoph Thösen, Tobias Herrmann, and Ingo Pantenburg pp 2260 - 2265; DOI: 10.1021/ic0112950 |
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Kinetics and Mechanism of Rhenium-Catalyzed Oxygen Atom Transfer from Pyridine N-Oxides to Phosphines Ying Wang and James H. Espenson pp 2266 - 2274; DOI: 10.1021/ic0112995 |
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Synthesis, Structures, and Emissive Properties of Platinum(II) Complexes with a Cyclometallating Aryldiamine Ligand Hershel Jude, Jeanette A. Krause Bauer, and William B. Connick pp 2275 - 2281; DOI: 10.1021/ic0108991 |
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Biomimetic Studies of Terminal Oxidases: Trisimidazole Picket Metalloporphyrins James P. Collman, Christopher J. Sunderland, and Roman Boulatov pp 2282 - 2291; DOI: 10.1021/ic011191p |
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KBa2InAs3 with Coexisting Monomers of [In2As7]13- and Their One-Dimensional Polymers Franck Gascoin and Slavi C. Sevov pp 2292 - 2295; DOI: 10.1021/ic011261s |
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Unique 2:1 Complex with a trans-Chelating Bis-Pyridine Ligand Yi-Zhen Hu, Charles Chamchoumis, Janusz S. Grebowicz, and Randolph P. Thummel pp 2296 - 2300; DOI: 10.1021/ic010965z |
Issue 9
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Multiple Reactions of Triphenylstannane with Ru5(CO)12(C6H6)(5-C) Yield Bimetallic Clusters with Unusually Large Numbers of Tin Ligands Richard D. Adams, Burjor Captain, Wei Fu, and Mark D. Smith pp 2302 - 2303; DOI: 10.1021/ic011321u |
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Hydrothermal Synthesis and Structure of a New One-Dimensional, Mixed-Metal U(VI) Iodate, Cs2[(UO2)(CrO4)(IO3)2] Richard E. Sykora, Daniel M. Wells, and Thomas E. Albrecht-Schmitt pp 2304 - 2306; DOI: 10.1021/ic020055x |
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Oxygen Reactivity of a Nickel(II)-Polyoximate Complex Michael J. Goldcamp, Sara E. Robison, Jeanette A. Krause Bauer, and Michael J. Baldwin pp 2307 - 2309; DOI: 10.1021/ic015590w |
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Single Crystal Structure Determination of a New Zirconium N-Ethylpyridinium Phosphonate: Zr(O3PCH2CH2NC5H5)(F-)3 Lori A. Vermeulen, Rasheta Z. Fateen, and Paul D. Robinson pp 2310 - 2312; DOI: 10.1021/ic015614z |
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New Insights into the Effects of Self-Association of the Cation [Au{C(NHMe)2}2]+ on Its Solid State Structure and Luminescence Rochelle L. White-Morris, Marilyn M. Olmstead, Feilong Jiang, and Alan L. Balch pp 2313 - 2315; DOI: 10.1021/ic020030y |
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Low-Temperature Synthesis of Uranium Tetraboride by Solid-State Metathesis Reactions Anthony J. Lupinetti, Julie L. Fife, Eduardo Garcia, Peter K. Dorhout, and Kent D. Abney pp 2316 - 2318; DOI: 10.1021/ic015607a |
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Metal Carboxylate-Phosphonate Hybrid Layered Compounds: Synthesis and Single Crystal Structures of Novel Divalent Metal Complexes with N-(Phosphonomethyl)iminodiacetic Acid Jiang-Gao Mao and Abraham Clearfield pp 2319 - 2324; DOI: 10.1021/ic011094w |
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Complexes Formed between Nitrilotris(methylenephosphonic acid) and M2+ Transition Metals: Isostructural Organic-Inorganic Hybrids Aurelio Cabeza, Xiang Ouyang, C. V. Krishnamohan Sharma, Miguel A. G. Aranda, Sebastian Bruque, and Abraham Clearfield pp 2325 - 2333; DOI: 10.1021/ic0110373 |
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Synthesis, Characterization, and Crystal Structures of Two Divalent Metal Diphosphonates with a Layered and a 3D Network Structure Jiang-Gao Mao, Zhike Wang, and Abraham Clearfield pp 2334 - 2340; DOI: 10.1021/ic011202e |
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Magnetic Coupling and Intermetallic Electron Transfer in the Heterodinuclear Bioctahedral Complexes MWIIICl9n- (M = VII, CrIII, MnIV): Tweaking the Balance between Ferromagnetism and Antiferromagnetism Simon Petrie and Robert Stranger pp 2341 - 2347; DOI: 10.1021/ic0109703 |
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Dinuclear Rhodium and Iridium Complexes with Mixed Amido/Methoxo and Amido/Hydroxo Bridges Cristina Tejel, Miguel A. Ciriano, Marta Bordonaba, José A. López, Fernando J. Lahoz, and Luis A. Oro pp 2348 - 2355; DOI: 10.1021/ic0109952 |
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Apical versus Equatorial Disposition of Substituents in Tetraoxyphosphoranes Bearing a 1,3,2-Dioxaphosphocin Ring: Implications on Apicophilicity in Trigonal Bipyramidal Phosphorus Praveen Kommana, Sudha Kumaraswamy, J. J. Vittal, and K. C. Kumara Swamy pp 2356 - 2363; DOI: 10.1021/ic010935w |
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Lattice Potential Energy Estimation for Complex Ionic Salts from Density Measurements H. Donald Brooke Jenkins, David Tudela, and Leslie Glasser pp 2364 - 2367; DOI: 10.1021/ic011216k |
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Thermodynamic and Kinetic Control over the Reduction Mechanism of the Pd3(dppm)3(CO)(I)+ Cluster Frédéric Lemaître, David Brevet, Dominique Lucas, Alain Vallat, Yves Mugnier, and Pierre D. Harvey pp 2368 - 2373; DOI: 10.1021/ic0107328 |
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Reactions of AlH3·NMe3 with Nitriles: Structural Characterization and Substitution Reactions of Hexameric Aluminum Imides N. Dastagiri Reddy, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt pp 2374 - 2378; DOI: 10.1021/ic011101g |
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Thiofunctional Vanadium Complexes H. Nekola, D. Wang, C. Grüning, J. Gätjens, A. Behrens, and D. Rehder pp 2379 - 2384; DOI: 10.1021/ic011118z |
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Synthesis and Molecular Structure of [{(HBpz3)Rh(PPh3)(-Cl)2}2Ag]BF4 (Hpz = Pyrazole), a Heterotrinuclear Rh2Ag Compound with Square-Planar Silver(I) Daniel Carmona, Fernando Viguri, Fernando J. Lahoz, and Luis A. Oro pp 2385 - 2388; DOI: 10.1021/ic011217c |
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Structural and Density Functional Studies of Uranium(III) and Lanthanum(III) Complexes with a Neutral Tripodal N-Donor Ligand Suggesting the Presence of a U-N Back-Bonding Interaction Marinella Mazzanti, Raphaël Wietzke, Jacques Pécaut, Jean-Marc Latour, Pascale Maldivi, and Michael Remy pp 2389 - 2399; DOI: 10.1021/ic010839v |
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Low-Temperature UV-Visible and NMR Spectroscopic Investigations of O2 Binding to (6L)FeII, a Ferrous Heme Bearing Covalently Tethered Axial Pyridine Ligands Reza A. Ghiladi and Kenneth D. Karlin pp 2400 - 2407; DOI: 10.1021/ic0103547 |
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Photochemical Image Generation in a Cyanogel System Synthesized from Tetrachloropalladate(II) and the Trimetallic Mixed-Valence Complex [(NC)5FeII-CN-PtIV(NH3)4-NC-FeII(CN)5]4-: Consideration of Photochemical and Dark Mechanistic Pathways of Prussian Blue Formation David F. Watson, Jennifer L. Willson, and Andrew B. Bocarsly pp 2408 - 2416; DOI: 10.1021/ic010710l |
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Crystal Structure and Spectroscopic Properties of Na2K6(VO)2(SO4)7 D. A. Karydis, S. Boghosian, K. Nielsen, K. M. Eriksen, and R. Fehrmann pp 2417 - 2421; DOI: 10.1021/ic011156i |
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Reactivity of [Re{3-H(-H)B(timMe)2}(CO)3] (timMe = 2-Mercapto-1-methylimidazolyl) toward Neutral Substrates Raquel Garcia, Ângela Domingos, António Paulo, Isabel Santos, and Roger Alberto pp 2422 - 2428; DOI: 10.1021/ic011171n |
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In2(OH)3(BDC)1.5 (BDC = 1,4-Benzendicarboxylate): An In(III) Supramolecular 3D Framework with Catalytic Activity B. Gomez-Lor, E. Gutiérrez-Puebla, M. Iglesias, M. A. Monge, C. Ruiz-Valero, and N. Snejko pp 2429 - 2432; DOI: 10.1021/ic0111482 |
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Synthesis, Characterization, and Reactivity of Mononuclear O,N-Chelated Vanadium(IV) and -(III) Complexes of Methyl 2-Aminocyclopent-1-ene-1-dithiocarboxylate Based Ligand: Reporting an Example of Conformational Isomerism in the Solid State Sudeep Bhattacharyya, Suman Mukhopadhyay, Satyabrata Samanta, Timothy J. R. Weakley, and Muktimoy Chaudhury pp 2433 - 2440; DOI: 10.1021/ic0108639 |
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Tetranuclear Manganese Complexes with Dimer-of-Dimer and Ladder Structures from the Use of a Bis-Bipyridyl Ligand E. Carolina Sañudo, Vincent A. Grillo, Michael J. Knapp, John C. Bollinger, John C. Huffman, David N. Hendrickson, and George Christou pp 2441 - 2450; DOI: 10.1021/ic011262k |
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Parahydrogen Induced Polarization and the Oxidative Addition of Hydrogen to Iridium Tribromostannyl Carbonylate Anions Alexei Permin and Richard Eisenberg pp 2451 - 2458; DOI: 10.1021/ic015621n |
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Highly Luminescent, Visible-Emitting Lanthanide Macrocyclic Chelates Stable in Water and Derived from the Cyclen Framework Gaël Zucchi, Anne-Claire Ferrand, Rosario Scopelliti, and Jean-Claude G. Bünzli pp 2459 - 2465; DOI: 10.1021/ic011121i |
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The Lengths of Molybdenum to Molybdenum Quadruple Bonds: Correlations, Explanations, and Corrections F. Albert Cotton, Lee M. Daniels, Elizabeth A. Hillard, and Carlos A. Murillo pp 2466 - 2470; DOI: 10.1021/ic025508c |
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Dinuclear Ruthenium(II) Polypyridyl Complexes Containing Large, Redox-Active, Aromatic Bridging Ligands: Synthesis, Characterization, and Intramolecular Quenching of MLCT Excited States Mahn-Jong Kim, Rama Konduri, Hongwei Ye, Frederick M. MacDonnell, Fausto Puntoriero, Scolastica Serroni, Sebastiano Campagna, Tina Holder, Gary Kinsel, and Krishnan Rajeshwar pp 2471 - 2476; DOI: 10.1021/ic011028u |
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Reactions of Trivacant Wells-Dawson Heteropolytungstates. Ionic Strength and Jahn-Teller Effects on Formation in Multi-Iron Complexes Travis M. Anderson, Xuan Zhang, Kenneth I. Hardcastle, and Craig L. Hill pp 2477 - 2488; DOI: 10.1021/ic0112443 |
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Structure and Magnetism of Heptanuclear Complexes Formed on Encapsulation of Hexacyanoferrate(II) with the Mn(II) and Ni(II) Complexes of 1,4-Bis(2-pyridylmethyl)-1,4,7-triazacyclononane Richard J. Parker, Leone Spiccia, Boujemaa Moubaraki, Keith S. Murray, David C. R. Hockless, A. David Rae, and Anthony C. Willis pp 2489 - 2495; DOI: 10.1021/ic010711d |
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Structure and Bonding in the Aluminum Radical Species Al·NH3, HAlNH2, HAlNH2·NH3, and Al(NH2)2 Studied by Means of Matrix IR Spectroscopy and Quantum Chemical Calculations Benjamin Gaertner and Hans-Jörg Himmel pp 2496 - 2504; DOI: 10.1021/ic011292n |
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Charge Transfer of Iron(III) Monomeric and Oligomeric Aqua Hydroxo Complexes: Semiempirical Investigation into Photoactivity Ludovic Lopes, Joseph de Laat, and Bernard Legube pp 2505 - 2517; DOI: 10.1021/ic011029m |
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Structure and Photochemistry of Nitrocobalt(III) Tetraphenylporphyrin with Axial Triphenylphosphine in Toluene Solutions Haruna Adachi, Hiroyuki Suzuki, Yoshio Miyazaki, Yasuhiro Iimura, and Mikio Hoshino pp 2518 - 2524; DOI: 10.1021/ic0108686 |
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Reactions of Hydroxymesitylboranes with Metal Alkyls: An Approach to New Sterically Hindered (Metaloxy)mesitylboranes Romana Anulewicz-Ostrowska, Sergiusz Luli ski, Edyta Pindelska, and Janusz Serwatowskipp 2525 - 2528; DOI: 10.1021/ic0112490 |
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Sterically Demanding Multidentate Ligand Tris[(2-(6-methylpyridyl))methyl]amine Slows Exchange and Enhances Solution State Ligand Proton NMR Coupling to 199Hg(II) Deborah C. Bebout, James F. Bush II, Kathleen K. Crahan, Edith V. Bowers, and Raymond J. Butcher pp 2529 - 2536; DOI: 10.1021/ic011209w |
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Electronic Structure of Diamagnetic and Paramagnetic Hexanuclear Chalcohalide Clusters of Rhenium André Deluzet, Hélène Duclusaud, Philippe Sautet, and Serguei A. Borshch pp 2537 - 2542; DOI: 10.1021/ic010789u |
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One- and Two-Dimensional Silver-Coordination Networks Containing -Sandwiched Silver-Silver Interactions Eric Bosch and Charles L. Barnes pp 2543 - 2547; DOI: 10.1021/ic010795q |
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Electrochemical and Spectral Studies of the Reactions of Aquocobalamin with Nitric Oxide and Nitrite Ion Donghong Zheng, Lei Yan, and Ronald L. Birke pp 2548 - 2555; DOI: 10.1021/ic010802a |
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Solution and Solid State Studies of a Triangle-Square Equilibrium: Anion-Induced Selective Crystallization in Supramolecular Self-Assembly Manuela Schweiger, S. Russell Seidel, Atta M. Arif, and Peter J. Stang pp 2556 - 2559; DOI: 10.1021/ic0112692 |
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Tripodal Pseudopeptides with Three Histidine or Cysteine Donors: Synthesis and Zinc Complexation Michael Gelinsky, Raphael Vogler, and Heinrich Vahrenkamp pp 2560 - 2564; DOI: 10.1021/ic011263c |
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Mechanistic Information on the Reversible Binding of NO to Selected Iron(II) Chelates from Activation Parameters Thorsten Schneppensieper, Alicja Wanat, Gra yna Stochel, and Rudi van Eldikpp 2565 - 2573; DOI: 10.1021/ic011220w |
Hydrolysis of Tin(II) Neo-pentoxide: Syntheses, Characterization, and X-ray Structures of [Sn(ONep)2] , Sn5(3-O)2(-ONep)6, and Sn6(3-O)4(-ONep)4 Where ONep = OCH2CMe3Timothy J. Boyle, Todd M. Alam, Mark A. Rodriguez, and Cecilia A. Zechmann pp 2574 - 2582; DOI: 10.1021/ic011247f |
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Synthesis and Characterization of Dimetallic Oxorhenium(V) and Dioxorhenium(VII) Compounds, and a Study of Stoichiometric and Catalytic Reactions James H. Espenson, Xiaopeng Shan, Ying Wang, Ruili Huang, David W. Lahti, JaNeille Dixon, Gábor Lente, Arkady Ellern, and Ilia A. Guzei pp 2583 - 2591; DOI: 10.1021/ic011287j |
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[CdII(bpdc)·H2O]n: A Robust, Thermally Stable Porous Framework through a Combination of a 2-D Grid and a Cadmium Dicarboxylate Cluster Chain (H2bpdc = 2,2'-Bipyridyl-4,4'-dicarboxylic Acid) Yen-Hsiang Liu, Yi-Long Lu, Huang-Chun Wu, Ju-Chun Wang, and Kuang-Lieh Lu pp 2592 - 2597; DOI: 10.1021/ic011192h |
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Mixed-Metal Supramolecular Complexes Coupling Phosphine-Containing Ru(II) Light Absorbers to a Reactive Pt(II) through Polyazine Bridging Ligands Shawn Swavey, Zhenglai Fang, and Karen J. Brewer pp 2598 - 2607; DOI: 10.1021/ic010806f |
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Reaction of Silicate Minerals To Form Tetramethoxysilane Larry N. Lewis, Florian J. Schattenmann, Tracey M. Jordan, James C. Carnahan, William P. Flanagan, Ronald J. Wroczynski, John P. Lemmon, Joseph M. Anostario, and Michelle A. Othon pp 2608 - 2615; DOI: 10.1021/ic0109546 |
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Pyridylazole Chelation of Oxorhenium(V) and Imidorhenium(V). Rates and Trends of Oxygen Atom Transfer from ReVO to Tertiary Phosphines Jaydip Gangopadhyay, Suman Sengupta, Sibaprasad Bhattacharyya, Indranil Chakraborty, and Animesh Chakravorty pp 2616 - 2622; DOI: 10.1021/ic011064t |
Issue 10
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Design and Spectroscopic Characterization of Peptide Models for the Plastocyanin Copper-Binding Loop Roxanne G. Daugherty, Tomasz Wasowicz, Brian R. Gibney, and Victoria J. DeRose pp 2623 - 2632; DOI: 10.1021/ic010555a |
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Cyclometalated Products of [(COE)2RhCl]2 and 1,3-(RSCH2)2C6H4 (R = tBu, iPr) Are Dimeric. Synthesis, Molecular Structures, and Solution Dynamics of [-ClRh(H)(RSCH2)2C6H3-2,6]2 Daniel R. Evans, Mingsheng Huang, W. Michael Seganish, Esther W. Chege, Yiu-Fai Lam, James C. Fettinger, and Tracie L. Williams pp 2633 - 2641; DOI: 10.1021/ic011189y |
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Electrochemistry and Photoelectron Spectroscopy of Oxomolybdenum(V) Complexes with Phenoxide Ligands: Effect of Para Substituents on Redox Potentials, Heterogeneous Electron Transfer Rates, and Ionization Energies Julie N. Graff, Anne E. McElhaney, Partha Basu, Nadine E. Gruhn, Chaung-Sheng J. Chang, and John H. Enemark pp 2642 - 2647; DOI: 10.1021/ic0110981 |
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Comparative Study of Structure-Properties Relationship for Novel -Halogenated Lanthanide Porphyrins and Their Nickel and Free Bases Precursors, as a Function of Number and Nature of Halogens Atoms G. A. Spyroulias, A. P. Despotopoulos, C. P. Raptopoulou, A. Terzis, D. de Montauzon, R. Poilblanc, and A. G. Coutsolelos pp 2648 - 2659; DOI: 10.1021/ic000738h |
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Statistical and Molecular Mechanics Analysis of the Effects of Changing Donor Type on Bond Length in the Two Series [CoIIINnO6-n] and [NiIINnO6-n] (n = 0-6): A New Route to Bond-Stretch Parameters Rosalie K. Hocking and Trevor W. Hambley pp 2660 - 2666; DOI: 10.1021/ic010930z |
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Synthesis, Characterization, and Structure of [{PtMe3(9-MeA)}3] (9-MeAH = 9-Methyladenine): A Cyclic Trimeric Platinum(IV) Complex with a Nucleobase Xuhui Zhu, Eduard Rusanov, Ralph Kluge, Harry Schmidt, and Dirk Steinborn pp 2667 - 2671; DOI: 10.1021/ic0110530 |
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Mechanism of Silver-Promoted Ligand Metathesis in Square-Planar Complexes of d8 Ions. Kinetics of Formation and Molecular Structures of a Trinuclear Intermediate [(Me)(N-N)Pt(-Cl)Ag(-Cl)Pt(N-N)(Me)]+ and Its Dinuclear Evolution Product [(Me)(N-N)Pt(-Cl)Pt(N-N)(Me)]+ (N-N = ArN=C(Me)C(Me)=NAr, Ar = 2,6-(i-Pr)2C6H3) Vincenzo G. Albano, Martino Di Serio, Magda Monari, Ida Orabona, Achille Panunzi, and Francesco Ruffo pp 2672 - 2677; DOI: 10.1021/ic011059p |
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Photolytic Reactions of Subvalent Aluminum(I) Halides in the Presence of Dioxygen: Generation and Characterization of the Peroxo Species XAlO2 and XAl(-O)2AlX (X = F, Cl, Br) Jan Bahlo, Hans-Jörg Himmel, and Hansgeorg Schnöckel pp 2678 - 2689; DOI: 10.1021/ic011313d |
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Mössbauer Study of the Three-Coordinate Planar FeII Thiolate Complex [Fe(SR)3]- (R = C6H2-2,4,6-tBu3): Model for the Trigonal Iron Sites of the MoFe7S9:Homocitrate Cofactor of Nitrogenase Yiannis Sanakis, Philip P. Power, Audria Stubna, and Eckard Münck pp 2690 - 2696; DOI: 10.1021/ic0111278 |
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Further Evidence for the Tetraoxoiodate(V) Anion, IO43-: Hydrothermal Syntheses and Structures of Ba[(MoO2)6(IO4)2O4]·H2O and Ba3[(MoO2)2(IO6)2]·2H2O Richard E. Sykora, Daniel M. Wells, and Thomas E. Albrecht-Schmitt pp 2697 - 2703; DOI: 10.1021/ic0112746 |
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Modeling Dioxygen-Activating Centers in Non-Heme Diiron Enzymes: Carboxylate Shifts in Diiron(II) Complexes Supported by Sterically Hindered Carboxylate Ligands Dongwhan Lee and Stephen J. Lippard pp 2704 - 2719; DOI: 10.1021/ic020186y |
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The Lacunary Polyoxoanion Synthon -P2W15O5612-: An Investigation of the Key Variables in Its Synthesis plus Multiple Control Reactions Leading to a Reliable Synthesis Brooks J. Hornstein and Richard G. Finke pp 2720 - 2730; DOI: 10.1021/ic020033a |
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Synthesis, NMR, and X-ray Crystallographic Analysis of C-Hydrazino-C-Carboxycarboranes: Versatile Ligands for the Preparation of BNCT and BNCS Agents and 99mTc Radiopharmaceuticals John F. Valliant, Oyebola O. Sogbein, Pierre Morel, Paul Schaffer, Katharina J. Guenther, and Alex D. Bain pp 2731 - 2737; DOI: 10.1021/ic0255048 |
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Synthesis and Structure of Singly Bridged and Doubly Bridged [MoFe3S4] Double Cubanes with Bidentate Phosphine Ligands Jaehong Han and Dimitri Coucouvanis pp 2738 - 2746; DOI: 10.1021/ic010913+ |
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Formation and Structure of 1:1 Complexes between Aryl Hydroxamic Acids and Vanadate at Neutral pH Jason H. Bell and R. F. Pratt pp 2747 - 2753; DOI: 10.1021/ic011193+ |
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Unusual Reactivity of Methylene Group Adjacent to Pyridine-2-Carboxamido Moiety in Iron(III) and Cobalt(III) Complexes John M. Rowland, Marilyn M. Olmstead, and Pradip K. Mascharak pp 2754 - 2760; DOI: 10.1021/ic011197e |
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Effects of Solvents on the Electron Configurations of the Low-Spin Dicyano[meso-tetrakis(2,4,6-triethylphenyl)porphyrinato]iron(III) Complex: Importance of the C-H···N Weak Hydrogen Bonding Akira Ikezaki and Mikio Nakamura pp 2761 - 2768; DOI: 10.1021/ic0108383 |
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Oxidations of Hydrocarbons by Manganese(III) Tris(hexafluoroacetylacetonate) Jasmine R. Bryant, Janelle E. Taves, and James M. Mayer pp 2769 - 2776; DOI: 10.1021/ic025541z |
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Highly Luminescent Eu3+ and Tb3+ Macrocyclic Complexes Bearing an Appended Phenanthroline Chromophore Silvio Quici, Giovanni Marzanni, Marco Cavazzini, Pier Lucio Anelli, Mauro Botta, Eliana Gianolio, Gianluca Accorsi, Nicola Armaroli, and Francesco Barigelletti pp 2777 - 2784; DOI: 10.1021/ic025543j |
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Coordination Chemistry and Reactivity of Monomeric Alkoxides and Amides of Magnesium and Zinc Supported by the Diiminato Ligand CH(CMeNC6H3-2,6-iPr2)2. A Comparative Study Malcolm H. Chisholm, Judith Gallucci, and Khamphee Phomphrai pp 2785 - 2794; DOI: 10.1021/ic020148e |
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Ab Initio Structure of the (Na2[CAl4])2 Dimer. Next Step Toward Solid Materials Containing Tetracoordinate Planar Carbon Grant D. Geske and Alexander I. Boldyrev pp 2795 - 2798; DOI: 10.1021/ic0112241 |
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Synthesis and Characterization of Uranyl Compounds with Iminodiacetate and Oxydiacetate Displaying Variable Denticity J. Jiang, M. J. Sarsfield, J. C. Renshaw, F. R. Livens, D. Collison, J. M. Charnock, M. Helliwell, and H. Eccles pp 2799 - 2806; DOI: 10.1021/ic020121v |
Issue 11
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Activation Volume Measurement for C-H Activation. Evidence for Associative Benzene Substitution at a Platinum(II) Center Joanna Procelewska, Achim Zahl, Rudi van Eldik, H. Annita Zhong, Jay A. Labinger, and John E. Bercaw pp 2808 - 2810; DOI: 10.1021/ic0201710 |
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The First Infrared Spectra and Quasirelativistic DFT Studies of the US, US2, and US3 Molecules Binyong Liang, Lester Andrews, Nina Ismail, and Colin J. Marsden pp 2811 - 2813; DOI: 10.1021/ic0255407 |
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New -Oxo Octanuclear Complexes of 3d Elements Stabilized by Dialkylcarbamato Ligands. Synthesis and X-ray Crystal and Molecular Structures Daniela Belli Dell'Amico, Consuelo Bradicich, Fausto Calderazzo, Alessandro Guarini, Luca Labella, Fabio Marchetti, and Alessandra Tomei pp 2814 - 2816; DOI: 10.1021/ic015626k |
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Two Isomeric Phosphacarboranes 2,1- and 6,1-PCB8H9, the First Representatives of the 10-Vertex closo Phosphacarborane Series Josef Holub, Mario Bakardjiev, Bohumil  tíbr, Drahomír Hnyk, Oleg L. Tok, and Bernd Wrackmeyerpp 2817 - 2819; DOI: 10.1021/ic020047g |
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Niobium-Arsenic Zintl Phases: A6NbAs5 (A = K, Rb, Cs), K6NbTlAs4, and K8NbPbAs5 with Edge-Bridged Niobium-Centered Tetrahedra of Arsenic, [NbAs4M]n- Where M = As, Tl, Pb Franck Gascoin and Slavi C. Sevov pp 2820 - 2825; DOI: 10.1021/ic020036n |
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Detection and Measurement of Noncoincidence between the Principal Axes of the g-Matrix and Zero-Field Splitting Tensor Using Multifrequency Powder EPR Spectroscopy: Application to cis-[(NH3)2Pt(1-MeU)2Cu(H2O)2](SO4)·4.5H2O (1-MeU = Monoanion of 1-Methyluracil) David Collison, David M. L. Goodgame, Michael A. Hitchman, Bernhard Lippert, Frank E. Mabbs, and Eric J. L. McInnes pp 2826 - 2833; DOI: 10.1021/ic011283e |
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Study of the Structural, Electronic, and Magnetic Properties of the Barium-Rich Iron(IV) Oxides, Ba2FeO4 and Ba3FeO5 James L. Delattre, Angelica M. Stacy, Victor G. Young, Jr., Gary J. Long, Raphaël Hermann, and Fernande Grandjean pp 2834 - 2838; DOI: 10.1021/ic0113247 |
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Catalytic Effect of Sulfoxides on the Fluxional Motion of 2,9-Dimethyl-1,10-phenanthroline in a Platinum(II) Complex: Evaluation of Steric and Electronic Contributions Raffaello Romeo, Lucia Fenech, Salvatore Carnabuci, Maria Rosaria Plutino, and Andrea Romeo pp 2839 - 2847; DOI: 10.1021/ic011206j |
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Occupancy of the Sodalite Cages in the Blue Ultramarine Pigments N. Gobeltz-Hautecoeur, A. Demortier, B. Lede, J. P. Lelieur, and C. Duhayon pp 2848 - 2854; DOI: 10.1021/ic010822c |
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Loss of Hoogsteen Pairing Ability upon N1 Adenine Platinum Binding Kathrin S. Schmidt, Jan Reedijk, Klaus Weisz, Eline M. Basilio Janke, Judit E. Sponer, Jiri Sponer, and Bernhard Lippert pp 2855 - 2863; DOI: 10.1021/ic0109602 |
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Structural Basis for Unusually Long Wavelength Charge Transfer Transitions in Complexes [MCl(ECH2CH2NMe2)(PR3)] (E = Te, Se; M = Pt, Pd): Experimental Results and TD-DFT Calculations Sandip Dey, Vimal K. Jain, Axel Knödler, Axel Klein, Wolfgang Kaim, and Stanislav Záli  pp 2864 - 2870; DOI: 10.1021/ic011210v |
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Proton Controlled Intramolecular Communication in Dinuclear Ruthenium(II) Polypyridine Complexes Cinzia Di Pietro, Scolastica Serroni, Sebastiano Campagna, Maria Teresa Gandolfi, Roberto Ballardini, Stefano Fanni, Wesley R. Browne, and Johannes G. Vos pp 2871 - 2878; DOI: 10.1021/ic0112894 |
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Synthesis, Structural Trends, and Physical and Electronic Properties of the Reduced Molybdenum Oxides R4Mo4O11 (R = Nd-Tm and Y) Containing Infinite Chains of Trans-Edge-Shared Octahedral Clusters P. Gall, N. Barrier, R. Gautier, and P. Gougeon pp 2879 - 2885; DOI: 10.1021/ic011000i |
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Dinuclear (FeII, GdIII) Complexes Deriving from Hexadentate Schiff Bases: Synthesis, Structure, and Mössbauer and Magnetic Properties Jean-Pierre Costes, Juan Modesto Clemente-Juan, Françoise Dahan, Frédéric Dumestre, and Jean-Pierre Tuchagues pp 2886 - 2891; DOI: 10.1021/ic0112793 |
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Crown Ether Appended Cyclam Receptors for Cationic Guests Paul V. Bernhardt and Elizabeth J. Hayes pp 2892 - 2902; DOI: 10.1021/ic011232h |
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Supramolecular Assemblies of Dimetal Complexes with Polydentate N-Donor Ligands: From a Discrete Pyramid to a 3D Channel Network F. Albert Cotton, Evgeny V. Dikarev, Marina A. Petrukhina, Marion Schmitz, and Peter J. Stang pp 2903 - 2908; DOI: 10.1021/ic020051s |
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Experimental Studies of Light-Induced Charge Transfer and Charge Redistribution in (X2-Bipyridine)ReI(CO)3Cl Complexes Keith A. Walters, Young-Jin Kim, and Joseph T. Hupp pp 2909 - 2919; DOI: 10.1021/ic011015g |
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Synthesis and Characterization of an Air-Stable Gallium Hydride, [t-Bu(H)Ga(-NEt2)]2, and Related Chloride Derivatives Luke Grocholl, Scott A. Cullison, Jianjun Wang, Dale C. Swenson, and Edward G. Gillan pp 2920 - 2926; DOI: 10.1021/ic011278a |
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Solvation Largely Accounts for the Effect of N-Alkylation on the Properties of Nickel(II/I) and Chromium(III/II) Cyclam Complexes Timothy Clark, Matthias Hennemann, Rudi van Eldik, and Dan Meyerstein pp 2927 - 2935; DOI: 10.1021/ic0113193 |
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Novel Vanadium(V) Compounds with a Layer Structure: Synthesis, Crystal Structures, and Solid State NMR Spectroscopy of [(VO2)2(4,4'-bpy)0.5(4,4'-Hbpy)(XO4)]·H2O (X = P and As) Li-Hsun Huang, Hsien-Ming Kao, and Kwang-Hwa Lii pp 2936 - 2940; DOI: 10.1021/ic0111841 |
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Density Functional Theory Calculations of Selected Ru(II) Two Ring Diimine Complex Dications Stanislav R. Stoyanov, John M. Villegas, and D. P. Rillema pp 2941 - 2945; DOI: 10.1021/ic0110629 |
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Spontaneous Assembly of a Polymeric Helicate of Sodium with LVO2 Units Forming the Strand: Photoinduced Transformation into a Mixed-Valence Product Subodh Kanti Dutta, Satyabrata Samanta, Suman Mukhopadhyay, Pannee Burckel, A. Alan Pinkerton, and Muktimoy Chaudhury pp 2946 - 2952; DOI: 10.1021/ic011311t |
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From 2D Framework to Quasi-1D Nanomaterial: Preparation, Characterization, and Formation Mechanism of Cu3SnS4 Nanorods Yujie Xiong, Yi Xie, Guoan Du, and Huilan Su pp 2953 - 2959; DOI: 10.1021/ic0200242 |
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Ruthenium Dihydride Complexes: NMR Studies of Intramolecular Isomerization and Fluxionality Including the Detection of Minor Isomers by Parahydrogen-Induced Polarization Daniele Schott, Christopher J. Sleigh, John P. Lowe, Simon B. Duckett, Roger J. Mawby, and Martin G. Partridge pp 2960 - 2970; DOI: 10.1021/ic011255w |
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Characterization of the {Ag(dmb)2+}n Oligomers (dmb = 1,8-Diisocyano-p-menthane) in Solution Martin Turcotte and Pierre D. Harvey pp 2971 - 2974; DOI: 10.1021/ic025522p |
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Kinetics and Mechanisms of the Ozone/Bromite and Ozone/Chlorite Reactions Jeffrey S. Nicoson, Lu Wang, Robert H. Becker, Kara E. Huff Hartz, Charles E. Muller, and Dale W. Margerum pp 2975 - 2980; DOI: 10.1021/ic011301s |
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Novel Reactivity Mode of Hydroxamic Acids: A Metalla-Pinner Reaction Konstantin V. Luzyanin, Vadim Yu. Kukushkin, Maxim L. Kuznetsov, Dmitrii A. Garnovskii, Matti Haukka, and Armando J. L. Pombeiro pp 2981 - 2986; DOI: 10.1021/ic025554c |
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Reactions of Amides with Organoaluminum Compounds: Factors Affecting the Coordination Mode of Aluminum Amidates Bor-Hunn Huang, Te-Liang Yu, Yi-Lun Huang, Bao-Tsan Ko, and Chu-Chieh Lin pp 2987 - 2994; DOI: 10.1021/ic011072+ |
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Large Effects of Ion Pairing and Protonic-Hydridic Bonding on the Stereochemistry and Basicity of Crown-, Azacrown-, and Cryptand-222-potassium Salts of Anionic Tetrahydride Complexes of Iridium(III) Shaun E. Landau, Kai E. Groh, Alan J. Lough, and Robert H. Morris pp 2995 - 3007; DOI: 10.1021/ic0255149 |
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A Convergent Synthetic Approach Using Sterically Demanding Aryldipyrrylmethanes for Tuning the Pocket Sizes of Cofacial Bisporphyrins Christopher J. Chang, Yongqi Deng, Shie-Ming Peng, Gene-Hsiang Lee, Chen-Yu Yeh, and Daniel G. Nocera pp 3008 - 3016; DOI: 10.1021/ic025507k |
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Synthesis and Characterization of Redox-Active Coordination Polymers Generated from Ferrocene-Containing Bridging Ligands Ryo Horikoshi, Tomoyuki Mochida, and Hiroshi Moriyama pp 3017 - 3024; DOI: 10.1021/ic011176k |
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Intramolecular Electronic Energy Transfer in Bichromophoric Macrocyclic Complexes Paul V. Bernhardt, Evan G. Moore, and Mark J. Riley pp 3025 - 3031; DOI: 10.1021/ic0255306 |
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New N3S Donor Ligand Small Peptide Analogues of the N-Mercaptoacetyl-glycylglycylglycine Ligand in the Clinically Used Tc-99m Renal Imaging Agent: Evidence for Unusual Amide Oxygen Coordination by Two New Ligands Malgorzata Lipowska, Lory Hansen, Xiaolong Xu, Patricia A. Marzilli, Andrew Taylor, Jr., and Luigi G. Marzilli pp 3032 - 3041; DOI: 10.1021/ic011325z |
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Influence of Filled d-Manifold and L/L' Ligands on the Structure, Basicity, and Bond Rotations of the Octahedral and d6 Amido Complexes TpRu(L)(L')(NHPh) (Tp = Hydridotris(pyrazolyl)borate; L = L' = PMe3 or P(OMe)3, or L = CO and L' = PPh3): Solid-State Structures of [TpRu(PMe3)2(NH2Ph)][OTf], [TpRu{P(OMe)3}2(NH2Ph)][OTf], and TpRu{P(OMe)3}2(NHPh) David Conner, K. N. Jayaprakash, T. Brent Gunnoe, and Paul D. Boyle pp 3042 - 3049; DOI: 10.1021/ic020163j |
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Contribution of the nido-[7,8-C2B9H10]- Anion to the Chemical Stability, Basicity, and 31P NMR Chemical Shift in nido-o-Carboranylmonophosphines Francesc Teixidor, Rosario Núñez, Clara Viñas, ReijoSillanpää, and Raikko Kivekäs: pp 3050 - 3050; DOI: 10.1021/ic0202357 |
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Jack Y. Lu, Karren A. Runnels, and Christine Norman: A NewMetal-Organic Polymer with Large Grid Acentric Structure Created by Unbalanced Inclusion Species and Its Electrospun Nanofibers pp 3050 - 3050; DOI: 10.1021/ic020267u |
Issue 12
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Giant Metal-Cyanide Coordination Clusters: Tetracapped Edge-Bridged Cubic Cr12Ni12(CN)48 and Double Face-Centered Cubic Cr14Ni13(CN)48 Species Jennifer J. Sokol, Matthew P. Shores, and Jeffrey R. Long pp 3052 - 3054; DOI: 10.1021/ic0255499 |
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Synthesis and Characterization of Phosphorescent Cyclometalated Platinum Complexes Jason Brooks, Yelizaveta Babayan, Sergey Lamansky, Peter I. Djurovich, Irina Tsyba, Robert Bau, and Mark E. Thompson pp 3055 - 3066; DOI: 10.1021/ic0255508 |
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Chemical Vapor Deposition of Gallium Nitride from the GaCl3+NH3 System. Theoretical Study of the Structure and Thermodynamics of Potential Intermediates Formed in the Gaseous Phase Attila Kovács pp 3067 - 3075; DOI: 10.1021/ic011140s |
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Kinetic Study of the Oxidation of Catechol by Aqueous Copper(II) P. Kamau and R. B. Jordan pp 3076 - 3083; DOI: 10.1021/ic010978c |
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Synthesis and Reactivity of 1,2-Bis(chlorodimethylgermyl)carborane and 1,2-Bis(bromodimethylstannyl)carborane Chongchan Lee, Junghyun Lee, Soon W. Lee, Sang Ook Kang, and Jaejung Ko pp 3084 - 3090; DOI: 10.1021/ic0110878 |
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Interpretation of Indirect Nuclear Spin-Spin Coupling Tensors for Polyatomic Xenon Fluorides and Group 17 Fluorides: Results from Relativistic Density-Functional Calculations David L. Bryce and Roderick E. Wasylishen pp 3091 - 3101; DOI: 10.1021/ic020025u |
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Structural, Spectroscopic, and Reactivity Comparison of Xanthene- and Dibenzofuran-Bridged Cofacial Bisporphyrins Christopher J. Chang, Erin A. Baker, Bradford J. Pistorio, Yongqi Deng, Zhi-Heng Loh, Scott E. Miller, Scott D. Carpenter, and Daniel G. Nocera pp 3102 - 3109; DOI: 10.1021/ic0111029 |
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Steric Control of Substituted Phenoxide Ligands on Product Structures of Uranyl Aryloxide Complexes Marianne P. Wilkerson, Carol J. Burns, David E. Morris, Robert T. Paine, and Brian L. Scott pp 3110 - 3120; DOI: 10.1021/ic011080q |
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Site-Selective EXAFS in Mixed-Valence Compounds Using High-Resolution Fluorescence Detection: A Study of Iron in Prussian Blue Pieter Glatzel, Lilian Jacquamet, Uwe Bergmann, Frank M. F. de Groot, and Stephen P. Cramer pp 3121 - 3127; DOI: 10.1021/ic010709m |
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Enhancing Reactivity via Structural Distortion Dirk Schweitzer, Jason Shearer, Durrell K. Rittenberg, Steven C. Shoner, Jeffrey J. Ellison, Reza Loloee, Scott Lovell, David Barnhart, and Julie A. Kovacs pp 3128 - 3136; DOI: 10.1021/ic0109187 |
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Substitution Reactions of [Ru(dppe)(CO)(H2O)3][OTf]2 Matthew D. Hargreaves, Mary F. Mahon, and Michael K. Whittlesey pp 3137 - 3145; DOI: 10.1021/ic020029z |
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Linear Heterotrinuclear Complexes Derived from an Alkyl Platinum(II) Twelve-Membered Macrocycle Hai-Bin Song, Zheng-Zhi Zhang, Zheng Hui, Chi-Ming Che, and Thomas C. W. Mak pp 3146 - 3154; DOI: 10.1021/ic011293f |
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Excited State Properties of Mixed Phosphine 2-(2'-Pyridyl)quinoline Complexes of Ruthenium(II) David M. Klassen and Rudi V. DelPup pp 3155 - 3160; DOI: 10.1021/ic010846j |
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Syntheses of Ruthenium(II) Quinonediimine Complexes of Cyclam and Characterization of Their DNA-Binding Activities and Cytotoxicity Hing-Leung Chan, Heng-Qian Liu, Biing-Chiau Tzeng, Yuan-Shyane You, Shie-Ming Peng, Mengsu Yang, and Chi-Ming Che pp 3161 - 3171; DOI: 10.1021/ic0112802 |
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Structural and Spectroscopic Studies of Valence-Delocalized Diiron(II,III) Complexes Supported by Carboxylate-Only Bridging Ligands Dongwhan Lee, Jennifer L. DuBois, Brad Pierce, Britt Hedman, Keith O. Hodgson, Michael P. Hendrich, and Stephen J. Lippard pp 3172 - 3182; DOI: 10.1021/ic011050n |
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Metal Ion Scrambling in Hexanuclear M6(Et2NCO2)12 Complexes (M = Co, Mg). Synthesis, Solid State Structure, and Solution Dynamics of Heteronuclear ConMg6-n(Et2NCO2)12 Complexes M. Tyler Caudle, Jason B. Benedict, Charles K. Mobley, Nicholas A. Straessler, and Thomas L. Groy pp 3183 - 3190; DOI: 10.1021/ic025604d |
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High-Nuclearity Sulfide-Rich Molybdenum-Iron-Sulfur Clusters: Reevaluation and Extension Hong-Cai Zhou, Weiping Su, Catalina Achim, P. Venkateswara Rao, and R. H. Holm pp 3191 - 3201; DOI: 10.1021/ic0201250 |
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Unprecedented Cage-Carbon to Cage-Boron NMe3 Transfer in a Monocarbon Molybdenacarborane Shaowu Du, Jason A. Kautz, Thomas D. McGrath, and F. Gordon A. Stone pp 3202 - 3211; DOI: 10.1021/ic020091w |
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Synthesis and Crystal Structures of (Fulvalene)W2(SH)2(CO)6, (Fulvalene)W2(-S2)(CO)6, and (Fulvalene)W2(-S)(CO)6: Low Valent Tungsten Carbonyl Sulfide and Disulfide Complexes Stabilized by the Bridging Fulvalene Ligand Kenneth B. Capps, Glenn D. Whitener, Andreas Bauer, Khalil A. Abboud, Ian M. Wasser, K. Peter C. Vollhardt, and Carl D. Hoff pp 3212 - 3217; DOI: 10.1021/ic025590b |
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Diverse Evolution of [{Ph2P(CH2)nPPh2}Pt(-S)2Pt{Ph2P(CH2)nPPh2}] (n = 2, 3) Metalloligands in CH2Cl2 Rubén Mas-Ballesté, Mercè Capdevila, Paul A. Champkin, William Clegg, Robert A. Coxall, Agustí Lledós, Claire Mégret, and Pilar González-Duarte pp 3218 - 3229; DOI: 10.1021/ic0107173 |
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Magnetic Molecular Conductors Based on BETS Molecules and Divalent Magnetic Anions [BETS = Bis(ethylenedithio)tetraselenafulvalene] Emiko Fujiwara, Victor Gritsenko, Hideki Fujiwara, Itaru Tamura, Hayao Kobayashi, Madoka Tokumoto, and Akiko Kobayashi pp 3230 - 3238; DOI: 10.1021/ic011160u |
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Study of pH-Dependent Zinc(II)-Carboxamide Interactions by Zinc(II)-Carboxamide-Appended Cyclen Complexes (Cyclen = 1,4,7,10-Tetraazacyclododecane) Eiichi Kimura, Teruhiro Gotoh, Shin Aoki, and Motoo Shiro pp 3239 - 3248; DOI: 10.1021/ic020087k |
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Synthesis, Characterization, and Properties of Three Europium 2-Propoxides: [Eu4(OPri)10(HOPri)3]*2HOPri, Eu5O(OPri)13, and EuAl3(OPri)12 G. Westin, M. Moustiakimov, and M. Kritikos pp 3249 - 3258; DOI: 10.1021/ic010745l |
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Investigation of Silver Salt Metathesis: Preparation of Cationic Germanium(II) and Tin(II) Complexes, and Silver Adducts Containing Unsupported Silver-Germanium and Silver-Tin Bonds Ashley E. Ayers and H. V. Rasika Dias pp 3259 - 3268; DOI: 10.1021/ic0200747 |
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Cooperative Ligation, Back-Bonding, and Possible Pyridine-Pyridine Interactions in Tetrapyridine-Vanadium(II): A Visible and X-ray Spectroscopic Study Patrick Frank, Phalguni Ghosh, Keith O. Hodgson, and Henry Taube pp 3269 - 3279; DOI: 10.1021/ic011221o |
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A Mechanistic Investigation of Oxidative Addition of Methyl Iodide to [Tp*Rh(CO)(L)] Valérie Chauby, Jean-Claude Daran, Carole Serra-Le Berre, François Malbosc, Philippe Kalck, Oscar Delgado Gonzalez, Claire E. Haslam, and Anthony Haynes pp 3280 - 3290; DOI: 10.1021/ic0255959 |
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Molten-Globule and Other Conformational Forms of Zinc Cytochrome c. Effect of Partial and Complete Unfolding of the Protein on Its Electron-Transfer Reactivity Scott M. Tremain and Nenad M. Kosti pp 3291 - 3301; DOI: 10.1021/ic010893b |
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Hydrothermal Synthesis, Structures, and Magnetic Properties of Three Novel 5-Aminoisophthalic Acid Ligand Bridged Transition Metal Cation Polymers Chuan-De Wu, Can-Zhong Lu, Wen-Bin Yang, Hong-Hui Zhuang, and Jin-Shun Huang pp 3302 - 3307; DOI: 10.1021/ic011182g |
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Magnetic Ordering in the Rare Earth Molecule-Based Magnets, Ln(TCNE)3 (Ln = Gd, Dy; TCNE = Tetracyanoethylene) James W. Raebiger and Joel S. Miller pp 3308 - 3312; DOI: 10.1021/ic0201093 |
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Synthesis and Structural Characterization of Cu(I) and Ni(II) Complexes that Contain the Bis[2-(diphenylphosphino)phenyl]ether Ligand. Novel Emission Properties for the Cu(I) Species Shan-Ming Kuang, Douglas G. Cuttell, David R. McMillin, Phillip E. Fanwick, and Richard A. Walton pp 3313 - 3322; DOI: 10.1021/ic0201809 |
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Two Chiral Coordination Polymers: Preparation and X-ray Structures of Mono(4-sulfo-L-phenylalanine)(diaqua) Zinc(II) and Copper(II) Complexes Yong-Rong Xie, Ren-Gen Xiong, Xiang Xue, Xue-Tai Chen, Ziling Xue, and Xiao-Zeng You pp 3323 - 3326; DOI: 10.1021/ic010862g |
Issue 13
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A Novel Coordination Polymer Containing Both Interdigitated 1D Chains and Interpenetrated 2D Grids Ponnaiyan Ayyappan, Owen R. Evans, and Wenbin Lin pp 3328 - 3330; DOI: 10.1021/ic025524+ |
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Synthesis and DNA-Binding Properties of Cationic 2,2':6',2' '-Terpyridineplatinum(II) Complexes Containing 1,2- and 1,7-Dicarba-closo-dodecaborane(12) Jean A. Todd and Louis M. Rendina pp 3331 - 3333; DOI: 10.1021/ic025536v |
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Metal Oxidation Promoted C-H Activation in Manganese Complexes of N-Confused Porphyrin D. Scott Bohle, Wan-Chin Chen, and Chen-Hsiung Hung pp 3334 - 3336; DOI: 10.1021/ic025573m |
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Synthesis and Characterization of Technetiumtetrakis(acetonitrile)bis(triphenylphosphine) Cationic Complexes Evan Freiberg, William M. Davis, Alan Davison, and Alun G. Jones pp 3337 - 3339; DOI: 10.1021/ic020017d |
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Flexibility in the Coordination Chemistry of the 2,3-Dimethylindolide Ligand with Potassium, Yttrium, and Samarium William J. Evans, Jason C. Brady, and Joseph W. Ziller pp 3340 - 3346; DOI: 10.1021/ic020137l |
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Redox Potential Modulation in Mixed Sandwich Pyrrolyl/ Dicarbollide Complexes Jordi Llop, Clara Viñas, Francesc Teixidor, Lluís Victori, Raikko Kivekäs, and Reijo Sillanpää pp 3347 - 3352; DOI: 10.1021/ic011285z |
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Synthesis, Crystal Structure, and Photoelectric Properties of Re(CO)3ClL (L = 2-(1-Ethylbenzimidazol-2-yl)pyridine) Kezhi Wang, Ling Huang, Lihua Gao, Linpei Jin, and Chunhui Huang pp 3353 - 3358; DOI: 10.1021/ic0107330 |
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Synthesis of Heterometallic Bismuth/Molydenum Alkoxides and Their Behavior on Silica Surfaces Christian Limberg, Marc Hunger, Wilhelm Habicht, and Elisabeth Kaifer pp 3359 - 3365; DOI: 10.1021/ic011252j |
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Synthesis and Structural and Spectroscopic Characterization of a Complex between Co(II) and Imino-bis(methylphosphonic acid): Gaining Insight into Biologically Relevant Metal-Ion Phosphonate Interactions or Looking at a New Co(II)-Organophosphonate Material? H. Jankovics, M. Daskalakis, C. P. Raptopoulou, A. Terzis, V. Tangoulis, J. Giapintzakis, T. Kiss, and A. Salifoglou pp 3366 - 3374; DOI: 10.1021/ic011033y |
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Synthesis, Structures, and Magnetic Properties of a Series of Lanthanum(III) and Gadolinium(III) Complexes with Chelating Benzimidazole-Substituted Nitronyl Nitroxide Free Radicals. Evidence for Antiferromagnetic GdIII-Radical Interactions Christophe Lescop, Elie Belorizky, Dominique Luneau, and Paul Rey pp 3375 - 3384; DOI: 10.1021/ic0200038 |
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Formation of Metal-Anion Arrays within Layered Perovskite Hosts. Preparation of a Series of New Metastable Transition-Metal Oxyhalides, (MCl)LaNb2O7 (M = Cr, Mn, Fe, Co) Liliana Viciu, Gabriel Caruntu, Nicolas Royant, Julien Koenig, Weilie L. Zhou, Thomas A. Kodenkandath, and John B. Wiley pp 3385 - 3388; DOI: 10.1021/ic020026m |
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A Novel Copper Cobalt Inorganometallic Cluster. Synthesis, Structure and Bonding Analysis of Cu3{2-(CCHCo2(CO)6)}3 Andrés Vega, Víctor Calvo, Evgenia Spodine, Antonio Zárate, Víctor Fuenzalida, and Jean-Yves Saillard pp 3389 - 3395; DOI: 10.1021/ic020117j |
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Synthesis of Heteroleptic Anthryl-Substituted -Ketoenolates of Rhodium(III) and Iridium(III): Photophysical, Electrochemical, and EPR Study of the Fluorophore-Metal Interaction Maurizio Carano, Francesca Cicogna, Julien L. Houben, Giovanni Ingrosso, Fabio Marchetti, Loïc Mottier, Francesco Paolucci, Calogero Pinzino, and Sergio Roffia pp 3396 - 3409; DOI: 10.1021/ic010698x |
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Construction of Hydrogen-Bonded and Coordination-Bonded Networks of Cobalt(II) with Pyromellitate: Synthesis, Structures, and Magnetic Properties Hitoshi Kumagai, Cameron J. Kepert, and Mohamedally Kurmoo pp 3410 - 3422; DOI: 10.1021/ic020065y |
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Bi-1,10-phenanthrolines and Their Mononuclear Ru(II) Complexes Yi-Zhen Hu, Qin Xiang, and Randolph P. Thummel pp 3423 - 3428; DOI: 10.1021/ic011126f |
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A Study of Structural and Bonding Variations in the Homologous Series [Mo2(CN)6(dppm)2]n- (n = 2, 1, 0) Jitendra K. Bera, Paul S. Szalay, and Kim R. Dunbar pp 3429 - 3436; DOI: 10.1021/ic020157n |
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Tristhiolatomolybdenum Nitrides, (RS)3MoN Where R = iPr and tBu, Preparation, Characterization and Comparisons with Related Trialkoxymolybdenumnitrides Malcolm H. Chisholm, Ernest R. Davidson, Maren Pink, and Kristine B. Quinlan pp 3437 - 3443; DOI: 10.1021/ic020106q |
Tuning the Electronic Structure of Octahedral Iron Complexes [FeL(X)] (L = 1-Alkyl-4,7-bis(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane, X = Cl, CH3O, CN, NO). The S = 1/2  S = 3/2 Spin Equilibrium of [FeLPr(NO)]Ming Li, Didier Bonnet, Eckhard Bill, Frank Neese, Thomas Weyhermüller, Nicole Blum, Dieter Sellmann, and Karl Wieghardt pp 3444 - 3456; DOI: 10.1021/ic011243a |
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Polyatomic Clusters of the Triel Elements. Palladium-Centered Clusters of Thallium in A8Tl11Pd, A = Cs, Rb, K Stefan Kaskel, Michael T. Klem, and John D. Corbett pp 3457 - 3462; DOI: 10.1021/ic020078b |
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Carbon Dioxide as a Solubility "Switch" for the Reversible Dissolution of Highly Fluorinated Complexes and Reagents in Organic Solvents: Application to Crystallization Philip G. Jessop, Marilyn M. Olmstead, Christopher D. Ablan, Megan Grabenauer, Daniel Sheppard, Charles A. Eckert, and Charles L. Liotta pp 3463 - 3468; DOI: 10.1021/ic020057h |
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Effect of Steric Encumbrance of Tris(3-phenylpyrazolyl)borate on the Structure and Properties of Ternary Copper(II) Complexes Having N,N-Donor Heterocyclic Bases Shanta Dhar, Pattubala A. N. Reddy, Munirathinam Nethaji, Subramony Mahadevan, Manas K. Saha, and Akhil R. Chakravarty pp 3469 - 3476; DOI: 10.1021/ic0201396 |
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Controlling the Framework Formation of Silver(I) Coordination Polymers with 1,4-Bis(phenylthio)butane by Varying the Solvents, Metal-to-Ligand Ratio, and Counteranions Xian-He Bu, Wei Chen, Wen-Feng Hou, Miao Du, Ruo-Hua Zhang, and Francois Brisse pp 3477 - 3482; DOI: 10.1021/ic0113045 |
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Microspeciation in the Copper(II)-L-Histidylglycine System. An ESR Study by the Two-Dimensional Computer Simulation Method Terézia Szabó-Plánka, Nóra Veronika Nagy, Antal Rockenbauer, and László Korecz pp 3483 - 3490; DOI: 10.1021/ic0113092 |
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Five-Coordinate Complexes [FeX(depe)2]BPh4, X = Cl, Br: Electronic Structure and Spin-Forbidden Reaction with N2 Oliver Franke, Beatrix E. Wiesler, Nicolai Lehnert, Christian Näther, Vadim Ksenofontov, Jörg Neuhausen, and Felix Tuczek pp 3491 - 3499; DOI: 10.1021/ic0111987 |
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Electronic Structure of the and Isomers Of [Mo8O26]4- Adam J. Bridgeman and Germán Cavigliasso pp 3500 - 3507; DOI: 10.1021/ic0255510 |
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Antiferromagnetic Coupling in a Six-Coordinate High Spin Cobalt(II)-Semiquinonato Complex Andrea Caneschi, Andrea Dei, Dante Gatteschi, and Vassilis Tangoulis pp 3508 - 3512; DOI: 10.1021/ic020243n |
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Unsymmetrical Tren-Based Ligands: Synthesis and Reactivity of Rhenium Complexes Nadia C. Mösch-Zanetti, Sinje Köpke, Regine Herbst-Irmer, and Manuel Hewitt pp 3513 - 3520; DOI: 10.1021/ic025572u |
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Tetrakis(N,N'-dimethylbenzamidinato)diruthenium(III) Compounds Bearing Axial Chloro and Alkynyl Ligands: A New Family of Redox Rich Diruthenium Compounds Guolin Xu, Charles Campana, and Tong Ren pp 3521 - 3527; DOI: 10.1021/ic0200794 |
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Chalcogen-Rich Lanthanide Clusters with Fluorinated Thiolate Ligands Mark Fitzgerald, Thomas J. Emge, and John G. Brennan pp 3528 - 3532; DOI: 10.1021/ic020138d |
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Synthesis and Characterization of Mononuclear Zinc Aryloxide Complexes Supported by Nitrogen/Sulfur Ligands Possessing an Internal Hydrogen Bond Donor Dewain K. Garner, Russell A. Allred, Kyle J. Tubbs, Atta M. Arif, and Lisa M. Berreau pp 3533 - 3541; DOI: 10.1021/ic020031q |
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Redox Energetics and Kinetics of Uranyl Coordination Complexes in Aqueous Solution David E. Morris pp 3542 - 3547; DOI: 10.1021/ic0201708 |
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Bimetallic Zirconium Heterocycles Supported by Boron-Oxygen Ligands Jessica E. Balkwill, Sarah C. Cole, Martyn P. Coles, and Peter B. Hitchcock pp 3548 - 3552; DOI: 10.1021/ic0200848 |
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Reactive Intermediates Relevant to the Carbonylation of CH3Mn(CO)5. Activation Parameters for Key Dynamic Processes Steve M. Massick, Verena Mertens, Jon Marhenke, and Peter C. Ford pp 3553 - 3559; DOI: 10.1021/ic020116r |
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Metal Cyanide Ions Mx(CN)y]+,- in the Gas Phase: M = Fe, Co, Ni, Zn, Cd, Hg, Fe + Ag, Co + Ag Ian G. Dance, Philip A. W. Dean, Keith J. Fisher, and Hugh H. Harris pp 3560 - 3569; DOI: 10.1021/ic011227d |
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Spin Dimer Analysis of the Spin Exchange Interactions in Paramelaconite Cu4O3 and Its Analogue Ag2Cu2O3 and the Spin Ordering of the Cu2O3 Spin Lattice Leading to Their Magnetic Phase Transitions M.-H. Whangbo and H.-J. Koo pp 3570 - 3577; DOI: 10.1021/ic020141x |
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Photodriven Electron and Energy Transfer from a Light-Harvesting Metallodendrimer Daniel S. Tyson, Charles R. Luman, and Felix N. Castellano pp 3578 - 3586; DOI: 10.1021/ic011298c |
Issue 14
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New Low Temperature Synthetic Route to an Ammonium Zinc Arsenate Zeolite Analogue with an ABW-Type Structure Christopher D. Johnson, Donald E. Macphee, and Jörg Feldmann pp 3588 - 3589; DOI: 10.1021/ic025603l |
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Evidence for an Unstable Bi(II) Radical from Bi-O Bond Homolysis. Implications in the Rate-Determining Step of the SOHIO Process Tracy A. Hanna, Anne L. Rieger, Philip H. Rieger, and Xiaoyu Wang pp 3590 - 3592; DOI: 10.1021/ic0202864 |
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Dissolution of Plutonium(IV) Hydroxide by Desferrioxamine Siderophores and Simple Organic Chelators Christy E. Ruggiero, John H. Matonic, Sean D. Reilly, and Mary P. Neu pp 3593 - 3595; DOI: 10.1021/ic015591o |
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Peculiar Transformation of a Nonaromatic Al4Cl4(NH3)4 into an Aromatic Na2Al4Cl4(NH3)4 Aleksey E. Kuznetsov and Alexander I. Boldyrev pp 3596 - 3598; DOI: 10.1021/ic0256314 |
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Corner Sharing Tetrahedral Network in Co3(HAT)[N(CN)2]6(OH2)2 (HAT = 1,4,5,8,9,12-Hexaazatriphenylene) Shireen R. Marshall, Arnold L. Rheingold, Louise N. Dawe, William W. Shum, Chitoshi Kitamura, and Joel S. Miller pp 3599 - 3601; DOI: 10.1021/ic020176x |
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Photoluminescence of Tetragonal ZrO2 Nanoparticles Synthesized by Microwave Irradiation Jiahe Liang, Zhaoxiang Deng, Xin Jiang, Fuli Li, and Yadong Li pp 3602 - 3604; DOI: 10.1021/ic025532q |
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Controlling Lewis Basicity in Polythioarsenate Fluxes: Stabilization of KSnAsS5 and K2SnAs2S6. Extended Chains and Slabs Based on Pyramidal -[AsS4]3- and [AsS3]3- Units Ratnasabapathy G. Iyer and Mercouri G. Kanatzidis pp 3605 - 3607; DOI: 10.1021/ic025523h |
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Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen Vsevolod V. Rostovtsev, Lawrence M. Henling, Jay A. Labinger, and John E. Bercaw pp 3608 - 3619; DOI: 10.1021/ic0112903 |
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Vibrational Spectra of Bridging Carbonyl Groups in Transition Metal Carbonyl Clusters S. F. A. Kettle, E. Boccaleri, E. Diana, M. C. Iapalucci, R. Rossetti, and P. L. Stanghellini pp 3620 - 3627; DOI: 10.1021/ic020068a |
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Decomposition of Silver Carbonate; the Crystal Structure of Two High-Temperature Modifications of Ag2CO3 P. Norby, R. Dinnebier, and A. N. Fitch pp 3628 - 3637; DOI: 10.1021/ic0111177 |
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Synthesis and Structure of Multicomponent Crystals of Fullerenes and Metal Tetraarylporphyrins Dmitri V. Konarev, Andrey Yu. Kovalevsky, Xue Li, Ivan S. Neretin, Alexey L. Litvinov, Natal'ya V. Drichko, Yury L. Slovokhotov, Philip Coppens, and Rimma N. Lyubovskaya pp 3638 - 3646; DOI: 10.1021/ic011312l |
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Anionic Ligand Effect on the Nature of Epoxidizing Intermediates in Iron Porphyrin Complex-Catalyzed Epoxidation Reactions Wonwoo Nam, Sook Won Jin, Mi Hee Lim, Ju Yeon Ryu, and Cheal Kim pp 3647 - 3652; DOI: 10.1021/ic011145p |
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Insertion of SO2 into the S-S Bond of Cp2MoS2 and Cp2MoS2O To Give Molybdocene Dithiosulfate and Bis(O-alkylthiosulfates) Andrzej Z. Rys, Anne-Marie Lebuis, Alan Shaver, and David N. Harpp pp 3653 - 3655; DOI: 10.1021/ic011001a |
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Linear Trimer Analogues of Calixarene as Chiral Coordinating Ligands: X-ray Crystallographic and NMR Spectroscopic Characterization of Chiral and Achiral Trisphenolates Complexed to Titanium(IV) and Aluminum(III) William O. Appiah, Angela D. DeGreeff, Gina L. Razidlo, Sarah J. Spessard, Maren Pink, Victor G. Young, Jr., and Gretchen E. Hofmeister pp 3656 - 3667; DOI: 10.1021/ic010685j |
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Synthesis of a Homoleptic Niobium(V) Thiolate Complex and the Preparation of Niobium Sulfide via Thio "Sol-Gel" and Vapor Phase Thin-Film Experiments Claire J. Carmalt, Christopher W. Dinnage, Ivan P. Parkin, Andrew J. P. White, and David J. Williams pp 3668 - 3672; DOI: 10.1021/ic020097l |
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A Solvent-Controlled Switch of Manganese Complex Assemblies with a -Diketonate-Based Ligand Guillem Aromí, Patrick Gamez, Olivier Roubeau, Paula Carrero Berzal, Huub Kooijman, Anthony L. Spek, Willem L. Driessen, and Jan Reedijk pp 3673 - 3683; DOI: 10.1021/ic0200491 |
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Bonding and Stability of the Hydrogen Storage Material Mg2NiH4 Ulrich Häussermann, Helen Blomqvist, and Dag Noréus pp 3684 - 3692; DOI: 10.1021/ic0201046 |
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Contribution of Individual Zinc Ligands to Metal Binding and Peptide Folding of Zinc Finger Peptides Akiko Nomura and Yukio Sugiura pp 3693 - 3698; DOI: 10.1021/ic025557p |
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Design and Synthesis of a Self-Assembled Photochemical Dyad Based on Selective Imidazole Recognition Dharam Paul, Jennifer A. Wytko, Matthieu Koepf, and Jean Weiss pp 3699 - 3704; DOI: 10.1021/ic020043b |
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Temperature Dependence of the Crystal Lattice Organization of Coordination Compounds Involving Nitronyl Nitroxide Radicals: A Magnetic and Structural Investigation Mohammed Fettouhi, Bassam El Ali, Abdel Moneim El-Ghanam, Stéphane Golhen, Lahcène Ouahab, Nathalie Daro, and Jean-Pascal Sutter pp 3705 - 3712; DOI: 10.1021/ic020021p |
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Synthesis, Characterization, and Crystal Structures of Two New Divalent Metal Complexes of N,N'-Bis(phosphonomethyl)-1,10-diaza-18-crown-6: A Hydrogen-Bonded 1D Array and a 3D Network with a Large Channel Jiang-Gao Mao, Zhike Wang, and Abraham Clearfield pp 3713 - 3720; DOI: 10.1021/ic0200601 |
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Aurophilicity-Based One-Dimensional Arrays of Gold(I) Phenylene-1,3- and -1,4-dithiolates Hendrik Ehlich, Annette Schier, and Hubert Schmidbaur pp 3721 - 3727; DOI: 10.1021/ic020107i |
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Photochemical Nitric Oxide Precursors: Synthesis, Photochemistry, and Ligand Substitution Kinetics of Ruthenium Salen Nitrosyl and Ruthenium Salophen Nitrosyl Complexes Carmen F. Works, Christoph J. Jocher, Gwen D. Bart, Xianhui Bu, and Peter C. Ford pp 3728 - 3739; DOI: 10.1021/ic020248k |
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Dramatic Changes in Geometry after Ionization: Experimental and Theoretical Studies on the Electronic Properties of Fluorocarbonyl (Mono-, Di-, and Tri-) Sulfur Compounds Mauricio F. Erben and Carlos O. Della Védova pp 3740 - 3748; DOI: 10.1021/ic020046o |
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Study of the Ligand Substitution Reactions of cis,cis-[(bpy)2(L)RuORu(L')(bpy)2]n+ (L, L' = H2O, OH-, NH3) Using Electrospray Ionization Mass Spectrometry and 1H NMR Ryuichi Arakawa, Naoko Kubota, Tsuyoshi Fukuo, Osamu Ishitani, and Emiko Ando pp 3749 - 3754; DOI: 10.1021/ic0109445 |
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New Metalloligands [M(SC{O}Ph)4]-: Synthesis and Characterization of Polymeric [A(MeCN)x{M(SC{O}Ph)4}] Compounds (A = Li, Na and K; M = Ga and In; x = 0-2) Theivanayagam C. Deivaraj, Wei Hoon Lye, and Jagadese J. Vittal pp 3755 - 3760; DOI: 10.1021/ic025533i |
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New Tetrathiapentalene-Derived Charge Transfer Salts with Paramagnetic Transition Metal Complex Anion: -(EDDH-TTP)3[Cr(phen)(NCS)4]·2CH2Cl2 and 21-(BDH-TTP)5[Cr(phen)(NCS)4]2·2CH2Cl2 Fatima Setifi, Lahcène Ouahab, Stéphane Golhen, Olivier Hernandez, Akira Miyazaki, Toshiaki Enoki, Takashi Toita, Jun-ichi Yamada, Hiroyuki Nishikawa, Andrzej apiski, and Roman  wietlikpp 3761 - 3768; DOI: 10.1021/ic0255961 |
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Exchange Coupling in Halo-Bridged Dinuclear Cu(II) Compounds: A Density Functional Study Antonio Rodríguez-Fortea, Pere Alemany, Santiago Alvarez, and Eliseo Ruiz pp 3769 - 3778; DOI: 10.1021/ic011308+ |
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Conformational Behavior and Coordination Chemistry of 2,11-Dithia[3.3]orthocyclophane with Platinum Group Metals Jorge Tiburcio, William D. Jones, Stephen J. Loeb, and Hugo Torrens pp 3779 - 3785; DOI: 10.1021/ic0256157 |
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Bulk Weak Ferromagnet in Ferrimagnetic Chains of Organic-Inorganic Hybrid Materials Based on BDH-TTP and Paramagnetic Thiocyanato Complex Anions: (BDH-TTP)[M(isoq)2(NCS)4], M = CrIII, FeIII Fatima Setifi, Stéphane Golhen, Lahcène Ouahab, Akira Miyazaki, Kazuki Okabe, Toshiaki Enoki, Takashi Toita, and Jun-ichi Yamada pp 3786 - 3790; DOI: 10.1021/ic025553k |
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1,2,3,4-Tetraphenyl-1,2,3,4-tetraphospholane, a Highly Versatile Cyclocarbaphosphine Ligand: Reactions with Activated Triosmium Clusters and Characterization of the Products Siau-Gek Ang, Xinhua H. Zhong, and How-Ghee Ang pp 3791 - 3800; DOI: 10.1021/ic025589c |
Issue 15
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Mechanistic Insight from a Volume Profile for Electron Transfer between Promazine and Hexaaquairon(III) Joanna Wi  niewska and Rudi van Eldikpp 3802 - 3804; DOI: 10.1021/ic0201349 |
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Anionic Templating: Synthesis, Structure, and Characterization of Novel Three-Dimensional Mixed-Metal Oxychlorides Te4M3O15·Cl (M = Nb5+ or Ta5+) Kang Min Ok and P. Shiv Halasyamani pp 3805 - 3807; DOI: 10.1021/ic025733u |
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DNA Photocleavage by a Supramolecular Ru(II)-Viologen Complex Patty K.-L. Fu, Patricia M. Bradley, Dietmar van Loyen, Heinz Dürr, Stefan H. Bossmann, and Claudia Turro pp 3808 - 3810; DOI: 10.1021/ic020136t |
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Di- and Tricobalt Dawson Sandwich Complexes: Synthesis, Spectroscopic Characterization, and Electrochemical Behavior of Na18[(NaOH2)2Co2(P2W15O56)2] and Na17[(NaOH2)Co3(H2O)(P2W15O56)2] Laurent Ruhlmann, Jacqueline Canny, Roland Contant, and René Thouvenot pp 3811 - 3819; DOI: 10.1021/ic020146u |
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Ligand Substitution, pH Dependent Deoxygenation, and Linkage Isomerization Reactions of the 2,2'-Bipyridinetetranitroruthenate Dianion Daniel A. Freedman, Daron E. Janzen, Jennifer L. Vreeland, Hannah M. Tully, and Kent R. Mann pp 3820 - 3829; DOI: 10.1021/ic0255205 |
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Di- and Tetranuclear Ruthenium(II) and/or Osmium(II) Complexes of Polypyridyl Ligands Bridged by a Fully Conjugated Aromatic Spacer: Synthesis, Characterization, and Electrochemical and Photophysical Studies Anvarhusen K. Bilakhiya, Beena Tyagi, Parimal Paul, and P. Natarajan pp 3830 - 3842; DOI: 10.1021/ic010676a |
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Synthesis and Structures of Aluminum Alkanethiolate Complexes Sherrika Daniel and David M. Hoffman pp 3843 - 3849; DOI: 10.1021/ic011257g |
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A New Dinuclear Vanadium(V)-Citrate Complex from Aqueous Solutions. Synthetic, Structural, Spectroscopic, and pH-Dependent Studies in Relevance to Aqueous Vanadium(V)-Citrate Speciation M. Kaliva, T. Giannadaki, A. Salifoglou, C. P. Raptopoulou, and A. Terzis pp 3850 - 3858; DOI: 10.1021/ic010971v |
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Reaction of Bis(phosphine)(hydrotris(3,5-dimethylpyrazolyl)borato)rhodium(I) with Phenylacetylene, p-Nitrobenzaldehyde, and Triphenyltin Hydride: Structures of [Rh(Tp*)(PPh3)2], [Rh(Tp*)(H)(C2Ph){P(4-C6H4F)3}], [Rh(Tp*)(H)(COC6H4-4-NO2)(PPh3)], and [Rh(Tp*)(H)(SnPh3)(PPh3)] Viorel Cîrcu, Manuel A. Fernandes, and Laurence Carlton pp 3859 - 3865; DOI: 10.1021/ic0112037 |
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Metal-Metal Interactions in Dinuclear d8 Metal Cyanide Complexes Supported by Phosphine Ligands. Spectroscopic Properties and ab Initio Calculations of [M2(-diphosphine)2(CN)4] and trans-[M(phosphine)2(CN)2] (M = Pt, Ni) Bao-Hui Xia, Chi-Ming Che, David Lee Phillips, King-Hung Leung, and Kung-Kai Cheung pp 3866 - 3875; DOI: 10.1021/ic020077j |
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Synthesis, Coordination to Rh(I), and Hydroformylation Catalysis of New -Aminophosphines Bearing a Dangling Nitrogen Group: An Unusual Inversion of a Rh-Coordinated P Center Jacques Andrieu, Philippe Richard, Jean-Michel Camus, and Rinaldo Poli pp 3876 - 3885; DOI: 10.1021/ic011035i |
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A Homologous Series of Alkaline Earth Phosphanides: Syntheses, Crystal Structures, and Unusual Dynamic Behavior of (THF)nM[P{CH(SiMe3)2}(C6H4-2-CH2NMe2)]2 (M = Mg, Ca, Sr, Ba) Stuart Blair, Keith Izod, and William Clegg pp 3886 - 3893; DOI: 10.1021/ic0201194 |
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Coordination of cyclo-Octasulfur and cyclo-Heptaselenium to Dinuclear Rhenium(I) Systems Alessia Bacchi, Walter Baratta, Fausto Calderazzo, Fabio Marchetti, and Giancarlo Pelizzi pp 3894 - 3900; DOI: 10.1021/ic025570+ |
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Dianionic Complexes with Hexacoordinate Silicon(IV) or Germanium(IV) and Three Bidentate Ligands of the Hydroximato(2-) Type: Syntheses and Structural Characterization in the Solid State Andreas Biller, Christian Burschka, Martin Penka, and Reinhold Tacke pp 3901 - 3908; DOI: 10.1021/ic0255757 |
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Synthesis and Characterization of Three-Coordinate and Related -Diketiminate Derivatives of Manganese, Iron, and Cobalt Arunashree Panda, Matthias Stender, Robert J. Wright, Marilyn M. Olmstead, Peter Klavins, and Philip P. Power pp 3909 - 3916; DOI: 10.1021/ic025552s |
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Catalysis of H2/D2 Scrambling and Other H/D Exchange Processes by [Fe]-Hydrogenase Model Complexes Xuan Zhao, Irene P. Georgakaki, Matthew L. Miller, Rosario Mejia-Rodriguez, Chao-Yi Chiang, and Marcetta Y. Darensbourg pp 3917 - 3928; DOI: 10.1021/ic020237r |
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Synthesis, Crystal Structure, and Solid State NMR Spectroscopy of NH4[(V2O3)2(4,4'-bpy)2(H2PO4)(PO4)2]·0.5H2O, a Mixed-Valence Vanadium(IV,V) Phosphate with a Pillared Layer Structure Ling-I Hung, Sue-Lein Wang, Hsien-Ming Kao, and Kwang-Hwa Lii pp 3929 - 3934; DOI: 10.1021/ic011277i |
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Synthetic Models of the Reduced Active Site of Superoxide Reductase Jason A. Halfen, Heather L. Moore, and Derek C. Fox pp 3935 - 3943; DOI: 10.1021/ic025517l |
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KNa3In9: A Zintl Network Phase Built of Layered Indium Icosahedra and Zigzag Chains. Synthesis, Structure, Bonding, and Properties Bin Li and John D. Corbett pp 3944 - 3949; DOI: 10.1021/ic020152q |
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The Hexacoordinate Silicate Dianions mer-Tris[glycolato(2-)-O1,O2]silicate and fac-Tris[benzilato(2-)-O1,O2]silicate: Syntheses and Structural Characterization Ingo Richter, Martin Penka, and Reinhold Tacke pp 3950 - 3955; DOI: 10.1021/ic025597t |
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Siting of Antimony Dopants and Gallium in Ba8Ga16Ge30 Clathrates Grown from Gallium Flux S. E. Latturner, J. D. Bryan, N. Blake, H. Metiu, and G. D. Stucky pp 3956 - 3961; DOI: 10.1021/ic011286r |
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Hydrothermal Synthesis and Structural Characterization of a New Organically Templated Germanate, Ge10O21(OH)·N4C6H21 Lionel Beitone, Thierry Loiseau, and Gérard Férey pp 3962 - 3966; DOI: 10.1021/ic020193m |
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Molecular Triangle of Palladium(II) and Its Anion Binding Properties Zengquan Qin, Michael C. Jennings, and Richard J. Puddephatt pp 3967 - 3974; DOI: 10.1021/ic020227q |
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Generation and Reactivity of Rhodium(IV) Complexes in Aqueous Solutions Oleg Pestovsky and Andreja Bakac pp 3975 - 3982; DOI: 10.1021/ic0256415 |
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Substrate Binding in Catechol Oxidase Activity: Biomimetic Approach Stéphane Torelli, Catherine Belle, Sylvain Hamman, Jean-Louis Pierre, and Eric Saint-Aman pp 3983 - 3989; DOI: 10.1021/ic025599d |
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Alkyl and Aryl Substituted Corroles. 3. Reactions of Cofacial Cobalt Biscorroles and Porphyrin-Corroles with Pyridine and Carbon Monoxide Karl M. Kadish, Zhongping Ou, Jianguo Shao, Claude P. Gros, Jean-Michel Barbe, François Jérôme, Frédéric Bolze, Fabien Burdet, and Roger Guilard pp 3990 - 4005; DOI: 10.1021/ic020058+ |
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Different Complexation Properties of Some Hydroxy Keto Heterocycles toward Beryllium(II) in Aqueous Solutions: Experimental and Theoretical Studies Franco Cecconi, Carlo A. Ghilardi, Andrea Ienco, Palma Mariani, Carlo Mealli, Stefano Midollini, Annabella Orlandini, and Alberto Vacca pp 4006 - 4017; DOI: 10.1021/ic025612u |
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Mechanistic Studies of a Calcium-Dependent MRI Contrast Agent Wen-hong Li, Giacomo Parigi, Marco Fragai, Claudio Luchinat, and Thomas J. Meade pp 4018 - 4024; DOI: 10.1021/ic0200390 |
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Metalla-Supramolecular Rectangles as Electron Reservoirs for Multielectron Reduction and Oxidation Wolfgang Kaim, Brigitte Schwederski, Akbey Dogan, Jan Fiedler, Christopher J. Kuehl, and Peter J. Stang pp 4025 - 4028; DOI: 10.1021/ic020122n |
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Synthesis and Characterization of [Mo7O16(O3PCH2PO3)3]:8- A Mixed-Valent Polyoxomolybdenum Diphosphonate Anion with Octahedrally and Tetrahedrally Coordinated Molybdenum Eddy Dumas, Capucine Sassoye, Kristin D. Smith, and Slavi C. Sevov pp 4029 - 4032; DOI: 10.1021/ic0202209 |
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Synthesis and Structural, Spectroscopic, and Electrochemical Characterization of New Ruthenium Dimethyl Sulfoxide Nitrosyls Barbara Serli, Ennio Zangrando, Elisabetta Iengo, Giovanni Mestroni, Lesley Yellowlees, and Enzo Alessio pp 4033 - 4043; DOI: 10.1021/ic011291v |
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Synthesis and Study of Ru,Rh,Ru Triads: Modulation of Orbital Energies in a Supramolecular Architecture Shawn Swavey and Karen J. Brewer pp 4044 - 4050; DOI: 10.1021/ic020201z |
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Antimony Ethylene Glycolate and Catecholate Compounds: Structural Characterization of Polyesterification Catalysts Shannon M. Biros, Brian M. Bridgewater, Adriel Villeges-Estrada, Joseph M. Tanski, and Gerard Parkin pp 4051 - 4057; DOI: 10.1021/ic020204b |
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Synthesis, Structure, and Magnetic Properties of Dinuclear Cobalt(II) Complexes with a New Phenol-Based Dinucleating Ligand with Four Hydroxyethyl Chelating Arms Md. Jamil Hossain, Mikio Yamasaki, Masahiro Mikuriya, Atsushi Kuribayashi, and Hiroshi Sakiyama pp 4058 - 4062; DOI: 10.1021/ic0255297 |
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Synthesis and Structures of Zirconium Amide-Iodide Complexes Jean-Sébastien M. Lehn and David M. Hoffman pp 4063 - 4067; DOI: 10.1021/ic025630b |
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Two-Dimensional Rhombohedral Grid Coordination Polymers [M(bbbt)2(NCS)2]n (M = Co, Mn, or Cd; bbbt = 1,1'-(1,4-butanediyl) bis-1H-benzotriazole): Synthesis, Crystal Structures, and Third-Order Nonlinear Optical Properties Hongwei Hou, Xiangru Meng, Yinglin Song, Yaoting Fan, Yu Zhu, Huijie Lu, Chenxia Du, and Weihua Shao pp 4068 - 4075; DOI: 10.1021/ic0255858 |
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Synthesis, Structure, and Bonding of Sc6MTe2 (M = Ag, Cu, Cd): Heterometal-Induced Polymerization of Metal Chains in Sc2Te Ling Chen and John D. Corbett: pp 4076 - 4076; DOI: 10.1021/ic020394q |
Issue 16
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Copper(I) Ion Mediated Self-Organization of Molecular Rectangular Boxes from 1,2-Bis(2-pyridylethynyl)benzene Ligands with Bulky Substituents Tomikazu Kawano, Jun Kuwana, Chong-Xu Du, and Ikuo Ueda pp 4078 - 4080; DOI: 10.1021/ic025574e |
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Synthesis and Characterization of a Novel Linear Trinuclear Ruthenium(II) Complex: Variation of Photosensitization Ability with Chain Length in a Homologous Series Simona Vaduvescu and Pierre G. Potvin pp 4081 - 4083; DOI: 10.1021/ic025511w |
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Novel Coordination Polymer Containing a Mixed Valence Copper(I,II) Phosphonate Unit: CuI2CuII(hedpH2)2(4,4'-bpy)2·2H2O (hedp = 1-Hydroxyethylidenediphosphonate) Li-Min Zheng, Ping Yin, and Xin-Quan Xin pp 4084 - 4086; DOI: 10.1021/ic015631o |
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An Electron-Excessive Nitrosyl Complex: Reactivity of a Ligand-Centered Radical Leading to Coordinated HNO Alexei V. Marchenko, Andrei N. Vedernikov, David F. Dye, Maren Pink, Jeffrey M. Zaleski, and Kenneth G. Caulton pp 4087 - 4089; DOI: 10.1021/ic025699j |
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Tetraarylpentaborates, [B5O6Ar4]- (Ar = C6H4OMe-4, C6H3Me2-2,6): Their Formation from the Reaction of Arylboronic Acids with an Aryloxorhodium Complex, Structure, and Chemical Properties Yasushi Nishihara, Kyoko Nara, and Kohtaro Osakada pp 4090 - 4092; DOI: 10.1021/ic015630w |
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C-S Bond Cleavage of Pyridine-2-thiol: A New Functionality of Quadruply Bridged Dinuclear Platinum and Palladium Complexes Keisuke Umakoshi, Toshinori Yamasaki, Atsushi Fukuoka, Hiroyuki Kawano, Masaru Ichikawa, and Masayoshi Onishi pp 4093 - 4095; DOI: 10.1021/ic020282z |
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Unsymmetrical Linear Pentanuclear Nickel String Complexes: [Ni5(tpda)4(H2O)(BF4)](BF4)2 and [Ni5(tpda)4(SO3CF3)2](SO3CF3) Chen-Yu Yeh, Yi-Li Chiang, Gene-Hsiang Lee, and Shie-Ming Peng pp 4096 - 4098; DOI: 10.1021/ic025582v |
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Synthesis, Structure, and DNA Cleavage Activity of New Trinuclear Zn3 and Zn2Cu Complexes of a Chiral Macrocycle: Structural Correlation with the Active Center of P1 Nuclease Srinivas R. Korupoju, Nagarathinam Mangayarkarasi, Panthapally S. Zacharias, Jun Mizuthani, and Hiroshi Nishihara pp 4099 - 4101; DOI: 10.1021/ic0201102 |
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Alkylation Reactions of [WS4]2- and [(5-C5Me5)WS3]- with 2,6-Bis(bromomethyl)pyridine: The First Isolation of Bisalkylated Tetrathiometalate WS2{2,6-(SCH2)2(C5H3N)} Rong Cao and Kazuyuki Tatsumi pp 4102 - 4104; DOI: 10.1021/ic0256258 |
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Synthesis, Structures, and Properties of a Series of Four-, Five-, and Six-Coordinate Cobalt(III) Triazacorrole Complexes: The First Examples of Transition Metal Corrolazines Bobby Ramdhanie, Lev N. Zakharov, Arnold L. Rheingold, and David P. Goldberg pp 4105 - 4107; DOI: 10.1021/ic020297x |
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Synthesis and Structure of Ag6[(UO2)3O(MoO4)5]: A Novel Sheet of Triuranyl Clusters and MoO4 Tetrahedra Sergey V. Krivovichev and Peter C. Burns pp 4108 - 4110; DOI: 10.1021/ic025662z |
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Formation of a 1-Azaallenylidene Ligand by Reaction of an Amido Complex with Tetracyanoethylene Dolores Morales, Julio Pérez, Lucía Riera, Víctor Riera, and Daniel Miguel pp 4111 - 4113; DOI: 10.1021/ic025665b |
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Synthesis, Characterization, and Solution Redox Properties of (trimpsi)M(CO)2(NO) Complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3] Trevor W. Hayton, P. James Daff, Peter Legzdins, Steven J. Rettig, and Brian O. Patrick pp 4114 - 4126; DOI: 10.1021/ic020041r |
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Synthesis of the New Metastable Skutterudite Compound NiSb3 from Modulated Elemental Reactants Joshua R. Williams and David C. Johnson pp 4127 - 4130; DOI: 10.1021/ic011131j |
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Insight into the Structure of Silver Cyanide from 13C and 15N Solid-State NMR Spectroscopy David L. Bryce and Roderick E. Wasylishen pp 4131 - 4138; DOI: 10.1021/ic0201553 |
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Reduced and Excited States of (bpym)[PtCl2]n (bpym = 2,2'-Bipyrimidine; n = 1, 2): Experiments and DFT Calculations Wolfgang Kaim, Akbey Dogan, Matthias Wanner, Axel Klein, Ioannis Tiritiris, Thomas Schleid, Derk J. Stufkens, Theo L. Snoeck, Eric J. L. McInnes, Jan Fiedler, and Stanislav Záli pp 4139 - 4148; DOI: 10.1021/ic020158f |
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Synthesis and Characterization of Iron Complexes with Monoanionic and Dianionic N,N',N' '-Trialkylguanidinate Ligands Stephen R. Foley, Glenn P. A. Yap, and Darrin S. Richeson pp 4149 - 4157; DOI: 10.1021/ic020088c |
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Mechanistic Studies on the Reactions of PhS- or [MoS4]2- with [M4(SPh)10]2- (M = Fe or Co) Zhen Cui and Richard A Henderson pp 4158 - 4166; DOI: 10.1021/ic020284j |
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Deviation from Tetrahedral Geometry in Me2GeCl2: Crystal Structure of a Model Compound and Insight from ab Initio Calculations Heidi Rohwer and Jan Dillen pp 4167 - 4172; DOI: 10.1021/ic0256011 |
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First Anhydrous Gold Perchlorato Complex: ClO2Au(ClO4)4. Synthesis and Molecular and Crystal Structure Analysis Frédérique Cunin, Catherine Deudon, Frédéric Favier, Bernard Mula, and Jean Louis Pascal pp 4173 - 4178; DOI: 10.1021/ic020161z |
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Theoretical Evidence for the Singlet Diradical Character of Square Planar Nickel Complexes Containing Two o-Semiquinonato Type Ligands Vinzenz Bachler, Gottfried Olbrich, Frank Neese, and Karl Wieghardt pp 4179 - 4193; DOI: 10.1021/ic0113101 |
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Heterobimetallic Bismuth-Transition Metal Salicylate Complexes as Molecular Precursors for Ferroelectric Materials. Synthesis and Structure of Bi2M2(sal)4(Hsal)4(OR) 4 (M = Nb, Ta; R = CH2CH3, CH(CH3)2), Bi2Ti3(sal)8(Hsal)2, and Bi2Ti4(OiPr)(sal)10(Hsal) (sal = O2CC6H4-2-O; Hsal = O2CC6H4-2-OH) John H. Thurston and Kenton H. Whitmire pp 4194 - 4205; DOI: 10.1021/ic0255454 |
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High-Temperature, High-Pressure Hydrothermal Synthesis, Crystal Structure, and Solid State NMR Spectroscopy of a New Vanadium(IV) Silicate: Rb2(VO)(Si4O10)·xH2O Chun-Yi Li, Chan-Yen Hsieh, Hsiu-Mei Lin, Hsien-Ming Kao, and Kwang-Hwa Lii pp 4206 - 4210; DOI: 10.1021/ic020187q |
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Site-Differentiated Hexanuclear Rhenium(III) Cyanide Clusters [Re6Se8(PEt3)n(CN)6-n]n-4 (n = 4, 5) and Kinetics of Solvate Ligand Exchange on the Cubic [Re6Se8]2+ Core Thomas G. Gray and R. H. Holm pp 4211 - 4216; DOI: 10.1021/ic020214c |
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Synthesis and Structure of a Series of New d1-Aryl Imido-Vanadium(IV) Complexes Stabilized by N-Donor Ligands Christian Lorber, Robert Choukroun, and Bruno Donnadieu pp 4217 - 4226; DOI: 10.1021/ic020312y |
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New Mercury Vanadium Phosphate Hydrate Hg4-xO1-y((VO)(PO4)2·H2O with Unprecedented Tetrahedral Oxo-Cluster [Hg~4O~5] E. Le Fur, R. Gautier, E. Furet, and J. Y. Pivan pp 4227 - 4231; DOI: 10.1021/ic020229a |
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How to Make a Major Shift in a Redox Potential: Ligand Control of the Oxidation State of Dimolybdenum Units F. Albert Cotton, Lee M. Daniels, Chun Y. Liu, Carlos A. Murillo, Arthur J. Schultz, and Xiaoping Wang pp 4232 - 4238; DOI: 10.1021/ic025632w |
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Synthesis of the arachno-4-CB8H122- Monocarbaborane Dianion and NMR/Computational Studies of the Fluxional Processes Observed in the Isoelectronic Nine-Vertex arachno Anions: arachno-4-CB8H122-, arachno-4-CB8H13-, and arachno-4-SB8H11- Daniel E. Kadlecek and Larry G. Sneddon pp 4239 - 4244; DOI: 10.1021/ic0202155 |
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Routes to Regioselective Deuteriation of Heteroaromatic Compounds Wesley R. Browne, Christine M. O'Connor, J. Scott Killeen, Adrian L. Guckian, Micheal Burke, Paraic James, Maurice Burke, and Johannes G. Vos pp 4245 - 4251; DOI: 10.1021/ic020226y |
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Modeling Reactive Metal Oxides. Kinetics, Thermodynamics, and Mechanism of M3 Cap Isomerization in Polyoxometalates Travis M. Anderson and Craig L. Hill pp 4252 - 4258; DOI: 10.1021/ic020224d |
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Synthesis, Structure Determination, and Quantum-Chemical Characterization of an Alternate HgNCN Polymorph Xiaohui Liu, Paul Müller, Peter Kroll, and Richard Dronskowski pp 4259 - 4265; DOI: 10.1021/ic020133g |
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Competing Interactions in the Tetranuclear Spin Cluster {Ni[(OH)2Cr(bispictn)]3}I55H2O. An Inelastic Neutron Scattering and Magnetic Study Ralph Schenker, H  gni Weihe, Hanspeter Andres, Reto Basler, Grégory Chaboussant, Kirsten Michelsen, Michael Aebersold, Herma Büttner, and Hans U. Güdelpp 4266 - 4274; DOI: 10.1021/ic0111031 |
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Synthesis and Characterization of the SO2N3-, (SO2)2N3-, and SO3N3- Anions Karl O. Christe, Jerry A. Boatz, Michael Gerken, Ralf Haiges, Stefan Schneider, Thorsten Schroer, Fook S. Tham, Ashwani Vij, Vandana Vij, Ross I. Wagner, and William W. Wilson pp 4275 - 4285; DOI: 10.1021/ic020183l |
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Structural and Mechanistic Look at the Orthoplatination of Aryl Oximes by Dichlorobis(sulfoxide or sulfide)platinum(II) Complexes Alexander D. Ryabov, Stefanus Otto, Pavel V. Samuleev, Vladimir A. Polyakov, Larissa Alexandrova, Grigory M. Kazankov, Sergiu Shova, Mikhail Revenco, Janusz Lipkowski, and Maria H. Johansson pp 4286 - 4294; DOI: 10.1021/ic020192u |
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o-Iminobenzosemiquinonato(1-) and o-Amidophenolato(2-) Complexes of Palladium(II) and Platinum(II): A Combined Experimental and Density Functional Theoretical Study Xianru Sun, Hyungphil Chun, Knut Hildenbrand, Eberhard Bothe, Thomas Weyhermüller, Frank Neese, and Karl Wieghardt pp 4295 - 4303; DOI: 10.1021/ic011297k |
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%Structural Model for the CuB Site of Dopamine -Hydroxylase: Crystal Structure of a Copper(II) Complex Showing N3OS Coordination with an Axial Sulfur Ligation Bidyut K. Santra, Pattubala A. N. Reddy, Munirathinam Nethaji, and Akhil R. Chakravarty: pp 4304 - 4304; DOI: 10.1021/ic020317v |
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A Novel Chiral Three-Dimensional Iron(III) Compound Exhibiting Magnetic Ordering at Tc = 40 K Donatella Armentano, Giovanni De Munno, Francesc Lloret, Andrei V. Palli, and Miguel Julve pp 4304 - 4304; DOI: 10.1021/ic020359j |
Issue 17
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Tin-Capped Trinuclear Nickel Clusters: Redox Isomerism between 3-Stannyl and 3-Stannylene Clusters of the Class [Ni3(dppm)3(3-I)(3-SnClx)]n+ (x = 2, n = 1; x = 3, n = 0) Brian K. Breedlove, Philip E. Fanwick, and Clifford P. Kubiak pp 4306 - 4308; DOI: 10.1021/ic020108a |
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Dichloromethane Alkylates a Trithiolato-Ruthenium Complex to Yield a Methylene-Bridged Thioether Core. Synthesis and Structural Comparison to the Thiolato-Ruthenium Precursor Craig A. Grapperhaus, Selma Poturovic, and Mark S. Mashuta pp 4309 - 4311; DOI: 10.1021/ic025735e |
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Decomposition of Ascorbic Acid in the Presence of Cadmium Ions Leads to Formation of a Polymeric Cadmium Oxalate Species with Peculiar Structural Features Pierluigi Orioli, Bruno Bruni, Massimo Di Vaira, Luigi Messori, and Francesca Piccioli pp 4312 - 4314; DOI: 10.1021/ic025598l |
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The Monophosphino Urea Derivative PPh2NMeC(O)NMeH: A Hemilabile Ligand Switching between P,O- and P,N-Coordination Olaf Kühl and Peter Lönnecke pp 4315 - 4317; DOI: 10.1021/ic025614e |
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Direct Observation of Competitive Ultrafast CO Dissociation and Relaxation of an MLCT Excited State: Picosecond Time-Resolved Infrared Spectroscopic Study of [Cr(CO)4(2,2'-bipyridine)] Ian R. Farrell, Pavel Matousek, Michael Towrie, Anthony W. Parker, David C. Grills, Michael W. George, and Antonín Vl ek Jr.pp 4318 - 4323; DOI: 10.1021/ic020218h |
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Sulfur-Bridged Early-Late Heterobimetallics Synthesized by Incorporation of Titanium, Vanadium, and Molybdenum into Bis(hydrosulfido) Templates of Group 9 Metals Shigeki Kuwata, Tatsuya Nagano, Akihiro Matsubayashi, Youichi Ishii, and Masanobu Hidai pp 4324 - 4330; DOI: 10.1021/ic020105y |
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Reductive Growth of Nanosized Ligated Metal Clusters on Silicon Nanowires X. H. Sun, C. P. Li, N. B. Wong, C. S. Lee, S. T. Lee, and Boon K. Teo pp 4331 - 4336; DOI: 10.1021/ic011219x |
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Lead(II) Complexes with Macrocyclic Receptors Derived from 4,13-Diaza-18-crown-6 David Esteban, Fernando Avecilla, Carlos Platas-Iglesias, Jose Mahía, Andrés de Blas, and Teresa Rodríguez-Blas pp 4337 - 4347; DOI: 10.1021/ic0255095 |
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Syntheses and X-ray Structures of Potassium Derivatives and a Paramagnetic Nickel(II) Complex of a Cyclodiphosph(III/V)azane Monoselenide Tristram Chivers, Mark Krahn, and Gabriele Schatte pp 4348 - 4354; DOI: 10.1021/ic020167o |
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A DFT Study of SiH4 Activation by Cp2LnH Lionel Perrin, Laurent Maron, and Odile Eisenstein pp 4355 - 4362; DOI: 10.1021/ic011275y |
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Synthesis, Magnetic Properties, and Electronic Spectra of Bis(-diketonato)chromium(III) and Nickel(II) Complexes with a Chelated Imino Nitroxide Radical: X-ray Structures of [Cr(acaMe)2(IM2py)]PF6 and [Ni(acac)2(IM2py)] Yasunori Tsukahara, Takayuki Kamatani, Atsushi Iino, Takayoshi Suzuki, and Sumio Kaizaki pp 4363 - 4370; DOI: 10.1021/ic011282m |
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A New Tantalum Dinitrogen Complex and a Parahydrogen-Induced Polarization Study of Its Reaction with Hydrogen Dawn C. Bregel, Susan M. Oldham, Rene J. Lachicotte, and Richard Eisenberg pp 4371 - 4377; DOI: 10.1021/ic025578j |
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Ionic Hydrates, MpXq·nH2O: Lattice Energy and Standard Enthalpy of Formation Estimation H. Donald Brooke Jenkins and Leslie Glasser pp 4378 - 4388; DOI: 10.1021/ic020222t |
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Excited-State Electronic Coupling and Photoinduced Multiple Electron Transfer in Two Related Ligand-Bridged Hexanuclear Mixed-Valence Compounds Brian W. Pfennig, Carolyn J. Mordas, Alex McCloskey, Jenny V. Lockard, Patty M. Salmon, Jamie L. Cohen, David F. Watson, and Andrew B. Bocarsly pp 4389 - 4395; DOI: 10.1021/ic020232u |
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Tetracyanometalates of Ni, Pd, and Pt with Cyclic Diquaternary Cations of 2,2'-Bipyridine and 1,10-Phenanthroline. A Vibrational, Crystallographic, and Theoretical Study of Intermolecular Weak Interactions Pablo Vitoria, Javier I. Beitia, Juan M. Gutiérrez-Zorrilla, Emilio R. Sáiz, Antonio Luque, Maite Insausti, and José J. Blanco pp 4396 - 4404; DOI: 10.1021/ic0200287 |
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Polynuclear Complexes of the Pendent-Arm Ligand 1,4,7-Tris(acetophenoneoxime)-1,4,7-triazacyclononane Vitaly Pavlishchuk, Frank Birkelbach, Thomas Weyhermüller, Karl Wieghardt, and Phalguni Chaudhuri pp 4405 - 4416; DOI: 10.1021/ic011322m |
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Density Functional Calculations for Modeling the Oxidized States of the Active Site of Nickel-Iron Hydrogenases. 1. Verification of the Method with Paramagnetic Ni and Co Complexes Christian Stadler, Antonio L. de Lacey, Belén Hernández, Víctor M. Fernández, and Jose C. Conesa pp 4417 - 4423; DOI: 10.1021/ic020015t |
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Density Functional Calculations for Modeling the Active Site of Nickel-Iron Hydrogenases. 2. Predictions for the Unready and Ready States and the Corresponding Activation Processes Christian Stadler, Antonio L. de Lacey, Yael Montet, Anne Volbeda, Juan C. Fontecilla-Camps, Jose C. Conesa, and Víctor M. Fernández pp 4424 - 4434; DOI: 10.1021/ic020016l |
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Preparation and Structural Characterization of Ionic Five-Coordinate Palladium(II) and Platinum(II) Complexes of the Ligand Tris[2-(diphenylphosphino)ethyl]phosphine. Insertion of SnCl2 into M-Cl Bonds (M = Pd, Pt) and Hydroformylation Activity of the Pt-SnCl3 Systems Damián Fernández, M. Inés García-Seijo, Tamás Kégl, György Petocz, László Kollár, and M. Esther García-Fernández pp 4435 - 4443; DOI: 10.1021/ic020006k |
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Synthesis and Ligand-Based Mixed Valency of cis- and trans-CrIII(X4SQ)(X4Cat)(L)n (X = Cl and Br, n = 1 or 2) Complexes: Effects of Solvent Media on Intramolecular Charge Distribution and Ligand Dissociation of CrIII(X4SQ)3 Ho-Chol Chang, Katsunori Mochizuki, and Susumu Kitagawa pp 4444 - 4452; DOI: 10.1021/ic025643p |
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Solid-State Structural and Magnetic Investigations of {M[HC(3,5-Me2pz)3]2}(BF4)2 (M = Fe, Co, Ni, Cu): Observation of a Thermally Induced Solid-State Phase Change Controlling an Iron(II) Spin-State Crossover Daniel L. Reger, Christine A. Little, Mark D. Smith, and Gary J. Long pp 4453 - 4460; DOI: 10.1021/ic0112645 |
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Site Specificity of Metal Ions in Heterodinuclear Complexes Derived from an "End-Off" Compartmental Ligand Koji Abe, Kanako Matsufuji, Masaaki Ohba, and Hisashi kawapp 4461 - 4467; DOI: 10.1021/ic020002f |
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Synthesis and Catalytic Application of Octahedral Lewis Base Adducts of Dichloro and Dialkyl Dioxotungsten(VI) Fritz E. Kühn, Wen-Mei Xue, Ahmad Al-Ajlouni, Ana M. Santos, Shuliang Zang, Carlos C. Romão, Georg Eickerling, and Eberhardt Herdtweck pp 4468 - 4477; DOI: 10.1021/ic0200085 |
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EPR Spectra from "EPR-Silent" Species: High-Frequency and High-Field EPR Spectroscopy of Pseudotetrahedral Complexes of Nickel(II) J. Krzystek, Ju-Hyun Park, Mark W. Meisel, Michael A. Hitchman, Horst Stratemeier, Louis-Claude Brunel, and Joshua Telser pp 4478 - 4487; DOI: 10.1021/ic020198j |
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Characterization of the Side-On Coordinated Bissuperoxo Complexes of Aluminum FAl(O2)2, ClAl(O2)2, and BrAl(O2)2 with Triplet Electronic Ground States: A Combined Matrix IR and Quantum Chemical Study Jan Bahlo, Hans-Jörg Himmel, and Hansgeorg Schnöckel pp 4488 - 4495; DOI: 10.1021/ic020208g |
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Three-Dimensional Open-Framework Neodymium Oxalates with Organic Functional Groups Protruding in 12-Member Channels R. Vaidhyanathan, Srinivasan Natarajan, and C. N. R. Rao pp 4496 - 4501; DOI: 10.1021/ic020197r |
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A Family of Vanadate Esters of Monoionized and Diionized Aromatic 1,2-Diols: Synthesis, Structure, and Redox Activity Bharat Baruah, Samir Das, and Animesh Chakravorty pp 4502 - 4508; DOI: 10.1021/ic020259d |
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Reactions of a Ruthenium(II) Arene Antitumor Complex with Cysteine and Methionine Fuyi Wang, Haimei Chen, John A. Parkinson, Piedad del Socorro Murdoch, and Peter J. Sadler pp 4509 - 4523; DOI: 10.1021/ic025538f |
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Self-Assembling Vanadium Oxide Nanotubes by Organic Molecular Templates Xing Chen, Xiaoming Sun, and Yadong Li pp 4524 - 4530; DOI: 10.1021/ic020092o |
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Chromium Complexes of an Isomeric N-Donor Ligand, 2-[(N-Arylamino)phenylazo]pyridine: Amination Reactions, X-ray Structure, and Redox Properties Kunal K. Kamar, Amrita Saha, Alfonso Castiñeiras, Chen-Hsiung Hung, and Sreebrata Goswami pp 4531 - 4538; DOI: 10.1021/ic0201497 |
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Cadmium Cyclam Complexes: Interconversion of Cis and Trans Configurations and Fixation of CO2 Xiangyang Liang, John A. Parkinson, Simon Parsons, Michael Weishäupl, and Peter J. Sadler pp 4539 - 4547; DOI: 10.1021/ic0255050 |
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New Alkyl-Cobalt(III) Complexes Containing Chiral Centers in the Chelating System Renata Dreos, Alessandro Felluga, Giorgio Nardin, Lucio Randaccio, Mauro Sandri, and Giovanni Tauzher pp 4548 - 4554; DOI: 10.1021/ic025534a |
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Octahedral-Tetrahedral Equilibrium and Solvent Exchange of Cobalt(II) Ions in Primary Alkylamines Sen-ichi Aizawa and Shigenobu Funahashi pp 4555 - 4559; DOI: 10.1021/ic020289g |
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Growth of Compound BiIII- VIA-VIIA Crystals with Special Morphologies under Mild Conditions Liying Zhu, Yi Xie, Xiuwen Zheng, Xing Yin, and Xiaobo Tian pp 4560 - 4566; DOI: 10.1021/ic025527m |
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Solution and Solid-State Structure of the Anion [Ag2{closo-CB11H12}4]2- Mark A. Fox, Mary F. Mahon, Nathan J. Patmore, and Andrew S. Weller pp 4567 - 4573; DOI: 10.1021/ic025730h |
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The Structure of 1-Thia-closo-decaborane(9), 1-SB9H9, as Determined by Microwave Spectroscopy and Quantum Chemical Calculations Harald M llendal, Svein Samdal, Josef Holub, and Drahomír Hnykpp 4574 - 4578; DOI: 10.1021/ic025660e |
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Dinuclear Gold(I) Dithiophosphonate Complexes: Synthesis, Luminescent Properties, and X-ray Crystal Structures of [AuS2PR(OR')]2 (R = Ph, R' = C5H9; R = 4-C6H4OMe, R' = (1S,5R,2S)-(-)-Menthyl; R = Fc, R' = (CH2)2O(CH2)2OMe) Werner E. van Zyl, José M. López-de-Luzuriaga, Ahmed A. Mohamed, Richard J. Staples, and John P. Fackler, Jr. pp 4579 - 4589; DOI: 10.1021/ic0201856 |
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Supramolecular Gold(I) Thiobarbiturate Chemistry: Combining Aurophilicity and Hydrogen Bonding to Make Polymers, Sheets, and Networks William J. Hunks, Michael C. Jennings, and Richard J. Puddephatt pp 4590 - 4598; DOI: 10.1021/ic020178h |
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Flexible Square Supramolecular Rings with Hydrogen-Bonded Bushing in Solid-State Oxalurate Complexes: Versatility of the Oxalurate Ligand in Covalent and Noncovalent Binding Larry R. Falvello, Raquel Garde, and Milagros Tomás pp 4599 - 4604; DOI: 10.1021/ic025648m |
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Chemistry of Some Amino Acid Complexes of Ruthenium. Synthesis, Characterization, and DNA Binding Properties Kanchana Majumder, Ray J. Butcher, and Samaresh Bhattacharya pp 4605 - 4609; DOI: 10.1021/ic010775o |
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Preparative and Structural Studies on the Carbonyl Cyanides of Iron, Manganese, and Ruthenium: Fundamentals Relevant to the Hydrogenases Stephen M. Contakes, Sodio C. N. Hsu, Thomas B. Rauchfuss, and Scott R. Wilson: pp 4610 - 4610; DOI: 10.1021/ic020428u |
Issue 18
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pH-Controlled Fluorescent Emission in the Nickel(II) Complex of a Bifunctional Tetramine Macrocycle Luigi Fabbrizzi, Francesco Foti, Maurizio Licchelli, and Antonio Poggi pp 4612 - 4614; DOI: 10.1021/ic025620a |
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Ferromagnetism and Chirality in Two-Dimensional Cyanide-Bridged Bimetallic Compounds Eugenio Coronado, Carlos J. Gómez-García, Alicia Nuez, Francisco M. Romero, Eduard Rusanov, and Helen Stoeckli-Evans pp 4615 - 4617; DOI: 10.1021/ic0257219 |
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X-ray Crystal Structure of (5-Pentaphenylcyclopentadienyl){1- (5/6-phenyl)-2,3,4,5-tetraphenylcyclopentadienyl}iron(II), [Fe(5-C5Ph5){(5/6-C6H5)C5Ph4}], a Linkage Isomer of Decaphenylferrocene Leslie D. Field, Trevor W. Hambley, Paul A. Humphrey, Anthony F. Masters, and Peter Turner pp 4618 - 4620; DOI: 10.1021/ic025592w |
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Hydrothermal Synthesis of the First Vanadomolybdenum Polyoxocation with a "Metal-Bonded" Spherical Framework Wenbin Yang, Canzhong Lu, Xiaoping Zhan, and Honghui Zhuang pp 4621 - 4623; DOI: 10.1021/ic025679h |
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Synthesis, Structure, Properties, and Phosphatase-Like Activity of the First Heterodinuclear FeIIIMnII Complex with the Unsymmetric Ligand H2BPBPMP as a Model for the PAP in Sweet Potato Peter Karsten, Ademir Neves, Adailton J. Bortoluzzi, Mauricio Lanznaster, and Valderes Drago pp 4624 - 4626; DOI: 10.1021/ic025674k |
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Molecular Structures of Five-Coordinated Halide Ligated Iron(III) Porphyrin, Porphycene, and Corrphycene Complexes Yoshiki Ohgo, Saburo Neya, Takahisa Ikeue, Masashi Takahashi, Masuo Takeda, Noriaki Funasaki, and Mikio Nakamura pp 4627 - 4629; DOI: 10.1021/ic0256866 |
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Possible Nonactivated Conductivity of the Low-Dimensional Ternary Nitride Ca2GeN2 Josep M. Oliva and Enric Canadell pp 4630 - 4632; DOI: 10.1021/ic0256361 |
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A Periodic Walk: A Series of First-Row Transition Metal Complexes with the Pentadentate Ligand PY5 Robertus J. M. Klein Gebbink, Robert T. Jonas, Christian R. Goldsmith, and T. Daniel P. Stack pp 4633 - 4641; DOI: 10.1021/ic025617r |
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A Spectrochemical Walk: Single-Site Perturbation within a Series of Six-Coordinate Ferrous Complexes Christian R. Goldsmith, Robert T. Jonas, Adam P. Cole, and T. Daniel P. Stack pp 4642 - 4652; DOI: 10.1021/ic025616z |
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New Oxorhenium(V) Complexes from the Widely Used Diaminedithiol (DADT) Ligand System Katerina Chryssou, Maria Pelecanou, Ioannis C. Pirmettis, Minas S. Papadopoulos, Catherine Raptopoulou, Aris Terzis, Efstratios Chiotellis, and Chariklia I. Stassinopoulou pp 4653 - 4663; DOI: 10.1021/ic020247s |
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Flux Growth of Vanadyl Pyrophosphate, (VO)2P2O7, and Spin Dimer Analysis of the Spin Exchange Interactions of (VO)2P2O7 and Vanadyl Hydrogen Phosphate, VO(HPO4)·0.5H2O Hyun-Joo Koo, Myung-Hwan Whangbo, Paul D. VerNooy, Charlie C. Torardi, and William J. Marshall pp 4664 - 4672; DOI: 10.1021/ic020249c |
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New Synthetic Routes to Cationic Rhenium Tricarbonyl Bipyridine Complexes with Labile Ligands Eva Hevia, Julio Pérez, Víctor Riera, Daniel Miguel, Scott Kassel, and Arnold Rheingold pp 4673 - 4679; DOI: 10.1021/ic020174c |
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Binding of the Two-Valence-Electron Metal Ions Sc+, Ti2+, and V3+ to the Second-Row Hydrides BeH2, BH3, NH3, OH2, and FH: A Computational Study Charles W. Bock and Mendel Trachtman pp 4680 - 4688; DOI: 10.1021/ic020216x |
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Electronic Structure, Electrical and Magnetic Properties of RMo8O14 Compounds (R = La, Ce, Pr, Nd, Sm) Containing Bicapped Mo8 Clusters Régis Gautier, Ole Krogh Andersen, Patrick Gougeon, Jean-François Halet, Enric Canadell, and James D. Martin pp 4689 - 4699; DOI: 10.1021/ic020194e |
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Gallium and Gallium Dichloride, New Solid-State Reductants in Preparative Transition Metal Chemistry. New, Lower Temperature Syntheses and Convenient Isolation of Hexatantalum Tetradecachloride Octahydrate, Ta6(-Cl)12Cl2(OH2)4.4H2O, and Synthesis and Solid-State Structure of a Tetraalkylammonium Derivative, [N(CH2Ph)Bu3]4[Ta6(-Cl)12Cl6], of the Reduced [Ta6(-Cl)12]2+ Cluster Core Daniel N. T. Hay, Dale C. Swenson, and Louis Messerle pp 4700 - 4707; DOI: 10.1021/ic0201452 |
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The Effect of Ligand Charge on the Coordination Geometry of an Fe(III) Ion: Five- and Six-Coordinate Fe(III) Complexes of Tris(2-benzimidazolylmethyl)amine Dohyun Moon, Myoung Soo Lah, Rico E. Del Sesto, and Joel S. Miller pp 4708 - 4714; DOI: 10.1021/ic011155q |
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Tris(dimethylamino)oxosulfonium Difluorotrimethylsilicate, (Me2N)3SO+Me3SiF2- (TAOS Fluoride) Jens Wessel, Ulrich Behrens, Enno Lork, Tobias Borrmann, Wolf-Dieter Stohrer, and Rüdiger Mews pp 4715 - 4721; DOI: 10.1021/ic0201755 |
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Flattening of Rhodium Vertices in Mixed Rhodium-Nickel Carbonyl Clusters: Relationships to Borane and Zintl Ion Structures R. B. King pp 4722 - 4726; DOI: 10.1021/ic0202662 |
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Kinetics and Mechanism of Oxygen Atom Abstraction from a Dioxo-Rhenium(VII) Complex JaNeille Dixon and James H. Espenson pp 4727 - 4731; DOI: 10.1021/ic011166j |
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From Monomer Zinc-Oxamato Complexes to Tetranuclear Inverse 12-Membered and Octanuclear 12-Membered Metallacrowns Maria Alexiou, Catherine Dendrinou-Samara, Catherine P. Raptopoulou, Aris Terzis, and Dimitris P. Kessissoglou pp 4732 - 4738; DOI: 10.1021/ic0200904 |
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Conformation versus Coordination: Synthesis and Structural Investigations of Tellurium(II) Dithiolates Derived from -Donor-Substituted Thiols Holger Fleischer and Dieter Schollmeyer pp 4739 - 4747; DOI: 10.1021/ic020277v |
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Spectroscopic and Structural Assignment of the Absolute Stereochemistry in a Series of 1,2-Difluorovinyl Organometalloids. The First Crystallographic Characterization and Structural Series of Group 14 Fluorovinyl Compounds Alan K. Brisdon, Ian R. Crossley, Robin G. Pritchard, and John E. Warren pp 4748 - 4755; DOI: 10.1021/ic025593o |
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Characterization of a Soluble Molecular Magnet: Unusual Magnetic Behavior of Cyano-Bridged Gd(III)-Cr(III) Complexes with One-Dimensional and Nanoscaled Square Structures Hui-Zhong Kou, Song Gao, Chun-Hui Li, Dai-Zheng Liao, Bei-Chuan Zhou, Ru-Ji Wang, and Yadong Li pp 4756 - 4762; DOI: 10.1021/ic025704j |
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Metallic Conductivity and Ferromagnetic Interaction of Iron(III) d Spins in the Needle Crystals of (Ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)2·FeBr4 Salt Takuya Matsumoto, Tsuyoshi Kominami, Kazumasa Ueda, Toyonari Sugimoto, Toshiji Tada, Satoru Noguchi, Harukazu Yoshino, Keizo Murata, Motoo Shiro, Ei-ichi Negishi, Naoki Toyota, Satoshi Endo, and Kazuko Takahashi pp 4763 - 4769; DOI: 10.1021/ic020143h |
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Dichlorogallane (HGaCl2)2: Its Molecular Structure and Synthetic Potential Stefan Nogai and Hubert Schmidbaur pp 4770 - 4774; DOI: 10.1021/ic0203015 |
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Reactions of N-Silylphosphoranimines with Alcohols: Synthesis and Structure of Cyclotriphosphazenes with Nongeminal Methyl and Phenyl Substituents Patty Wisian-Neilson, Ralph S. Johnson, Hongming Zhang, June-Ho Jung, Robert H. Neilson, Junmin Ji, William H. Watson, and Mariusz Krawiec pp 4775 - 4779; DOI: 10.1021/ic025760k |
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Kinetic and Mechanistic Studies of Sulfur Transfer from Imidomethylrhenium Sulfides Wei-Dong Wang, Ilia A. Guzei, and James H. Espenson pp 4780 - 4787; DOI: 10.1021/ic0255196 |
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Peroxynitrite Decomposition Activity of Iron Porphyrin Complexes Michael P. Jensen and Dennis P. Riley pp 4788 - 4797; DOI: 10.1021/ic011089s |
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Zinc(II)/Ketoxime System as a Simple and Efficient Catalyst for Hydrolysis of Organonitriles Maximilian N. Kopylovich, Vadim Yu. Kukushkin, Matti Haukka, João J. R. Fraústo da Silva, and Armando J. L. Pombeiro pp 4798 - 4804; DOI: 10.1021/ic0256720 |
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Inter- and Intramolecular -Stacking Interactions in cis-Bis{1-(9-anthracene)}phosphirane Complexes of Platinum(II) Fan Yang, Philip E. Fanwick, and Clifford P. Kubiak pp 4805 - 4809; DOI: 10.1021/ic020061t |
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Protonation State of the Equatorial Ligands and Dynamics of the OH···O Units in a Cobaloxime Biomimetic Carme Rovira, Karel Kunc, and Michele Parrinello pp 4810 - 4814; DOI: 10.1021/ic025583n |
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Stoichiometric and Catalytic Oxygen Activation by Trimesityliridium(III) Bridey Grant Jacobi, David S. Laitar, Lihung Pu, Michael F. Wargocki, Antonio G. DiPasquale, Kevin C. Fortner, Stephany M. Schuck, and Seth N. Brown pp 4815 - 4823; DOI: 10.1021/ic025700e |
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Synthesis and Reactions of Group 6 Metal Half-Sandwich Complexes of 2,2-Dicyanoethylene-1,1-dichalcogenolates [(Cp*)M{E2C=C(CN)2}2]- (M = Mo, W; E = S, Se) Maochun Hong, Rong Cao, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi pp 4824 - 4833; DOI: 10.1021/ic025609a |
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(RO)2Ta[tris(2-oxy-3,5-dimethylbenzyl)amine]: Structure and Lactide Polymerization Activities Youngjo Kim, Pramesh N. Kapoor, and John G. Verkade pp 4834 - 4838; DOI: 10.1021/ic0257571 |
Issue 19
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Silver(III) Carbaporphyrins: The First Organometallic Complexes of True Carbaporphyrins Melanie A. Muckey, Lisa F. Szczepura, Gregory M. Ferrence, and Timothy D. Lash pp 4840 - 4842; DOI: 10.1021/ic020285b |
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A Novel Carboxylate-Free Ferromagnetic Trinuclear 3-Oxo-Manganese(III) Complex with Distorted Pentagonal-Bipyramidal Metal Centers Subramanya Gupta Sreerama and Samudranil Pal pp 4843 - 4845; DOI: 10.1021/ic0202559 |
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Pseudo-Polyrotaxane and -Sheet Layer-Based Three-Dimensional Coordination Polymers Constructed with Silver Salts and Flexible Pyridyl-Type Ligands Ming-Liang Tong, Yin-Miao Wu, Jie Ru, Xiao-Ming Chen, Ho-Chol Chang, and Susumu Kitagawa pp 4846 - 4848; DOI: 10.1021/ic0256922 |
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Transformation of Ammonium Dicyanamide into Dicyandiamide in the Solid Barbara Jürgens, Henning A. Höppe, Elisabeth Irran, and Wolfgang Schnick pp 4849 - 4851; DOI: 10.1021/ic025800k |
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From Linear Inorganic Chains to Helices: Chirality in the M(pyz)(H2O)2MoO2F4 (M = Zn, Cd) Compounds Paul A. Maggard, Amy L. Kopf, Charlotte L. Stern, Kenneth R. Poeppelmeier, Kang Min Ok, and P. Shiv Halasyamani pp 4852 - 4858; DOI: 10.1021/ic0255712 |
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Cobalt(II) and Cobalt(III) Dipicolinate Complexes: Solid State, Solution, and in Vivo Insulin-like Properties Luqin Yang, Debbie C. Crans, Susie M. Miller, Agnete la Cour, Oren P. Anderson, Peter M. Kaszynski, Michael E. Godzala, III, LaTanya D. Austin, and Gail R. Willsky pp 4859 - 4871; DOI: 10.1021/ic020062l |
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Modeling Substrate- and Inhibitor-Bound Forms of Liver Alcohol Dehydrogenase: Chemistry of Mononuclear Nitrogen/Sulfur-Ligated Zinc Alcohol, Formamide, and Sulfoxide Complexes Magdalena M. Makowska-Grzyska, Peter C. Jeppson, Russell A. Allred, Atta M. Arif, and Lisa M. Berreau pp 4872 - 4887; DOI: 10.1021/ic0255609 |
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Lewis Acidity of Gallium Halides Atsushi Ogawa and Hiroshi Fujimoto pp 4888 - 4894; DOI: 10.1021/ic020268m |
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New Cd(II)-, Co(II)-, and Cu(II)-Containing Coordination Polymers Synthesized by Using the Rigid Ligand 1,2-Bis(3-pyridyl)ethyne (3,3'-DPA) Md. Badruz Zaman, Mark D. Smith, Delia M. Ciurtin, and Hans-Conrad zur Loye pp 4895 - 4903; DOI: 10.1021/ic011305x |
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First CuII Diamondoid Net with 2-Fold Interpenetrating Frameworks. The Role of Anions in the Construction of the Supramolecular Arrays Miao Du, Xian-He Bu, Ya-Mei Guo, He Liu, Stuart R. Batten, Joan Ribas, and Thomas C. W. Mak pp 4904 - 4908; DOI: 10.1021/ic025559+ |
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[Ag2(C33H26N2O2)(H2O)2(SO3CF3)2]·0.5C6H6: A Luminescent Supramolecular Silver(I) Complex Based on Metal-Carbon and Metal-Heteroatom Interactions Yu-Bin Dong, Guo-Xia Jin, Mark D. Smith, Ru-Qi Huang, Bo Tang, and Hans-Conrad zur Loye pp 4909 - 4914; DOI: 10.1021/ic020228i |
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Organometallic Pt(II) Compounds. A Complementary Study of a Triplet Emitter Based on Optical High-Resolution and Optically Detected Magnetic Resonance Spectroscopy Hartmut Yersin, Dirk Donges, Werner Humbs, Johann Strasser, Rolf Sitters, and Max Glasbeek pp 4915 - 4922; DOI: 10.1021/ic020132o |
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Factors Influencing Conformer Equilibria in Retro Models of Cisplatin-DNA Adducts As Revealed by Moderately Dynamic (N,N'-Dimethyl-2,3-diaminobutane)PtG2 Retro Models (G = a Guanine Derivative) Jamil S. Saad, Tommaso Scarcia, Giovanni Natile, and Luigi G. Marzilli pp 4923 - 4935; DOI: 10.1021/ic011115m |
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Lanthanide-Transition-Metal Carbonyl Complexes. 1. Syntheses and Structures of Ytterbium(II) Solvent-Separated Ion Pairs and Isocarbonyl Polymeric Arrays of Tetracarbonylcobaltate Christine E. Ple nik, Shengming Liu, Jianping Liu, Xuenian Chen, Edward A. Meyers, and Sheldon G. Shorepp 4936 - 4943; DOI: 10.1021/ic020254g |
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Diastereoisomeric Singly Bridged Cyclophosphazene-Macrocyclic Compounds Iwona Porwolik-Czomperlik, Krystyna Brandt, T. Andrew Clayton, David B. Davies, Robert J. Eaton, and Robert A. Shaw pp 4944 - 4951; DOI: 10.1021/ic020264h |
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Matrix Reactivity of AlF and AlCl in the Presence of HCl and HBr: Generation and Characterization of the New Al(III) Hydrides HAlFCl, HAlFBr, and HAlClBr and the Monomeric Mixed Al(III) Halides AlX2Y (X, Y = F, Cl, or Br) Hans-Jörg Himmel, Jan Bahlo, Michael Haussmann, Fabian Kurth, Gregor Stösser, and Hansgeorg Schnöckel pp 4952 - 4960; DOI: 10.1021/ic020275a |
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Novel Intramolecular C-H Bond Activation in an Iridium dppm Complex Jackson S. Wiley and D. M. Heinekey pp 4961 - 4966; DOI: 10.1021/ic0257367 |
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Variation in the Coordination Mode of Arenedisulfonates: Syntheses and Structural Characterization of Mononuclear and Dinuclear Cadmium(II) Arenedisulfonate Complexes with Two- to Zero-Dimensional Architectures Cai-Hong Chen, Jiwen Cai, Cheng-Zhu Liao, Xiao-Long Feng, Xiao-Ming Chen, and Seik Weng Ng pp 4967 - 4974; DOI: 10.1021/ic020102l |
Issue 20
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Simultaneous N7,O6-Binding of Guanine to Two Zinc Centers and Its Possible Biological Significance Felix Zamora and Michal Sabat pp 4976 - 4977; DOI: 10.1021/ic0258532 |
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Nonlinear Optically Active Polymeric Coordination Networks Based on Metal m-Pyridylphosphonates Ponnaiyan Ayyappan, Owen R. Evans, Yong Cui, Kraig A. Wheeler, and Wenbin Lin pp 4978 - 4980; DOI: 10.1021/ic025819n |
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Hydrolytically Active Tetranuclear Nickel Complexes with Structural Resemblance to the Active Site of Urease Håkan Carlsson, Matti Haukka, and Ebbe Nordlander pp 4981 - 4983; DOI: 10.1021/ic025839p |
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Construction of a Functional Layered Solid Using the Tetrakis(imidazolyl)borate Coordinating Anion Barton H. Hamilton, Kathryn A. Kelly, Todd A. Wagler, Matthew P. Espe, and Christopher J. Ziegler pp 4984 - 4986; DOI: 10.1021/ic025796c |
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Dynamic Behavior in Diplatinum Metalloreceptors Andrew J. Baer, Bryan D. Koivisto, Adrien P. Côté, Nicholas J. Taylor, Garry S. Hanan, Hélène Nierengarten, and Alain Van Dorsselaer pp 4987 - 4989; DOI: 10.1021/ic0256819 |
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CuCN: A Polymorphic Material. Structure of One Form Determined from Total Neutron Diffraction Simon J. Hibble, Simon M. Cheyne, Alex C. Hannon, and Sharon G. Eversfield pp 4990 - 4992; DOI: 10.1021/ic0257569 |
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Tuning of Spin Density Wave Strengths in Quasi-One-Dimensional Mixed-Halogen-Bridged Nickel(III) Complexes with Strong Electron Correlation, [NiIII(chxn)2Cl1-xBrx](NO3)2 Toshio Manabe, Kohei Yokoyama, Sachie Furukawa, Chihiro Kachi-Terajima, Kazuya Nakata, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken-ichi Sugiura, Masahiro Yamashita, Hideo Kishida, and Hiroshi Okamoto pp 4993 - 4995; DOI: 10.1021/ic025654i |
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Large-Scale Synthesis of Sodium and Potassium Titanate Nanobelts Xiaoming Sun, Xing Chen, and Yadong Li pp 4996 - 4998; DOI: 10.1021/ic0257827 |
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Rhodium(I) and Rhodium(III) Complexes Containing the Chiral Ligand 2,6-Bis[4'(S)-isopropyloxazolin-2'-yl]pyridine (Pybox): An Unprecedented Monohapto Coordination of Pybox Darío Cuervo, Josefina Díez, M. Pilar Gamasa, S. García-Granda, and José Gimeno pp 4999 - 5001; DOI: 10.1021/ic025569a |
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First Fluorescent Ferrocenyl Compound as Multiresponsive Calcium-Sensing Device. NMR, Electrochemical, and Photophysical Preliminary Investigations in CH3CN Jérôme Maynadié, Béatrice Delavaux-Nicot, Suzanne Fery-Forgues, Dominique Lavabre, and René Mathieu pp 5002 - 5004; DOI: 10.1021/ic0257120 |
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Synthesis and Characterization of Volatile, Fluorine-Free -Ketoiminate Lanthanide MOCVD Precursors and Their Implementation in Low-Temperature Growth of Epitaxial CeO2 Buffer Layers for Superconducting Electronics Nikki L. Edleman, Anchuan Wang, John A. Belot, Andrew W. Metz, Jason R. Babcock, Amber M. Kawaoka, Jun Ni, Matthew V. Metz, Christine J. Flaschenriem, Charlotte L. Stern, Louise M. Liable-Sands, Arnold L. Rheingold, Paul R. Markworth, Robert P. H. Chang, Michael P. Chudzik, Carl R. Kannewurf, and Tobin J. Marks pp 5005 - 5023; DOI: 10.1021/ic020299h |
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A Ligand-Field Analysis of the trensal (H3trensal = 2,2',2' '-Tris(salicylideneimino)triethylamine) Ligand. An Application of the Angular Overlap Model to Lanthanides Bernadine M. Flanagan, Paul V. Bernhardt, Elmars R. Krausz, Stefan R. Lüthi, and Mark J. Riley pp 5024 - 5033; DOI: 10.1021/ic011276q |
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Water-Soluble Phosphines. 17.1 Novel Water-Soluble Secondary and Tertiary Phosphines with Disulfonated 1,1'-Biphenyl Backbones and Dibenzophosphole Moieties Oliver Herd, Dietmar Hoff, Konstantin W. Kottsieper, Christian Liek, Kirsten Wenz, Othmar Stelzer, and William S. Sheldrick pp 5034 - 5042; DOI: 10.1021/ic011239z |
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Experimental and Theoretical Study of the Transannular Intramolecular Interaction and Cage Effect in the Atrane Framework of Boratrane and 1-Methylsilatrane Alexander A. Korlyukov, Konstantin A. Lyssenko, Mikhail Yu. Antipin, Valerii N. Kirin, Eugenii A. Chernyshev, and Sergei P. Knyazev pp 5043 - 5051; DOI: 10.1021/ic010842e |
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Synthesis and Characterization of Novel Homoleptic N,N-Dialkylcarbamato Complexes of Antimony: Precursors for the Deposition of Antimony Oxides Graeme A. Horley, Mary F. Mahon, Kieran C. Molloy, Peter W. Haycock, and Christopher P. Myers pp 5052 - 5058; DOI: 10.1021/ic0202716 |
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One-Dimensional Assembling of Diiodo[phthalocyaninato(1-)] Chromate(III) Molecules through Neutral I2 Molecules. Alternating Ferro- and Antiferromagnetic Interactions in the Metal-Radical System Jan Janczak and Ynara Marina Idemori pp 5059 - 5065; DOI: 10.1021/ic020258l |
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Magnetic Semiconductor: Structural, Magnetic, and Conducting Properties of the Salts of the 6-Oxoverdazyl Radical Cation with M(dmit)2 Anions (M = Ni, Zn, Pd, and Pt, dmit = 1,3-dithiol-2-thione-4,5-dithiolate) K. Mukai, T. Hatanaka, N. Senba, T. Nakayashiki, Y. Misaki, K. Tanaka, K. Ueda, T. Sugimoto, and N. Azuma pp 5066 - 5074; DOI: 10.1021/ic020212s |
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Elucidating Drug-Metalloprotein Interactions with Tris(pyrazolyl)borate Model Complexes David T. Puerta and Seth M. Cohen pp 5075 - 5082; DOI: 10.1021/ic0204272 |
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Synthesis and Reactions of Triphenylsilanethiolato Complexes of Manganese(II), Iron(II), Cobalt(II), and Nickel(II) Takashi Komuro, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi pp 5083 - 5090; DOI: 10.1021/ic025715c |
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Octahedral (cis-Cyclam)iron(III) Complexes with O,N-Coordinated o-Iminosemiquinonate(1-) Radicals and o-Imidophenolate(2-) Anions Hyungphil Chun, Eckhard Bill, Eberhard Bothe, Thomas Weyhermüller, and Karl Wieghardt pp 5091 - 5099; DOI: 10.1021/ic020329g |
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Synthesis and Characterization of Completely Delocalized Mixed-Valent Dicopper Complexes Rajeev Gupta, Zhi Hui Zhang, Douglas Powell, Michael P. Hendrich, and A. S. Borovik pp 5100 - 5106; DOI: 10.1021/ic0202918 |
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Single-Molecule Magnets: Novel Mn8 and Mn9 Carboxylate Clusters Containing an Unusual Pentadentate Ligand Derived from Pyridine-2,6-dimethanol Colette Boskovic, Wolfgang Wernsdorfer, Kirsten Folting, John C. Huffman, David N. Hendrickson, and George Christou pp 5107 - 5118; DOI: 10.1021/ic020217p |
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Out-of-Center Distortions in d0 Transition Metal Oxide Fluoride Anions Margaret E. Welk, Alexander J. Norquist, Frederick P. Arnold, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 5119 - 5125; DOI: 10.1021/ic025622v |
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Mixed-Metal Uranium(VI) Iodates: Hydrothermal Syntheses, Structures, and Reactivity of Rb[UO2(CrO4)(IO3)(H2O)], A2[UO2(CrO4)(IO3)2] (A = K, Rb, Cs), and K2[UO2(MoO4)(IO3)2] Richard E. Sykora, Steven M. McDaniel, Daniel M. Wells, and Thomas E. Albrecht-Schmitt pp 5126 - 5132; DOI: 10.1021/ic025773y |
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Synthesis, Structure, and Magnetic Properties of the Single-Molecule Magnet [Ni21(cit)12(OH)10(H2O)10]16- Stefan T. Ochsenbein, Mark Murrie, Eduard Rusanov, Helen Stoeckli-Evans, Chihiro Sekine, and Hans U. Güdel pp 5133 - 5140; DOI: 10.1021/ic020252w |
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Architecture Dependence on the Steric Constrains of the Ligand in Cyano-Bridged Copper(I) and Copper(II)-Copper(I) Mixed-Valence Polymer Compounds Containing Diamines: Crystal Structures and Spectroscopic and Magnetic Properties Enrique Colacio, Raikko Kivekäs, Francesc Lloret, Markku Sunberg, José Suarez-Varela, Manuel Bardají, and Antonio Laguna pp 5141 - 5149; DOI: 10.1021/ic025743v |
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A Detailed Mechanistic Study of the Substitution Behavior of an Unusual Seven-Coordinate Iron(III) Complex in Aqueous Solution Ivana Ivanovic-Burmazovic, Mohamed S. A. Hamza, and Rudi van Eldik pp 5150 - 5161; DOI: 10.1021/ic0200803 |
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Pyrazolylcyclotriphosphazene Containing Pendant Polymers: Synthesis, Characterization, and Phosphate Ester Hydrolysis Using a Cu(II)-Metalated Cross-Linked Polymeric Catalyst Vadapalli Chandrasekhar, Arunachalampillai Athimoolam, S. G. Srivatsan, P. Shanmuga Sundaram, Sandeep Verma, Alexander Steiner, Stefano Zacchini, and Raymond Butcher pp 5162 - 5173; DOI: 10.1021/ic011159v |
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Self-Assembly of Polymer and Sheet Structures in Palladium(II) Complexes Containing Carboxylic Acid Substituents Zengquan Qin, Michael C. Jennings, Richard J. Puddephatt, and Kenneth W. Muir pp 5174 - 5186; DOI: 10.1021/ic020239b |
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Syntheses, Structures, and Electroluminescence of Ln2(acac-azain)4(-acac-azain)2 [acac-azain = 1-(N-7-azaindolyl)-1,3-butanedionato, Ln = Tb(III) and Y(III)] Ruiyao Wang, Datong Song, Corey Seward, Ye Tao, and Suning Wang pp 5187 - 5192; DOI: 10.1021/ic0111740 |
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Preparation of New Monoanionic "Scorpionate" Ligands: Synthesis and Structural Characterization of Titanium(IV) Complexes Bearing This Class of Ligand A. Otero, J. Fernández-Baeza, A. Antiñolo, F. Carrillo-Hermosilla, J. Tejeda, A. Lara-Sánchez, L. Sánchez-Barba, M. Fernández-López, A. M. Rodríguez, and I. López-Solera pp 5193 - 5202; DOI: 10.1021/ic020319f |
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Charge-Transfer Spectra of Structurally Characterized Mixed-Valence Thiolate-Bridged Cu(I)/Cu(II) Cluster Complexes Robert T. Stibrany, Ronald Fikar, Mark Brader, Marc N. Potenza, Joseph A. Potenza, and Harvey J. Schugar pp 5203 - 5215; DOI: 10.1021/ic020156v |
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Participation of Co-Ligands in Electronic Transitions of Platinum(II) Diazabutadiene Complexes Axel Klein, Joris van Slageren, and Stanislav Záli pp 5216 - 5225; DOI: 10.1021/ic025547o |
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Open-Framework Cadmium Succinates of Different Dimensionalities R. Vaidhyanathan, Srinivasan Natarajan, and C. N. R. Rao pp 5226 - 5234; DOI: 10.1021/ic020333s |
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Pseudoheptacoordination and Pseudohexacoordination in Tris(2-N,N-dimethylbenzylamino)phosphane A. Chandrasekaran, Natalya V. Timosheva, Roberta O. Day, and Robert R. Holmes pp 5235 - 5240; DOI: 10.1021/ic020153i |
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Ion Pair Charge-Transfer Complexes between Anionic and Cationic Metal-Dithiolenes [M(II) = Pd, Pt] Francesco Bigoli, Paola Deplano, Maria Laura Mercuri, Maria Angela Pellinghelli, Luca Pilia, Gloria Pintus, Angela Serpe, and Emanuele F. Trogu pp 5241 - 5248; DOI: 10.1021/ic025788w |
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Selective Synthesis and Characterization of CdSe Nanorods and Fractal Nanocrystals Qing Peng, Yajie Dong, Zhaoxiang Deng, and Yadong Li pp 5249 - 5254; DOI: 10.1021/ic0257266 |
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Phosphine and Phosphonite Complexes of a Ruthenium(II) Porphyrin. 1. Synthesis, Structure, and Solution State Studies Eugen Stulz, Michael Maue, Neil Feeder, Simon J. Teat, Yiu-Fai Ng, Andrew D. Bond, Scott L. Darling, and Jeremy K. M. Sanders pp 5255 - 5268; DOI: 10.1021/ic025727y |
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Phosphine and Phosphonite Complexes of a Ru(II) Porphyrin. 2. Photophysical and Electrochemical Studies Eugen Stulz, Jeremy K. M. Sanders, Marco Montalti, Luca Prodi, Nelsi Zaccheroni, Fabrizia Fabrizi de Biani, Emanuela Grigiotti, and Piero Zanello pp 5269 - 5275; DOI: 10.1021/ic025728q |
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New Chloro, -Oxo, and Alkyl Derivatives of Dioxomolybdenum(VI) and -Tungsten(VI) Complexes Chelated with N2O Tridentate Ligands: Synthesis and Catalytic Activities toward Olefin Epoxidation Yee-Lok Wong, Dennis K. P. Ng, and Hung Kay Lee pp 5276 - 5285; DOI: 10.1021/ic020173k |
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Synthesis and Characterization of a Series of (Hydroperoxo)-, (Alkylperoxo)-, and (-Peroxo)palladium Complexes Containing the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (TpiPr2): (TpiPr2)(py)Pd-OO-X [X = H, t-Bu, Pd(TpiPr2)(py)] and (TpiPr2)(py)Pd-(-1:2-OO)-PdTpiPr2 Taichi Miyaji, Masato Kujime, Shiro Hikichi, Yoshihiko Moro-oka, and Munetaka Akita pp 5286 - 5295; DOI: 10.1021/ic020355e |
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Syntheses and Structural Characterizations of the Unsymmetrical Diphosphene DmpP=PMes* (Dmp = 2,6-Mes2C6H3, Mes* = 2,4,6-tBu3C6H2) and the Cyclotetraphosphane [DmpPPPh]2 Rhett C. Smith, Eugenijus Urnezius, Kin-Chung Lam, Arnold L. Rheingold, and John D. Protasiewicz pp 5296 - 5299; DOI: 10.1021/ic025759l |
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X-ray Diffraction and 1H NMR in Solution: Structural Determination of Lanthanide Complexes of a Py2N6Ac4 Ligand L. Valencia, J. Martinez, A. Macías, R. Bastida, R. A. Carvalho, and C. F. G. C. Geraldes pp 5300 - 5312; DOI: 10.1021/ic0257017 |
Issue 21
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Heterobinuclear Complexes as Building Blocks in Designing Extended Structures Ruxandra Gheorghe, Marius Andruh, Achim Müller, and Marc Schmidtmann pp 5314 - 5316; DOI: 10.1021/ic020293s |
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New Single Source Route to the Molybdenum Nitride Mo2N Pavel Afanasiev pp 5317 - 5319; DOI: 10.1021/ic025564d |
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Comparative Preparations of Homoleptic Hydridic Anions of Iron and Ruthenium Using Solution-Based Organometal Hydrogenation Techniques Donald E. Linn, Jr., Gabriel M. Skidd, and Stacci N. Mc Vay pp 5320 - 5322; DOI: 10.1021/ic025748s |
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Luminescence Enhancement Induced by Aggregation of Alkoxy-Bridged Rhenium(I) Molecular Rectangles Bala. Manimaran, P. Thanasekaran, T. Rajendran, Ren-Jay Lin, I-Jy Chang, Gene-Hsiang Lee, Shie-Ming Peng, S. Rajagopal, and Kuang-Lieh Lu pp 5323 - 5325; DOI: 10.1021/ic020364n |
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A Tetranuclear Heterobimetallic Square Formed from the Cooperative Ligand Binding Properties of Square Planar and Tetrahedral Metal Centers Nathan C. Gianneschi, Chad A. Mirkin, Lev N. Zakharov, and Arnold L. Rheingold pp 5326 - 5328; DOI: 10.1021/ic025875o |
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Synthesis, Structural Characterization, and Reactions of Cyclic Organohydroborate Half-Zirconocene Compounds Errun Ding, Fu-Chen Liu, Shengming Liu, Edward A. Meyers, and Sheldon G. Shore pp 5329 - 5335; DOI: 10.1021/ic0202817 |
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Structural and Photophysical Properties of Heterobimetallic 4f-Zn Iminophenolate Cryptates Raquel Rodríguez-Cortiñas, Fernando Avecilla, Carlos Platas-Iglesias, Daniel Imbert, Jean-Claude G. Bünzli, Andrés de Blas, and Teresa Rodríguez-Blas pp 5336 - 5349; DOI: 10.1021/ic025587s |
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Electronic Structure of Reduced Symmetry Peripheral Fused-Ring-Substituted Phthalocyanines Nagao Kobayashi, John Mack, Kazuyuki Ishii, and Martin J. Stillman pp 5350 - 5363; DOI: 10.1021/ic011152d |
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Trigonal Bipyramidal Geometry and Tridentate Coordination Mode of the Tripod in FeCl2 Complexes with Tris(2-pyridylmethyl)amine Derivatives Bis--Substituted with Bulky Groups. Structures and Spectroscopic Comparative Studies Dominique Mandon, Ahmed Machkour, Sandrine Goetz, and Richard Welter pp 5364 - 5372; DOI: 10.1021/ic011104t |
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New Oxamato-Bridged Trinuclear CuII-CuII-CuII Complexes with Hydrogen-Bond Supramolecular Structures: Synthesis and Magneto-Structural Studies Javier Tercero, Carmen Diaz, Joan Ribas, José Mahía, and Miguel Angel Maestro pp 5373 - 5381; DOI: 10.1021/ic011081i |
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New Dirhenium(III) Compounds Bridged by Carboxylate Ligands: N(C4H9)4[Re2(OOCCF3)Cl6] and Re2(OOCCCHCo2(CO)6)4Cl2 Andrés Vega, Víctor Calvo, Jorge Manzur, Evgenia Spodine, and Jean-Yves Saillard pp 5382 - 5387; DOI: 10.1021/ic020234e |
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Differing Reactivities of (trimpsi)M(CO)2(NO) Complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3] with Halogens and Halogen Sources Trevor W. Hayton, Peter Legzdins, and Brian O. Patrick pp 5388 - 5396; DOI: 10.1021/ic020340g |
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Salen-Type Compounds of Calcium and Strontium Mario Sánchez, Melanie J. Harvey, Fredrick Nordstrom, Sean Parkin, and David A. Atwood pp 5397 - 5402; DOI: 10.1021/ic020101t |
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Spontaneous Reduction of a Low-Spin Fe(III) Complex of a Neutral Pentadentate N5 Schiff Base Ligand to the Corresponding Fe(II) Species in Acetonitrile Apurba K. Patra, Marilyn M. Olmstead, and Pradip K. Mascharak pp 5403 - 5409; DOI: 10.1021/ic020373w |
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Nitric Oxide Photorelease from Ruthenium Salen Complexes in Aqueous and Organic Solutions Jeane Bordini, David L. Hughes, Joaquim Delphino Da Motta Neto, and Carlos Jorge da Cunha pp 5410 - 5416; DOI: 10.1021/ic011273d |
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Kinetics and Mechanism of the Formation of Nitroprusside from Aquapentacyanoferrate(III) and NO: Complex Formation Controlled by Outer-Sphere Electron Transfer Federico Roncaroli, José A. Olabe, and Rudi van Eldik pp 5417 - 5425; DOI: 10.1021/ic020288o |
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Synthesis, Purification, and Structural Characterization of the Dimethyldiselenoarsinate Anion Jürgen Gailer, Graham N. George, Hugh H. Harris, Ingrid J. Pickering, Roger C. Prince, Arpad Somogyi, Gavin A. Buttigieg, Richard S. Glass, and M. Bonner Denton pp 5426 - 5432; DOI: 10.1021/ic0113146 |
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Iron(III) and Iron(IV) Corroles: Synthesis, Spectroscopy, Structures, and No Indications for Corrole Radicals Liliya Simkhovich, Israel Goldberg, and Zeev Gross pp 5433 - 5439; DOI: 10.1021/ic020118b |
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Copper-Bispidine Coordination Chemistry: Syntheses, Structures, Solution Properties, and Oxygenation Reactivity Heidi Börzel, Peter Comba, Karl S. Hagen, Marion Kerscher, Hans Pritzkow, Markus Schatz, Siegfried Schindler, and Olaf Walter pp 5440 - 5452; DOI: 10.1021/ic011114u |
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Precursors to Water-Soluble Dinitrogen Carriers. Synthesis of Water-Soluble Complexes of Iron(II) Containing Water-Soluble Chelating Phosphine Ligands of the Type 1,2-Bis(bis(hydroxyalkyl)phosphino)ethane Warren K. Miller, John D. Gilbertson, Carmen Leiva-Paredes, Paul R. Bernatis, Timothy J. R. Weakley, David K. Lyon, and David R. Tyler pp 5453 - 5465; DOI: 10.1021/ic025774q |
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Stabilization of Molecular LiF and LiFHF inside Metallamacrocyclic Hosts Marie-Line Lehaire, Rosario Scopelliti, and Kay Severin pp 5466 - 5474; DOI: 10.1021/ic025749k |
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Corynebactin and a Serine Trilactone Based Analogue: Chirality and Molecular Modeling of Ferric Complexes Martin E. Bluhm, Benjamin P. Hay, Sanggoo S. Kim, Emily A. Dertz, and Kenneth N. Raymond pp 5475 - 5478; DOI: 10.1021/ic025531y |
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Gd1.33Pt3(Al,Si)8 and Gd0.67Pt2(Al,Si)5: Two Structures Containing a Disordered Gd/Al Layer Grown in Liquid Aluminum S. E. Latturner and M. G. Kanatzidis pp 5479 - 5486; DOI: 10.1021/ic025623n |
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Substitution Reactions of [Fe4S4Cl4]2- with ButNC or Et2NCS2-: Trapping Intermediates and Detecting New Pathways Adrian J. Dunford and Richard A. Henderson pp 5487 - 5494; DOI: 10.1021/ic0202110 |
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Expanding the Remarkable Structural Diversity of Uranyl Tellurites: Hydrothermal Preparation and Structures of K[UO2Te2O5(OH)], Tl3{(UO2)2[Te2O5(OH)](Te2O6)}·2H2O, -Tl2[UO2(TeO3)2], and Sr3[UO2(TeO3)2](TeO3)2 Philip M. Almond and Thomas E. Albrecht-Schmitt pp 5495 - 5501; DOI: 10.1021/ic025820m |
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HostDesigner: A Program for the de Novo Structure-Based Design of Molecular Receptors with Binding Sites that Complement Metal Ion Guests Benjamin P. Hay and Timothy K. Firman pp 5502 - 5512; DOI: 10.1021/ic0202920 |
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Structural and Spectroscopic Features of a cis (Hydroxo)-FeIII-(Carboxylato) Configuration as an Active Site Model for Lipoxygenases Seiji Ogo, Ryo Yamahara, Mark Roach, Tomoyoshi Suenobu, Michihiko Aki, Takashi Ogura, Teizo Kitagawa, Hideki Masuda, Shunichi Fukuzumi, and Yoshihito Watanabe pp 5513 - 5520; DOI: 10.1021/ic0200040 |
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Ba(SbF6)2·5XeF2: First Xenon(II) Compound with Barium. Synthesis, Vibrational Spectra, and Crystal Structure Alenka Turi nik, Primo Benki, and Boris  emvapp 5521 - 5524; DOI: 10.1021/ic025670f |
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Reactions of Thioethers with Mn2(CO)7(-S2) Proceed with CO Displacement and Insertion of the Sulfur Atom into the Mn-Mn Bond Richard D. Adams, O.-Sung Kwon, and Mark D. Smith pp 5525 - 5529; DOI: 10.1021/ic020408s |
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Hydro/Solvothermal Synthesis and Structures of New Zinc Phosphates of Varying Dimensionality Srinivasan Natarajan pp 5530 - 5537; DOI: 10.1021/ic0203872 |
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Reduction of Octacyanomolybdate(V) by Thioglycolic Acid in Aqueous Media Basudeb Saha, Meiling Hung, and David M. Stanbury pp 5538 - 5543; DOI: 10.1021/ic025702z |
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Preparation of Highly Efficient Manganese Catalase Mimics Michael U. Triller, Wen-Yuan Hsieh, Vincent L. Pecoraro, Annette Rompel, and Bernt Krebs pp 5544 - 5554; DOI: 10.1021/ic025897a |
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Oxovanadium(V) and Cobalt(III) Complexes of Dithiocarbazate-Based Schiff Base Ligands: Formation of a Thiadiazole Ring by Vanadium-Induced Cyclization of the Coordinated Ligand Subodh Kanti Dutta, Satyabrata Samanta, Dipesh Ghosh, Ray J. Butcher, and Muktimoy Chaudhury pp 5555 - 5560; DOI: 10.1021/ic0200895 |
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A cis-IrL(CO) Group Responds to Increasing Steric Bulk of L by M-L Stretching, Not M-C-O Tilting or Bending Tiffany Dubé, J. W. Faller, and Robert H. Crabtree pp 5561 - 5565; DOI: 10.1021/ic020144+ |
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Synthesis, Structures, and Magnetic and Optical Properties of a Series of Europium(III) and Gadolinium(III) Complexes with Chelating Nitronyl and Imino Nitroxide Free Radicals Christophe Lescop, Dominique Luneau, Paul Rey, Guillaume Bussière, and Christian Reber pp 5566 - 5574; DOI: 10.1021/ic0257928 |
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Effect of Metal-Ligand Bond Lengths on Superexchange Interactions in Jahn-Teller d4 Ion Systems: Spin Dimer Analysis of the Magnetic Structure of Marokite CaMn2O4 Myung-Hwan Whangbo, Hyun-Joo Koo, Dadi Dai, and Dongwoon Jung pp 5575 - 5581; DOI: 10.1021/ic0202458 |
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Paramagnetic Cobalt(II) as a Probe for Kinetic and NMR Relaxation Studies of Phosphate Binding and the Catalytic Mechanism of Streptomyces Dinuclear Aminopeptidase Michael N. Harris, Craig M. Bertolucci, and Li-June Ming pp 5582 - 5588; DOI: 10.1021/ic025584f |
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DFT Investigation of the Tri(amino)amine N(NH2)32+ and the Tri(azido)amine N(N3)32+ Dications and Related Mixed Amino(azido)ammonium Ions (N3)xN(NH2)4-x+ (x = 0-4)1 Golam Rasul, G. K. Surya Prakash, and George. A. Olah pp 5589 - 5592; DOI: 10.1021/ic020358r |
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High Nuclearity Ruthenium-Tin Clusters from the Reactions of Triphenylstannane with Pentaruthenium Carbonyl Carbido Cluster Complexes Richard D. Adams, Burjor Captain, Wei Fu, and Mark D. Smith pp 5593 - 5601; DOI: 10.1021/ic0204169 |
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A Novel Group of Alkaline Earth Metal Amides: Syntheses and Characterization of M[N(2,6-iPr2C6H3)(SiMe3)]2(THF)2 (M = Mg, Ca, Sr, Ba) and the Linear, Two-Coordinate Mg[N(2,6-iPr2C6H3)(SiMe3)]2 Wilda Vargas, Ulrich Englich, and Karin Ruhlandt-Senge pp 5602 - 5608; DOI: 10.1021/ic0203668 |
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Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}·12H2O]n (Ln = Dy, Ho, Er, Y; oda = Oxydiacetate) Alberto C. Rizzi, Rafael Calvo, Ricardo Baggio, María Teresa Garland, Octavio Peña, and Mireille Perec pp 5609 - 5614; DOI: 10.1021/ic025754o |
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Double Silyl Migration Converting ORe[N(SiMe2CH2PCy2)2] to NRe[O(SiMe2CH2PCy2)2] Substructures Oleg V. Ozerov, Hélène F. Gerard, Lori A. Watson, John C. Huffman, and Kenneth G. Caulton pp 5615 - 5625; DOI: 10.1021/ic020424p |
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Rates and Mechanism of Fluoride and Water Exchange in UO2F53- and [UO2F4(H2O)]2- Studied by NMR Spectroscopy and Wave Function Based Methods Valérie Vallet, Ulf Wahlgren, Zoltán Szabó, and Ingmar Grenthe pp 5626 - 5633; DOI: 10.1021/ic025713s |
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New Mononuclear, Cyclic Tetranuclear, and 1-D Helical-Chain Cu(II) Complexes Formed by Metal-Assisted Hydrolysis of 3,6-Di-2-pyridyl-1,2,4,5-tetrazine (DPTZ): Crystal Structures and Magnetic Properties Xian-He Bu, He Liu, Miao Du, Lei Zhang, Ya-Mei Guo, Mitsuhiko Shionoya, and Joan Ribas: pp 5634 - 5634; DOI: 10.1021/ic020469q |
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First Anhydrous Gold Perchlorato Complex: ClO2Au(ClO4)4. Synthesis and Molecular and Crystal Structure Analysis Frédérique Cunin, Catherine Deudon, Frédéric Favier, Bernard Mula, and Jean Louis Pascal: pp 5634 - 5634; DOI: 10.1021/ic020560u |
Issue 22
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Hybrid Coordination Polymer Constructed from -Octamolybdates Linked by Quinoxaline and Its Oxidized Product Benzimidazole Coordinated to Binuclear Copper(I) Fragments Chuan-De Wu, Can-Zhong Lu, Hong-Hui Zhuang, and Jin-Shun Huang pp 5636 - 5637; DOI: 10.1021/ic025668o |
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Novel Oxovanadium Phosphate Tubule Incorporating 2,2-Bipyridine Ligands: Hydrothermal Synthesis and Crystal Structure of [(VIVO)3(5-PO4)2(2,2'-bpy)(-OH2)]·1/3H2O Wenbin Yang and Canzhong Lu pp 5638 - 5640; DOI: 10.1021/ic0257874 |
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New FeIIIZnII Complex Containing a Single Terminal Fe-Ophenolate Bond as a Structural and Functional Model for the Active Site of Red Kidney Bean Purple Acid Phosphatase Mauricio Lanznaster, Ademir Neves, Adailton J. Bortoluzzi, Bruno Szpoganicz, and Erineu Schwingel pp 5641 - 5643; DOI: 10.1021/ic025892d |
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The First Observation of Heteronuclear Two-Bond J-Coupling in the Solid State: Crystal Structure and Solid-State NMR Spectroscopy of Rb4(NbO)2(Si8O21) Hsien-Ming Kao and Kwang-Hwa Lii pp 5644 - 5646; DOI: 10.1021/ic0204373 |
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Air-Stable, Electron-Deficient Fe(II) Catalytic Porphyrins. Characterization and Molecular Structures of Rare High Spin Fe(II) Hexacoordinated Porphyrins Kathleen M. Barkigia, Magali Palacio, Yu Sun, Marc Nogues, Mark W. Renner, François Varret, Pierrette Battioni, Daniel Mansuy, and Jack Fajer pp 5647 - 5649; DOI: 10.1021/ic025869s |
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A Mixed-Ligand Coordination Polymer from the in Situ, Cu(I)-Mediated Isomerization of Bis(4-pyridyl)ethylene Jacqueline M. Knaust and Steven W. Keller pp 5650 - 5652; DOI: 10.1021/ic025836c |
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Long-Lived Emission from Platinum(II) Terpyridyl Acetylide Complexes Qing-Zheng Yang, Li-Zhu Wu, Zi-Xin Wu, Li-Ping Zhang, and Chen-Ho Tung pp 5653 - 5655; DOI: 10.1021/ic025580a |
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Toward Synthetic Analogues of Linked Redox and Catalytic Multimetal Sites in Proteins: A Model of the Histidine-Cysteine Bridged Dicopper Array Way-Zen Lee and William B. Tolman pp 5656 - 5658; DOI: 10.1021/ic025937a |
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Catalytic Mechanism of Matrix Metalloproteinases: Two-Layered ONIOM Study Vladimir Pelmenschikov and Per E. M. Siegbahn pp 5659 - 5666; DOI: 10.1021/ic0255656 |
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Reduction of the Pertechnetate Anion with Bidentate Phosphine Ligands Evan Freiberg, William M. Davis, Terrence Nicholson, Alan Davison, and Alun G. Jones pp 5667 - 5674; DOI: 10.1021/ic020032i |
Inelastic Neutron Scattering on Three Mixed-Valence Dodecanuclear Polyoxovanadate Clusters Reto Basler, Grégory Chaboussant, Andreas Sieber, Hanspeter Andres, Mark Murrie, Paul Kögerler, Hartmut Bögge, Debbie C. Crans, Erich Krickemeyer, Stefan Janssen, Hannu Mutka, Achim Müller, and Hans-Ulrich Güdel pp 5675 - 5685; DOI: 10.1021/ic0202099 |
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Unusual Magnetic Properties of One-Dimensional Molecule-Based Magnets Associated with a Structural Phase Transition Xiaoming Ren, Qingjin Meng, You Song, Changsheng Lu, Chuanjiang Hu, and Xiaoyuan Chen pp 5686 - 5692; DOI: 10.1021/ic0111637 |
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Ternary Nanoclusters of CuHgS, CuHgSe, and CuInS Diem T. T. Tran, Lianne M. C. Beltran, Collin M. Kowalchuk, Nicholas R. Trefiak, Nicholas J. Taylor, and John F. Corrigan pp 5693 - 5698; DOI: 10.1021/ic0110528 |
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Trifluoroacetylsulfenyl Trifluoroacetate, CF3C(O)-S-O-C(O)CF3, a Novel Compound with a Symmetrically Substituted S-O Bond: Synthesis, Spectroscopic Characterization, and Quantum Chemical Calculations S. E. Ulic, C. O. Della Védova, A. Hermann, H.-G. Mack, and H. Oberhammer pp 5699 - 5705; DOI: 10.1021/ic025659f |
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Structure, Insertion Electrochemistry, and Magnetic Properties of a New Type of Substitutional Solid Solutions of Copper, Nickel, and Iron Hexacyanoferrates/Hexacyanocobaltates Antje Widmann, Heike Kahlert, Irena Petrovic-Prelevic, Harm Wulff, J. V. Yakhmi, Nitin Bagkar, and Fritz Scholz pp 5706 - 5715; DOI: 10.1021/ic0201654 |
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New Layered Rubidium Rare-Earth Selenides: Syntheses, Structures, Physical Properties, and Electronic Structures for RbLnSe2 Bin Deng, Donald E. Ellis, and James A. Ibers pp 5716 - 5720; DOI: 10.1021/ic020324j |
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Redox and Spectroscopic Orbitals in Ru(II) and Os(II) Phenolate Complexes Tia E. Keyes, Deirdre Leane, Robert J. Forster, Colin G. Coates, John J. McGarvey, Mark N. Nieuwenhuyzen, Egbert Figgemeier, and Johannes G. Vos pp 5721 - 5732; DOI: 10.1021/ic0202561 |
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Six-Coordinate Co2+ with H2O and NH3 Ligands: Which Spin State Is More Stable? Ann M. Schmiedekamp, M. Dominic Ryan, and Robert J. Deeth pp 5733 - 5743; DOI: 10.1021/ic0257930 |
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Metal Substitution in the Active Site of Nitrogenase MFe7S9 (M = Mo4+, V3+, Fe3+) Timothy Lovell, Rhonda A. Torres, Wen-Ge Han, Tiqing Liu, David A. Case, and Louis Noodleman pp 5744 - 5753; DOI: 10.1021/ic020474u |
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Binuclear Mesogenic Copper(I) Isocyanide Complexes with an Unusual Inorganic Core Formed by Two Tetrahedra Sharing an Edge Mohamed Benouazzane, Silverio Coco, Pablo Espinet, and Joaquín Barberá pp 5754 - 5759; DOI: 10.1021/ic025703r |
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Kinetic, Mechanistic, and DFT Study of the Electrophilic Reactions of Nitrosyl Complexes with Hydroxide Federico Roncaroli, Mara E. Ruggiero, Douglas W. Franco, Guillermina L. Estiú, and José A. Olabe pp 5760 - 5769; DOI: 10.1021/ic025653q |
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ZINDO Calculations of the Ground State and Electronic Transitions in the Tetracyanonickelate Ion, Ni(CN)42- Yves A. Mantz and Ronald L. Musselman pp 5770 - 5777; DOI: 10.1021/ic025798x |
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New Iron(III) Phosphate Phases: Crystal Structure and Electrochemical and Magnetic Properties Yanning Song, Peter Y. Zavalij, Masatsugu Suzuki, and M. Stanley Whittingham pp 5778 - 5786; DOI: 10.1021/ic025688q |
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Reactivity of MII Metal-Substituted Derivatives of Pig Purple Acid Phosphatase (Uteroferrin) with Phosphate Mark B. Twitchett, Gerhard Schenk, Manuel A. S. Aquino, Douglas T.-Y. Yiu, Tai-Chu Lau, and A. Geoffrey Sykes pp 5787 - 5794; DOI: 10.1021/ic020037f |
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{ReIIICl3} Core Complexes with Bifunctional Single Amino Acid Chelates Sangeeta Ray Banerjee, Lihui Wei, Murali K. Levadala, Neva Lazarova, Vladimir O. Golub, Charles J. O'Connor, Karin A. Stephenson, John F. Valliant, John W. Babich, and Jon Zubieta pp 5795 - 5802; DOI: 10.1021/ic020391d |
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Novel Copper(II) Induced Formation of a Porphyrinogen Derivative: X-ray Structural, Spectroscopic, and Electrochemical Studies of Porphyrinogen Complexes of Cu(II) and Co(III) Complex of a Trispyrazolyl Tripodal Ligand Sachindranath Paul, Anil Kumar Barik, Shie Ming Peng, and Susanta Kumar Kar pp 5803 - 5809; DOI: 10.1021/ic0112185 |
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Structural Systematics for o-C6H4XY Ligands with X,Y= O, NH, and S Donor Atoms. o-Iminoquinone and o-Iminothioquinone Complexes of Ruthenium and Osmium Samaresh Bhattacharya, Parna Gupta, Falguni Basuli, and Cortlandt G. Pierpont pp 5810 - 5816; DOI: 10.1021/ic025766+ |
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Cyanide-Bridged Molecular Squares with Ferromagnetically Coupled d, d, and p Spin System Hiroki Oshio, Masashi Yamamoto, and Tasuku Ito pp 5817 - 5820; DOI: 10.1021/ic0256112 |
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Cyclic Trinuclear and Chain of Cyclic Trinuclear Copper(II) Complexes Containing a Pyramidal Cu3O(H) Core. Crystal Structures and Magnetic Properties of [Cu3(3-OH)(aaat)3(H2O)3](NO3)2·H2O [aaat = 3-Acetylamino-5-amino-1,2,4-triazolate] and {[Cu3(3-OH)(aat)3(3-SO4)]·6H2O}n [aat = 3-Acetylamino-1,2,4-triazolate]: New Cases of Spin-Frustrated Systems Sacramento Ferrer, Francesc Lloret, Ignacio Bertomeu, Gloria Alzuet, JoaquÃn Borrás, Santiago GarcÃa-Granda, Malva Liu-González, and Jaap G. Haasnoot pp 5821 - 5830; DOI: 10.1021/ic020179+ |
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Example of Highly Stereoregulated Ruthenium Amidine Complex Formation: Synthesis, Crystal Structures, and Spectral and Redox Properties of the Complexes [RuII(trpy){NC5H4-CH=N-N(C6H5)C(CH3)=NH}](ClO4)2 (1) and [RuII(trpy)(NC5H4-CH=N-NH-C6H5)Cl]ClO4 (2) (trpy = 2,2':6',2' '-Terpyridine) Biplab Mondal, Vedavati G. Puranik, and Goutam Kumar Lahiri pp 5831 - 5836; DOI: 10.1021/ic020351+ |
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Phosphine-Boranes as Bidentate Ligands: Formation of [8,8-2-{2-(BH3)·dppm}-nido-8,7-RhSB9H10] and [9,9-2-{2-(BH3)·dppm}-nido-9,7,8-RhC2B8H11] from [8,8-(2-dppm)-8-(1-dppm)-nido-8,7-RhSB9H10] and [9,9-(2-dppm)-9-(1-dppm)-nido-9,7,8-RhC2B8H11], Respectively Oleg Volkov, Ramón Macías, Nigam P. Rath, and Lawrence Barton pp 5837 - 5843; DOI: 10.1021/ic0258375 |
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Dichloroacetylene Is Not the Precursor to Dichlorinated Vinylcobaloxime and Vinylcobalamin in Cobalt Catalyzed Dechlorination of Perchloro- and Trichloroethylene Kevin M. McCauley, Scott R. Wilson, and Wilfred A. van der Donk pp 5844 - 5848; DOI: 10.1021/ic025714k |
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Features of the Thermodynamics of Two-Phase Distribution Reactions of Americium(III) and Europium(III) Nitrates into Solutions of 2,6-Bis[(bis(2-ethylhexyl)phosphino)methyl]pyridine N,P,P '-Trioxide Kenneth L. Nash, Claire Lavallette, Marian Borkowski, Robert T. Paine, and Xinmin Gan pp 5849 - 5858; DOI: 10.1021/ic025707w |
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Synthesis and Characterization of Mixed-Substituent N-Silylphosphoranimines John R. Klaehn and Robert H. Neilson pp 5859 - 5865; DOI: 10.1021/ic025761c |
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Iron Complexes of 5,10,15,20-Tetraphenyl-21-oxaporphyrin Mi osz Pawlicki and Lechosaw Latos-Grayskipp 5866 - 5873; DOI: 10.1021/ic025718p |
Rotational Isomers of N-Alkylpyridylporphyrins and Their Metal Complexes. HPLC Separation, 1H NMR and X-ray Structural Characterization, Electrochemistry, and Catalysis of O2 - DisproportionationIvan Spasojevi , Ramil Menzeleev, Peter S. White, and Irwin Fridovichpp 5874 - 5881; DOI: 10.1021/ic025556x |
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Bond Dissociation Energies and Structures of CuNO+ and Cu(NO)2+ Konrad Koszinowski, Detlef Schröder, Helmut Schwarz, Max C. Holthausen, Joachim Sauer, Hideya Koizumi, and P. B. Armentrout pp 5882 - 5890; DOI: 10.1021/ic020315a |
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High-Spin Molecules: Synthesis, X-ray Characterization, and Magnetic Behavior of Two New Cyano-Bridged NiII9MoV6 and NiII9WV6 Clusters with a S = 12 Ground State Federica Bonadio, Mathias Gross, Helen Stoeckli-Evans, and Silvio Decurtins pp 5891 - 5896; DOI: 10.1021/ic025562t |
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Gas-Phase Chemistry of Bare and Oxo-Ligated Protactinium Ions: A Contribution to a Systematic Understanding of Actinide Chemistry John K. Gibson and Richard G. Haire pp 5897 - 5906; DOI: 10.1021/ic025683t |
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Photoelectron Spectroscopy of Bis(2,4-Pentanedione)-Oxovanadium(IV) [VO(acac)2] and Derivatives: Substituent Effects on the 2,4-Pentanedione Donor Nadine E. Gruhn, Laura J. Michelsen, and Barry L. Westcott pp 5907 - 5911; DOI: 10.1021/ic0256056 |
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Acid-Base Equilibrium of Aqua-Chromium-Dioxolene Complexes Aimed at Formation of Oxo-Chromium Complexes Kazushi Shiren and Koji Tanaka pp 5912 - 5919; DOI: 10.1021/ic020308m |
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Synthesis and Characterization of K38Nb7As24 and Cs9Nb2As6: The First Mixed-Valence Transition-Metal Zintl Phases Franck Gascoin and Slavi C. Sevov pp 5920 - 5924; DOI: 10.1021/ic020250b |
Issue 23
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Ab Initio Quantum Calculation of the Diabatic Coupling Matrix Elements for the Self-Exchange Redox Couples M(Cp)20/+ (M = Fe, Co; Cp = C5H5) Mu-Hyun Baik, Joseph B. Crystal, and Richard A. Friesner pp 5926 - 5927; DOI: 10.1021/ic025895q |
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"ortho-Wurster's Crowns": Synthesis and Properties of a Novel Phenylenediamine-Based Redox-Active Macrocyclic Ligand John W. Sibert and Philip B. Forshee pp 5928 - 5930; DOI: 10.1021/ic0259235 |
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Unusual Magnetic Property Associated with Dimerization within a Nickel Tetramer Xiaoming Ren, Qingjin Meng, You Song, Chuanjiang Hu, Changsheng Lu, Xiaoyuan Chen, and Ziling Xue pp 5931 - 5933; DOI: 10.1021/ic0255860 |
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Coupling of Coordinated 2-Iminophosphorano-1-phosphaallyl Leading to Bridged Iminophosphoranato Complexes of Zirconium and Hafnium Zhong-Xia Wang and Ye-Xin Li pp 5934 - 5936; DOI: 10.1021/ic0259179 |
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Trans Ruthenium(II) Complexes with NH-Bridged Tetradentate Symmetric and Asymmetric Polypyridyl Ligands Javier Concepción, Oliver Just, Ana María Leiva, Barbara Loeb, and William S. Rees, Jr. pp 5937 - 5939; DOI: 10.1021/ic025719h |
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Self-Assembly of Nanoscale, Porous T-Symmetric Molecular Adamantanoids Yong Cui, Helen L. Ngo, and Wenbin Lin pp 5940 - 5942; DOI: 10.1021/ic025804p |
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Ferromagnetic Coupling between Low- and High-Spin Iron(III) Ions in the Tetranuclear Complex fac-{[FeIII{HB(pz)3}(CN)2(-CN)]3FeIII(H2O)3}· 6H2O ([HB(pz)3]- = Hydrotris(1-pyrazolyl)borate) Rodrigue Lescouëzec, Jacqueline Vaissermann, Francesc Lloret, Miguel Julve, and Michel Verdaguer pp 5943 - 5945; DOI: 10.1021/ic020374o |
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Association Patterns of Platinated Purine Nucleobases in Metal-Modified Pairs and Triples Michael Roitzsch, Irene B. Rother, Michael Willermann, Andrea Erxleben, Burkhard Costisella, and Bernhard Lippert pp 5946 - 5953; DOI: 10.1021/ic020403v |
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The Effect of Substituents on the Phenyl Portion of the Imido Ligand on the Structure and Properties of Molybdenum(VI) Imido Complexes Martin Minelli, My Le Hoang, Michael Kraus, Gena Kucera, Jennifer Loertscher, Mark Reynolds, Nathan Timm, Michael Y. Chiang, and Douglas Powell pp 5954 - 5960; DOI: 10.1021/ic025642x |
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Nonstoichiometric Spinel Ferrites Obtained from -NaFeO2 via Molten Media Reactions Emilio Morán, M Carmen Blesa, M.-Eloisa Medina, Jesús D. Tornero, Nieves Menéndez, and Ulises Amador pp 5961 - 5967; DOI: 10.1021/ic011302k |
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Crystal Field Effects on the Optical Absorption and Luminescence Properties of Ni2+-Doped Chlorides and Bromides: Crossover in the Emitting Higher Excited State Oliver S. Wenger, Sophie Bénard, and Hans U. Güdel pp 5968 - 5977; DOI: 10.1021/ic020347y |
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Design and Crystal Structures of Triple Helicates with Crystallographic Idealized D3 Symmetry: The Role of Side Chain Effect on Crystal Packing Guo Dong, Pang Ke-liang, Duan Chun-ying, He Cheng, and Meng Qing-jin pp 5978 - 5985; DOI: 10.1021/ic0203623 |
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Synthesis and Characterization of Diametrically Substituted Tetra-O-n-butylcalix[4]arene Ligands and Their Chelated Complexes of Titanium, Molybdenum, and Palladium Daniel R. Evans, Mingsheng Huang, James C. Fettinger, and Tracie L. Williams pp 5986 - 6000; DOI: 10.1021/ic020446b |
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Nanocrystalline Tin as a Preparative Tool: Synthesis of Unprotected Nanoparticles of SnTe and SnSe and a New Route to (PhSe)4Sn Sabine Schlecht, Michael Budde, and Lorenz Kienle pp 6001 - 6005; DOI: 10.1021/ic020272y |
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Elimination of HX (X = Cl, Br) from Haloalkenes on the Ru2Q2 (Q = S, Se) Core Complex Shiho Hatemata, Hiroyasu Sugiyama, Saori Sasaki, and Kazuko Matsumoto pp 6006 - 6012; DOI: 10.1021/ic020499t |
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Pyrazolylborate-Zinc-Nucleobase-Complexes, 2:1 Preparations and Structures of TpCum,MeZn and TpPh,MeZn Complexes Dirk Badura and Heinrich Vahrenkamp pp 6013 - 6019; DOI: 10.1021/ic020280e |
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Pyrazolylborate-Zinc-Nucleobase-Complexes, 3:1 Base Pairing Studies Dirk Badura and Heinrich Vahrenkamp pp 6020 - 6027; DOI: 10.1021/ic020279f |
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Extraction of Pertechnetate and Perrhenate from Water with Deep-Cavity [CpFe(arene)]+-Derivatized Cyclotriveratrylenes James A. Gawenis, K. Travis Holman, Jerry L. Atwood, and Silvia S. Jurisson pp 6028 - 6031; DOI: 10.1021/ic0202312 |
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Dianionic Platinadiphospholene Complexes Cornelia Tirla, Nicolas Mézailles, Louis Ricard, François Mathey, and Pascal Le Floch pp 6032 - 6037; DOI: 10.1021/ic020103d |
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Mononuclear Ca(II)-Bulky Aryl-Phosphate Monoanion and Dianion Complexes with Ortho-Amide Groups Akira Onoda, Yusuke Yamada, Taka-aki Okamura, Hitoshi Yamamoto, and Norikazu Ueyama pp 6038 - 6047; DOI: 10.1021/ic010570f |
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Holo- and Hemidirected Lead(II) in the Polymeric [Pb4(-3,4-TDTA)2(H2O)2]·4H2O Complex. N,N,N',N'-Tetraacetate Ligands Derived from o-Phenylenediamines as Sequestering Agents for Lead(II) Joaquín Sanchiz, Pedro Esparza, Diego Villagra, Sixto Domínguez, Alfredo Mederos, Felipe Brito, Lorena Araujo, Agustin Sánchez, and Juan Manuel Arrieta pp 6048 - 6055; DOI: 10.1021/ic0201304 |
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Isolation of the New Cubic Phases RE4FeGa12-xGex (RE = Sm, Tb; x = 2.5) from Molten Gallium: Single-Crystal Neutron Diffraction Study of the Ga/Ge Distribution Marina A. Zhuravleva, Xiaoping Wang, Arthur J. Schultz, Thomas Bakas, and Mercouri G. Kanatzidis pp 6056 - 6061; DOI: 10.1021/ic025544b |
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Peculiar Antiaromatic Inorganic Molecules of Tetrapnictogen in Na+Pn4- (Pn = P, As, Sb) and Important Consequences for Hydrocarbons Aleksey E. Kuznetsov, Hua-Jin Zhai, Lai-Sheng Wang, and Alexander I. Boldyrev pp 6062 - 6070; DOI: 10.1021/ic020426+ |
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Application of Time-Resolved Infrared Spectroscopy to Electronic Structure in Metal-to-Ligand Charge-Transfer Excited States Dana M. Dattelbaum, Kristin M. Omberg, Jon R. Schoonover, Richard L. Martin, and Thomas J. Meyer pp 6071 - 6079; DOI: 10.1021/ic020400i |
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One-Dimensional Polymers Containing Strictly Collinear Metal Ions: Synthesis and XRPD Characterization of Homoleptic Binary Metal Pyrazolates Norberto Masciocchi, G. Attilio Ardizzoia, Stefano Brenna, Girolamo LaMonica, Angelo Maspero, Simona Galli, and Angelo Sironi pp 6080 - 6089; DOI: 10.1021/ic025821e |
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Synthesis and Structures of Niobium(V) Complexes Stabilized by Linear-Linked Aryloxide Trimers Tsukasa Matsuo and Hiroyuki Kawaguchi pp 6090 - 6098; DOI: 10.1021/ic025882c |
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Hypohalite Ion Catalysis of the Disproportionation of Chlorine Dioxide Lu Wang and Dale W. Margerum pp 6099 - 6105; DOI: 10.1021/ic020440m |
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New Lead Inorganic-Organic Hybrid Microporous and Layered Materials: Synthesis, Properties, and Crystal Structures Jiang-Gao Mao, Zhike Wang, and Abraham Clearfield pp 6106 - 6111; DOI: 10.1021/ic020396a |
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Lanthanide Complexes of [-2-P2W17O61]10-: Solid State and Solution Studies Qunhui Luo, Robertha C. Howell, Judit Bartis, Michaela Dankova, William DeW. Horrocks, Jr., Arnold L. Rheingold, and Lynn C. Francesconi pp 6112 - 6117; DOI: 10.1021/ic011187d |
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Hexaalkylguanidinium and 2-(Dialkylamino)-1,3-dimethylimidazolinium Trimethyldifluorosiliconates and Perfluoroalkoxides. Accidental Isolation and Molecular Structure of [C(NMe2)3]+F-·6CH2Cl2 Alexander A. Kolomeitsev, German Bissky, Jan Barten, Natalya Kalinovich, Enno Lork, and Gerd-Volker Röschenthaler pp 6118 - 6124; DOI: 10.1021/ic020081v |
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Structure of a Fluorinated Azoxy Compound: Fluoro(trifluoromethyl)-diazene-2-oxide, CF3N(O)NF Christiane Leibold, Jerry Foropoulos, Jr., Helen M. Marsden, Jean'ne M. Shreeve, and Heinz Oberhammer pp 6125 - 6128; DOI: 10.1021/ic020328o |
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Water Soluble Molecular Switches of Fluorescence Based on the NiIII/NiII Redox Change Luigi Fabbrizzi, Maurizio Licchelli, Stefano Mascheroni, Antonio Poggi, Donatella Sacchi, and Michele Zema pp 6129 - 6136; DOI: 10.1021/ic025826b |
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Reactivity of 3d Transition Metal Cations in Diethylene Glycol Solutions. Synthesis of Transition Metal Ferrites with the Structure of Discrete Nanoparticles Complexed with Long-Chain Carboxylate Anions Daniela Caruntu, Yann Remond, Nam Hawn Chou, Moo-Jin Jun, Gabriel Caruntu, Jibao He, Galina Goloverda, Charles O'Connor, and Vladimir Kolesnichenko pp 6137 - 6146; DOI: 10.1021/ic025664j |
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Synthesis and Characterization of the First Azastibatranes and Azabismatranes Pavel L. Shutov, Sergey S. Karlov, Klaus Harms, Daniil A. Tyurin, Andrei V. Churakov, Jörg Lorberth, and Galina S. Zaitseva pp 6147 - 6152; DOI: 10.1021/ic0257423 |
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Structural, Electronic, and Magnetic Consequences of O-Carbonyl vs O-Alkoxy Ester Coordination in New Dicopper Complexes Containing the Cu2(-Cl)2 Core Pratibha Kapoor, Anuradha Pathak, Ramesh Kapoor, Paloth Venugopalan, Montserrat Corbella, Montserrat RodrÃguez, Juvencio Robles, and Antoni Llobet pp 6153 - 6160; DOI: 10.1021/ic025568i |
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Syntheses and Characterizations of Copper(II) Polymeric Complexes Constructed from 1,2,4,5-Benzenetetracarboxylic Acid Rong Cao, Qian Shi, Daofeng Sun, Maochun Hong, Wenghua Bi, and Yingjun Zhao pp 6161 - 6168; DOI: 10.1021/ic0258577 |
Issue 24
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Conversion of a Re(IV) Tetrahedral Cluster to a Re(III) Octahedral Cluster: Synthesis of [(CH3)C(NH2)2]4[Re6Se8(CN)6] by a Solvothermal Route Mehtap Emirdag-Eanes and James A. Ibers pp 6170 - 6171; DOI: 10.1021/ic020433y |
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Analysis of Molecular Square Size and Purity via Pulsed-Field Gradient NMR Spectroscopy William H. Otto, Melinda H. Keefe, Kathryn E. Splan, Joseph T. Hupp, and Cynthia K. Larive pp 6172 - 6174; DOI: 10.1021/ic020334k |
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Novel Concentration-Driven Structural Interconversion in Shape-Specific Solids Supported by the Octahedral [Re6(3-Se)8]2+ Cluster Core Hugh D. Selby, Peter Orto, Michael D. Carducci, and Zhiping Zheng pp 6175 - 6177; DOI: 10.1021/ic025925p |
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Novel Luminescent Hexanuclear Platinum(II) Alkynyl Complex: Molecular Lego from a Face-to-Face Dinuclear Platinum(II) Building Block Chi-Kuen Hui, Ben Wai-Kin Chu, Nianyong Zhu, and Vivian Wing-Wah Yam pp 6178 - 6180; DOI: 10.1021/ic025685d |
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N-(2-Mercaptoethyl)picolylamine as a Diaminomonothiolate Ligand for the "fac-[Re(CO)3]+" Core Daniel J. Kramer, Alan Davison, William M. Davis, and Alun G. Jones pp 6181 - 6183; DOI: 10.1021/ic025887+ |
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C4N3OH7·Zn(H2O)HPO4, a Neutral Zincophosphate Cluster Iona Macdonald and William T. A. Harrison pp 6184 - 6186; DOI: 10.1021/ic025886h |
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Luminescence of the Nonclassical Homoleptic Metal Carbonyl Complex [Rh(CO)4]+ Theodore W. Bitner, Jeffrey I. Zink, Matthew D. Havighurst, and Steven H. Strauss pp 6187 - 6189; DOI: 10.1021/ic0203062 |
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Interligand Interactions Controlling the -N7,N9-Metal Bonding of Adenine (AdeH) to the N-Benzyliminodiacetato(2-) Copper(II) Chelate and Promoting the N9 versus N3 Tautomeric Proton Transfer: Molecular and Crystal Structure of [Cu2(NBzIDA)2(H2O)2(-N7,N9-Ade(N3)H)]·3H2O Perla X. Rojas-González, Alfonso Castiñeiras, Josefa M. González-Pérez, Duane Choquesillo-Lazarte, and Juan Niclós-Gutiérrez pp 6190 - 6192; DOI: 10.1021/ic025881k |
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New Class of Diiron Dithiolates Related to the Fe-Only Hydrogenase Active Site: Synthesis and Characterization of [Fe2(SR)2(CNMe)7]2+ Joshua D. Lawrence, Thomas B. Rauchfuss, and Scott R. Wilson pp 6193 - 6195; DOI: 10.1021/ic025919t |
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Visible Light Induced Photocleavage of DNA by a Mixed-Metal Supramolecular Complex: [{(bpy)2Ru(dpp)}2RhCl2]5+ Shawn Swavey and Karen J. Brewer pp 6196 - 6198; DOI: 10.1021/ic0257726 |
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Cation Substitutional Chemistry in the R7X12Z-Type Structure for Four Lanthanum Iodide Examples Elizabeth A. Jensen and John D. Corbett pp 6199 - 6205; DOI: 10.1021/ic020404n |
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Formation of the Magic Cluster Na8 in Noble Gas Matrixes Andreas Kornath, Anja Zoermer, and Ralf Ludwig pp 6206 - 6210; DOI: 10.1021/ic011161m |
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Analysis of Problematic Complexing Behavior of Ferric Chloride with N,N-Dimethylformamide Using Combined Techniques of FT-IR, XPS, and TGA/DTG Young Jeon Kim and Chong Rae Park pp 6211 - 6216; DOI: 10.1021/ic011306p |
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Providing a Chemical Basis toward Understanding the Histidine Base-On Motif of Methylcobalamin-Dependent Methionine Synthase: An Improved Purification of Methylcobinamide, plus Thermodynamic Studies of Methylcobinamide Binding Exogenous Imidazole and Pyridine Bases Jeanne Sirovatka Dorweiler, Rowena G. Matthews, and Richard G. Finke pp 6217 - 6224; DOI: 10.1021/ic010265u |
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Models for Cytochromes c': Spin States of Mono(imidazole)-Ligated (meso-Tetramesitylporphyrinato)iron(III) Complexes as Studied by UV-Vis, 13C NMR, 1H NMR, and EPR Spectroscopy Akira Ikezaki and Mikio Nakamura pp 6225 - 6236; DOI: 10.1021/ic020378t |
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N,N,N ',N '-Tetrakis(2-pyridylmethyl)ethylenediamine and Its Analogues as Hypodentate Ligands. Synthesis and Characterization of the Rhodium(III), Ruthenium(II), and Palladium(II) Complexes Maxim Sokolov, Keisuke Umakoshi, and Yoichi Sasaki pp 6237 - 6243; DOI: 10.1021/ic0203264 |
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Coordination Chemistry of Tripyridinedimethane Andrei N. Vedernikov, John C. Huffman, and Kenneth G. Caulton pp 6244 - 6248; DOI: 10.1021/ic025708o |
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Synthesis and Structures of Gallium Amido Imido Phenyl Clusters (PhGa)4(NHiBu)4(NiBu)2 and (PhGa)7(NHMe)4(NMe)5 Bing Luo and Wayne L. Gladfelter pp 6249 - 6257; DOI: 10.1021/ic020093g |
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Light-Driven Tyrosine Radical Formation in a Ruthenium-Tyrosine Complex Attached to Nanoparticle TiO2 Raed Ghanem, Yunhua Xu, Jie Pan, Tobias Hoffmann, Johan Andersson, Tomá Polívka, Torbjörn Pascher, Stenbjörn Styring, Licheng Sun, and Villy Sundströmpp 6258 - 6266; DOI: 10.1021/ic020472+ |
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Reactions of Acetonitrile Coordinated to a Nitrosylruthenium Complex with H2O or CH3OH under Mild Conditions: Structural Characterization of Imido-Type Complexes Hirotaka Nagao, Toshiyuki Hirano, Naotoshi Tsuboya, Soni Shiota, Masao Mukaida, Takao Oi, and Mikio Yamasaki pp 6267 - 6273; DOI: 10.1021/ic011241q |
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Syntheses, Structure, and Photoluminescence Properties of the 1-Dimensional Chain Compounds [(TPA)2Au][Au(CN)2] and (TPA)AuCl (TPA = 1,3,5-Triaza-7-phosphaadamantane) Zerihun Assefa, Mohammad A. Omary, Brian G. McBurnett, Ahmed A. Mohamed, Howard H. Patterson, Richard J. Staples, and John P. Fackler, Jr. pp 6274 - 6280; DOI: 10.1021/ic025784r |
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Disulfides of Manganese Carbonyl. Synthesis of Mn2(CO)7(-S2) and Its Reactions with Tertiary Phosphines and Arsines Richard D. Adams, O-Sung Kwon, and Mark D. Smith pp 6281 - 6290; DOI: 10.1021/ic0203670 |
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Factors Affecting Metal-Metal Bonding in the Face-Shared d3d3 Bioctahedral Dimer Systems, MM'Cl95- (M, M' = V, Nb, Ta) Simon Petrie and Robert Stranger pp 6291 - 6297; DOI: 10.1021/ic011250z |
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Group-4 1-Pyrrolyl Complexes Incorporating N,N-Di(pyrrolyl--methyl)-N-methylamine Yahong Li, Angie Turnas, James T. Ciszewski, and Aaron L. Odom pp 6298 - 6306; DOI: 10.1021/ic0259484 |
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Copper Chemistry of -Diketiminate Ligands: Monomer/Dimer Equilibria and a New Class of Bis(-oxo)dicopper Compounds Douglas J. E. Spencer, Anne M. Reynolds, Patrick L. Holland, Brian A. Jazdzewski, Carole Duboc-Toia, Laurent Le Pape, Seiji Yokota, Yoshimitsu Tachi, Shinobu Itoh, and William B. Tolman pp 6307 - 6321; DOI: 10.1021/ic020369k |
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4-Hydroxypyridine-2,6-dicarboxylatodioxovanadate(V) Complexes: Solid State and Aqueous Chemistry Luqin Yang, Agnete la Cour, Oren P. Anderson, and Debbie C. Crans pp 6322 - 6331; DOI: 10.1021/ic0201598 |
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Assessment of Relative Stabilities of Positional Isomers of Polyhedral Heteronuclear Clusters via a Simplified Method of Bond Energy Calculations Based on Tight-Binding Approach and Adjacent Matrix Method: Applications to Binary Icosahedral Clusters Boon K. Teo and Alex Strizhev pp 6332 - 6342; DOI: 10.1021/ic020325b |
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Photoinduced and Chemical Oxidation of Coordinated Imine to Amide in Isomeric Osmium(II) Complexes of N-Arylpyridine-2-carboxaldimines. Synthesis, Characterization, Electron Transfer Properties, and Structural Studies Amit K. Ghosh, Kunal K. Kamar, Parimal Paul, Shie-Ming Peng, Gene-Hsiang Lee, and Sreebrata Goswami pp 6343 - 6350; DOI: 10.1021/ic020454s |
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Novel Hydrogen-Bonded Three-Dimensional Networks Encapsulating One-Dimensional Covalent Chains: [M(4,4'-bipy)(H2O)4](4-abs)2·nH2O (4,4'-bipy = 4,4'-Bipyridine; 4-abs = 4-Aminobenzenesulfonate) (M = Co, n = 1; M = Mn, n = 2) Yonghui Wang, Liyun Feng, Yangguang Li, Changwen Hu, Enbo Wang, Ninghai Hu, and Hengqing Jia pp 6351 - 6357; DOI: 10.1021/ic025915o |
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Mössbauer Study of Reduced Rubredoxin As Purified and in Whole Cells. Structural Correlation Analysis of Spin Hamiltonian Parameters Vladislav V. Vrajmasu, Emile L. Bominaar, Jacques Meyer, and Eckard Münck pp 6358 - 6371; DOI: 10.1021/ic020508y |
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Salt-Free Synthesis of Samarium-Aluminum Mixed-Metal Alkoxides: X-ray Crystal Structures of {[(i-Pr-O)(i-Bu)Al(-O-i-Pr)2Sm(O-i-Pr)(HO-i-Pr)](-O-i-Pr)}2, [(THF)2Sm(O-t-Bu)2(-O-t-Bu)2Al(i-Bu)2], Sm(OAr)3(THF)3 (Ar = 2,4,6-Me3C6H2), [Nd(-OAr)(OAr)2(py)2]2 (Ar = 2,4,6-Me3C6H2), and (ArO)3Sm[(-O-t-Bu)2Al2(O-t-Bu)4] (Ar = 2,6-i-Pr2C6H3) Garth R. Giesbrecht, John C. Gordon, David L. Clark, Brian L. Scott, John G. Watkin, and Kenneth J. Young pp 6372 - 6379; DOI: 10.1021/ic0203116 |
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Phosphine-Stabilized Arsenium Salts: Water-Stable, Labile, Coordination Complexes Keith A. Porter, Anthony C. Willis, Johann Zank, and S. Bruce Wild pp 6380 - 6386; DOI: 10.1021/ic020410j |
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A Superior Polypyridine Ligand for Platinum(II) Lumaphors. Methyl Substituents with a Large Stereoelectronic Influence Jeffrey J. Moore, John J. Nash, Phillip E. Fanwick, and David R. McMillin pp 6387 - 6396; DOI: 10.1021/ic025922c |
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Structures of the BrF4+ and IF4+ Cations Ashwani Vij, Fook S. Tham, Vandana Vij, William W. Wilson, and Karl O. Christe pp 6397 - 6403; DOI: 10.1021/ic025900q |
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Di-tert-butyl Phosphate as Synthon for Metal Phosphate Materials via Single-Source Coordination Polymers [M(dtbp)2]n (M = Mn, Cu) and [Cd(dtbp)2(H2O)]n (dtbp-H = (tBuO)2P(O)OH) Malaichamy Sathiyendiran and Ramaswamy Murugavel pp 6404 - 6411; DOI: 10.1021/ic0259787 |
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Sandwich-Type Phosphotungstates: Structure, Electrochemistry, and Magnetism of the Trinickel-Substituted Polyoxoanion [Ni3Na(H2O)2(PW9O34)2]11- Ulrich Kortz, Israel M. Mbomekalle, Bineta Keita, Louis Nadjo, and Patrick Berthet pp 6412 - 6416; DOI: 10.1021/ic0255353 |
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Bifunctional Single Amino Acid Chelates for Labeling of Biomolecules with the {Tc(CO)3}+ and {Re(CO)3}+ Cores. Crystal and Molecular Structures of [ReBr(CO)3(H2NCH2C5H4N)], [Re(CO)3{(C5H4NCH2)2NH}]Br, [Re(CO)3{(C5H4NCH2)2NCH2CO2H}]Br, [Re(CO)3{X(Y)NCH2CO2CH2CH3}]Br (X = Y = 2-pyridylmethyl; X = 2-pyridylmethyl, Y = 2-(1-methylimidazolyl)methyl; X = Y = 2-(1-methylimidazolyl)methyl), [ReBr(CO)3{(C5H4NCH2)NH(CH2C4H3S)}], and [Re(CO)3{(C5H4NCH2)N(CH2C4H3S)(CH2CO2)}] Sangeeta Ray Banerjee, Murali K. Levadala, Neva Lazarova, Lihui Wei, John F. Valliant, Karin A. Stephenson, John W. Babich, Kevin P. Maresca, and Jon Zubieta pp 6417 - 6425; DOI: 10.1021/ic020476e |
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Synthesis and Structural Characterization of Di- and Tetranuclear Zinc Complexes with Phenolate and Carboxylate Bridges. Correlations between 13C NMR Chemical Shifts and Carboxylate Binding Modes Bao-Hui Ye, Xiao-Yuan Li, Ian D. Williams, and Xiao-Ming Chen pp 6426 - 6431; DOI: 10.1021/ic025806+ |
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Aluminum Orthovanadate (AlVO4): Synthesis and Characterization by 27Al and 51V MAS and MQMAS NMR Spectroscopy Ulla Gro Nielsen, Astrid Boisen, Michael Brorson, Claus J. H. Jacobsen, Hans J. Jakobsen, and J rgen Skibstedpp 6432 - 6439; DOI: 10.1021/ic0204023 |
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Vinyl C-F Cleavage by Os(H)3Cl(PiPr3)2 German Ferrando-Miguel, Hélène Gérard, Odile Eisenstein, and Kenneth G. Caulton pp 6440 - 6449; DOI: 10.1021/ic020365f |
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Four- and Five-Coordinate Aluminum Ketiminate Complexes: Synthesis, Characterization, and Ring-Opening Polymerization Ru-Ching Yu, Chen-Hsiung Hung, Jui-Hsien Huang, Horng-Yi Lee, and Jwu-Ting Chen pp 6450 - 6455; DOI: 10.1021/ic025785j |
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Metal-Hydride Bond Activation and Metal-Metal Interaction in Dinuclear Iron Complexes with Linking Dinitriles: A Synthetic, Electrochemical, and Theoretical Study Ana I. F. Venâncio, Maxim L. Kuznetsov, M. Fátima C. Guedes da Silva, Luísa M. D. R. S. Martins, João J. R. Fraústo da Silva, and Armando J. L. Pombeiro pp 6456 - 6467; DOI: 10.1021/ic025835k |
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Strongly Isolated Ferromagnetic Layers in Poly-trans--dichloro- and Poly-trans--dibromobis(1-(2-chloroethyl)-tetrazole-N4)copper(II) Complexes Arno F. Stassen, Huub Kooijman, Anthony L. Spek, L. Jos de Jongh, Jaap G. Haasnoot, and Jan Reedijk pp 6468 - 6473; DOI: 10.1021/ic0257470 |
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Novel Rectangular [Fe4(4-OHO)(-OH)2]7+ versus "Butterfly" [Fe4(3-O)2]8+ Core Topology in the FeIII/RCO2-/phen Reaction Systems (R = Me, Ph; phen = 1,10-Phenanthroline): Preparation and Properties of [Fe4(OHO)(OH)2(O2CMe)4(phen)4](ClO4)3, [Fe4O2(O2CPh)7(phen)2](ClO4), and [Fe4O2(O2CPh)8(phen)2] Athanassios K. Boudalis, Nikolia Lalioti, Georgios A. Spyroulias, Catherine P. Raptopoulou, Aris Terzis, Azzedine Bousseksou, Vassilis Tangoulis, Jean-Pierre Tuchagues, and Spyros P. Perlepes pp 6474 - 6487; DOI: 10.1021/ic025795k |
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Structures of Anhydrous and Hydrated Copper(II) Hexafluoroacetylacetonate Andrew W. Maverick, Frank R. Fronczek, Emily F. Maverick, Damon R. Billodeaux, Zuzanna T. Cygan, and Ralph A. Isovitsch pp 6488 - 6492; DOI: 10.1021/ic020448w |
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Unexpected Formation of an Azetidine-Carborane Derivative by Dehydration of N-(1,12-Dicarba-closo-dodecaboran-1-yl)formamide. The First X-ray Structure of a 2,3-Bis(imino)azetidine Paul Schaffer, Pierre Morel, James F. Britten, and John F. Valliant pp 6493 - 6499; DOI: 10.1021/ic025828w |
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New Pathways for Chlorine Dioxide Decomposition in Basic Solution Ihab N. Odeh, Joseph S. Francisco, and Dale W. Margerum pp 6500 - 6506; DOI: 10.1021/ic0204676 |
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Synthesis, Structure, and Reactivity of Some N-Phosphorylphosphoranimines Jon J. Longlet, Satish G. Bodige, William H. Watson, and Robert H. Neilson pp 6507 - 6513; DOI: 10.1021/ic025823z |
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Structures of Novel R2Mo5O18 and R6Mo12O45 (R = Eu and Gd) Prepared by Thermal Decomposition of Polyoxomolybdate Precursor [R2(H2O)12Mo8O27]·nH2O Haruo Naruke and Toshihiro Yamase pp 6514 - 6520; DOI: 10.1021/ic025697z |
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Cyclometalated Ruthenium Chloro and Nitrosyl Complexes Hassan Hadadzadeh, Maria C. DeRosa, Glenn P. A. Yap, Ali R. Rezvani, and Robert J. Crutchley pp 6521 - 6526; DOI: 10.1021/ic020451f |
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Oxorhenium(V) Complexes with the Non-Sulfur-Containing Amino Acid Histidine Christian Tessier, Fernande D. Rochon, and André L. Beauchamp pp 6527 - 6536; DOI: 10.1021/ic025809m |
Issue 25
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The Methanol-Methanolate CH3OH···OCH3- Bridging Ligand: Tuning of Exchange Coupling by Hydrogen Bonds in Dimethoxo-Bridged Dichromium(III) Complexes Tapan Kanti Paine, Thomas Weyhermüller, Karl Wieghardt, and Phalguni Chaudhuri pp 6538 - 6540; DOI: 10.1021/ic0204068 |
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Synthesis of the (Dialkylamino)borate, [Ph2B(CH2NMe2)2]-, Affords Access to N-Chelated Rhodium(I) Zwitterions Theodore A. Betley and Jonas C. Peters pp 6541 - 6543; DOI: 10.1021/ic0259336 |
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Hydrothermal Preparation of Novel Cd(II) Coordination Polymers Employing 5-(4-Pyridyl)tetrazolate as a Bridging Ligand Xiang Xue, Xi-Sen Wang, Li-Zhong Wang, Ren-Gen Xiong, Brendan F. Abrahams, Xiao-Zeng You, Zi-Ling Xue, and Chi-Ming Che pp 6544 - 6546; DOI: 10.1021/ic0257118 |
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Synthesis and Crystal Structure of Sr2AlH7: A New Structural Type of Alkaline Earth Aluminum Hydride Qing-An Zhang, Yumiko Nakamura, Ken-ich Oikawa, Takashi Kamiyama, and Etsuo Akiba pp 6547 - 6549; DOI: 10.1021/ic020450n |
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Synthesis, Characterization, and Reactivity of Cationic Hydride [HPd(diphosphine)2]+CF3SO3-, the Missing Member of the Family [HM(dppe)2]+X- (M = Ni, Pd, Pt). DFT QM/MM Structural Predictions for the [HPd(dppe)2]+ Moiety Michele Aresta, Angela Dibenedetto, Eliana Amodio, Imre Pápai, and Gábor Schubert pp 6550 - 6552; DOI: 10.1021/ic020631p |
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Pd(0) and Pt(0) Metallocryptands Encapsulating a Spinning Mercurous Dimer Vincent J. Catalano, Mark A. Malwitz, and Bruce C. Noll pp 6553 - 6559; DOI: 10.1021/ic020439n |
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NMR Shielding Calculations across the Periodic Table: Diamagnetic Uranium Compounds. 2. Ligand and Metal NMR Georg Schreckenbach pp 6560 - 6572; DOI: 10.1021/ic020370j |
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Bimetallic Carbonyl Thiolates as Functional Models for Fe-Only Hydrogenases Frédéric Gloaguen, Joshua D. Lawrence, Thomas B. Rauchfuss, Marc Bénard, and Marie-Madeleine Rohmer pp 6573 - 6582; DOI: 10.1021/ic025838x |
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Distal Metal Effects in Cobalt Porphyrins Related to CcO James P. Collman, Katja E. Berg, Christopher J. Sunderland, Ally Aukauloo, Michael A. Vance, and Edward I. Solomon pp 6583 - 6596; DOI: 10.1021/ic020395i |
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Synthesis, Structure, and Second-Order Nonlinear Optical Properties of Copper(II) and Palladium(II) Acentric Complexes with N-Salicylidene-N '-aroylhydrazine Tridentate Ligands F. Cariati, U. Caruso, R. Centore, W. Marcolli, A. De Maria, B. Panunzi, A. Roviello, and A. Tuzi pp 6597 - 6603; DOI: 10.1021/ic020127k |
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Room-Temperature Synthesis and Crystal, Magnetic, and Electronic Structure of the First Silver Copper Oxide Eva M. Tejada-Rosales, Juan Rodríguez-Carvajal, Nieves Casañ-Pastor, Pere Alemany, Eliseo Ruiz, M. Salah El-Fallah, Santiago Alvarez, and Pedro Gómez-Romero pp 6604 - 6613; DOI: 10.1021/ic025872b |
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A Density Functional Study of SN2 Substitution at Square-Planar Platinum(II) Complexes Jason Cooper and Tom Ziegler pp 6614 - 6622; DOI: 10.1021/ic020294k |
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Fluorometric Chemosensors. Interaction of Toxic Heavy Metal Ions PbII, CdII, and HgII with Novel Mixed-Donor Phenanthroline-Containing Macrocycles: Spectrofluorometric, Conductometric, and Crystallographic Studies M. Carla Aragoni, Massimiliano Arca, Francesco Demartin, Francesco A. Devillanova, Francesco Isaia, Alessandra Garau, Vito Lippolis, Fahimeh Jalali, Ulrich Papke, Mojtaba Shamsipur, Lorenzo Tei, Abdollah Yari, and Gaetano Verani pp 6623 - 6632; DOI: 10.1021/ic020270d |
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Variable Coordination Modes of NO2- in a Series of Ag(I) Complexes Containing Triorganophosphines, -arsines, and -stibines. Syntheses, Spectroscopic Characterization (IR, 1H and 31P NMR, Electrospray Ionization Mass), and Structures of [AgNO2(R3E)x] Adducts (E = P, As, Sb, x = 1-3) Augusto Cingolani, Effendy, Maura Pellei, Claudio Pettinari, Carlo Santini, Brian W. Skelton, and Allan H. White pp 6633 - 6645; DOI: 10.1021/ic020375g |
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Molecular Structures of Two Metal Tetrakis(tetrahydroborates), Zr(BH4)4 and U(BH4)4: Equilibrium Conformations and Barriers to Internal Rotation of the Triply Bridging BH4 Groups Arne Haaland, Dmitry J. Shorokhov, Andrey V. Tutukin, Hans Vidar Volden, Ole Swang, G. Sean McGrady, Nikolas Kaltsoyannis, Anthony J. Downs, Christina Y. Tang, and John F. C. Turner pp 6646 - 6655; DOI: 10.1021/ic020357z |
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Does Back-Bonding Involve Bonding Orbitals in Boryl Complexes? A Theoretical DFT Study Géraldine Sivignon, Paul Fleurat-Lessard, Jean-Marie Onno, and François Volatron pp 6656 - 6661; DOI: 10.1021/ic020066q |
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Paramagnetic 1H NMR Spectrum of Nickel(II) Pseudoazurin: Investigation of the Active Site Structure and the Acid and Alkaline Transitions Christopher Dennison and Katsuko Sato pp 6662 - 6672; DOI: 10.1021/ic020303p |
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Influence of Electronic and Structural Effects on the Oxidative Behavior of Nickel Porphyrins Karl M. Kadish, Min Lin, Eric Van Caemelbecke, Guido De Stefano, Craig J. Medforth, Daniel J. Nurco, Nora Y. Nelson, Bénédicte Krattinger, Cinzia M. Muzzi, Laurent Jaquinod, Yang Xu, David C. Shyr, Kevin M. Smith, and John A. Shelnutt pp 6673 - 6687; DOI: 10.1021/ic0200702 |
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Synthesis and Photochemistry of Ru(II) Complexes Containing Phenanthroline-Based Ligands with Fused Pyrrole Rings John M. Villegas, Stanislav R. Stoyanov, and D. P. Rillema pp 6688 - 6694; DOI: 10.1021/ic020436a |
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A Density Functional Study of Oxygen Atom Transfer Reactions between Biological Oxygen Atom Donors and Molybdenum(IV) Bis(dithiolene) Complexes Anders Thapper, Robert J. Deeth, and Ebbe Nordlander pp 6695 - 6702; DOI: 10.1021/ic020385h |
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Synthesis, Crystal Structures, and Redox Potentials of 2,3,12,13-Tetrasubstituted 5,10,15,20-Tetraphenylporphyrin Zinc(II) Complexes Yuichi Terazono, Brian O. Patrick, and David H. Dolphin pp 6703 - 6710; DOI: 10.1021/ic020339h |
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Interplay of Light Antenna and Excitation "Energy Reservoir" Effects in a Bichromophoric System Based on Ruthenium-Polypyridine and Pyrene Units Linked by a Long and Flexible Poly(ethylene glycol) Chain Angeles Farrán Morales, Gianluca Accorsi, Nicola Armaroli, Francesco Barigelletti, Simon J. A. Pope, and Michael D. Ward pp 6711 - 6719; DOI: 10.1021/ic025811d |
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Deprotonation-Substitution Reactions of Cyclic Methylphenylphosphazenes: Synthesis and Structures of Nongeminal P-Ethyl, P-Phenyl Cyclotriphosphazenes June-Ho Jung, Hongming Zhang, and Patty Wisian-Neilson pp 6720 - 6725; DOI: 10.1021/ic0259080 |
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Synthesis and Structures of One- and Two-Electron Oxidized Forms of Bis(acetylene)tetrairon Clusters Cp'4Fe4(HCCH)2 (Cp' = Cp, 5-C5H4Me) Masaaki Okazaki, Takeo Ohtani, Masato Takano, and Hiroshi Ogino pp 6726 - 6730; DOI: 10.1021/ic025763x |
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Hexadentate Hydroxypyridonate Iron Chelators Based on TREN-Me-3,2-HOPO: Variation of Cap Size1 Jide Xu, Brendon O'Sullivan, and Kenneth N. Raymond pp 6731 - 6742; DOI: 10.1021/ic025610+ |
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Heterobimetallic Coordination Polymers Incorporating [M(CN)2]- (M = Cu, Ag) and [Ag2(CN)3]- Units: Increasing Structural Dimensionality via M-M' and M···NC Interactions Carolyn J. Shorrock, Bao-Yu Xue, Peter B. Kim, Raymond J. Batchelor, Brian O. Patrick, and Daniel B. Leznoff pp 6743 - 6753; DOI: 10.1021/ic025850p |
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Oxidation of Organic Sulfides by Vanadium Haloperoxidase Model Complexes Thomas S. Smith, II and Vincent L. Pecoraro pp 6754 - 6760; DOI: 10.1021/ic025650d |
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Facile Pyrazolylborate Ligand Degradation at Lanthanide Centers: X-ray Crystal Structures of Pyrazolylborinate-Bridged Bimetallics Ângela Domingos, Mark R. J. Elsegood, Anna C. Hillier, Guanyang Lin, Sung Ying Liu, Irene Lopes, Noémia Marques, Graham H. Maunder, Robert McDonald, Andrea Sella, Jonathan W. Steed, and Josef Takats pp 6761 - 6768; DOI: 10.1021/ic025801c |
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Dinuclear Oxidative Addition of N-H and S-H Bonds at Chromium. Reaction of Cr(CO)3(C5Me5) with {o-(HA)C6H4S-Cr(CO)3(C5Me5)} (A = S, NH) Yielding [2-o-(-A)C6H4S-Cr(C5Me5)]2 and H-Cr(CO)3(C5Me5) Kengkaj Sukcharoenphon, Telvin D. Ju, Khalil A. Abboud, and Carl D. Hoff pp 6769 - 6774; DOI: 10.1021/ic0204934 |
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Aqueous Reactions of U(VI) at High Chloride Concentrations: Syntheses and Structures of New Uranyl Chloride Polymers Amanda C. Bean, Youwen Xu, Janet A. Danis, Thomas E. Albrecht-Schmitt, Brian L. Scott, and Wolfgang Runde pp 6775 - 6779; DOI: 10.1021/ic020177p |
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New Oxamidato-Bridged CuII-NiII Complexes: Supramolecular Structures with Thiocyanate Ligands and Hydrogen Bonds. Magnetostructural Studies: DFT Calculations Javier Tercero, Carmen Diaz, Joan Ribas, Eliseo Ruiz, José Mahía, and Miguel Maestro pp 6780 - 6789; DOI: 10.1021/ic025910r |
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Chemistry of a Binuclear Cadmium(II) Hydroxide Complex: Formation from Water, CO2 Reactivity, and Comparison to a Zinc Analog Russell A. Allred, Lenore H. McAlexander, Atta M. Arif, and Lisa M. Berreau pp 6790 - 6801; DOI: 10.1021/ic0258072 |
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Synthesis and Structural Characterization of Nonanuclear Lanthanide Complexes Gang Xu, Zhe-Ming Wang, Zheng He, Zhi Lü, Chun-Sheng Liao, and Chun-Hua Yan pp 6802 - 6807; DOI: 10.1021/ic025929u |
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Synthesis and X-ray Structures of Dilithium Complexes of the Phosphonate Anions [PhP(E)(NtBu)2]2- (E = O, S, Se, Te) and Dimethylaluminum Derivatives of [PhP(E)(NtBu)(NHtBu)]- (E = S, Se) Glen G. Briand, Tristram Chivers, Mark Krahn, and Masood Parvez pp 6808 - 6815; DOI: 10.1021/ic020471h |
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The Rhodafluor Family. An Initial Study of Potential Ratiometric Fluorescent Sensors for Zn2+ Shawn C. Burdette and Stephen J. Lippard pp 6816 - 6823; DOI: 10.1021/ic026048q |
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Cyclic Tetramers Composed of Rhodium(III), Iridium(III), or Ruthenium(II) Half-Sandwich and 6-Purinethiones Kazuaki Yamanari, Rie Ito, Shiori Yamamoto, Takumi Konno, Akira Fuyuhiro, Kousuke Fujioka, and Ryuichi Arakawa pp 6824 - 6830; DOI: 10.1021/ic020449o |
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Moderating Influence of Proteins on Nonplanar Tetrapyrrole Deformations: Coenzyme F430 in Methyl-Coenzyme-M Reductase Lindsay N. Todd and Marc Zimmer pp 6831 - 6837; DOI: 10.1021/ic025950v |
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Synthetic, Structural, Electrochemical, and Theoretical Studies of Heterometallic Aggregates with a [Pt2(-S)2M] Core (M = Hg, Au) Xingling Xu, S.-W. Audi Fong, Zhaohui Li, Zhi-Heng Loh, Feng Zhao, Jagadese J. Vittal, William Henderson, Soo-Beng Khoo, and T. S. Andy Hor pp 6838 - 6845; DOI: 10.1021/ic011181o |
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Polymethylated DOTA Ligands. 1. Synthesis of Rigidified Ligands and Studies on the Effects of Alkyl Substitution on Acid-Base Properties and Conformational Mobility Ramachandran S. Ranganathan, Radhakrishna K. Pillai, Natarajan Raju, Helen Fan, Hanh Nguyen, Michael F. Tweedle, Jean F. Desreux, and Vincent Jacques pp 6846 - 6855; DOI: 10.1021/ic025657v |
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Polymethylated DOTA Ligands. 2. Synthesis of Rigidified Lanthanide Chelates and Studies on the Effect of Alkyl Substitution on Conformational Mobility and Relaxivity Ramachandran S. Ranganathan, Natarajan Raju, Helen Fan, Xun Zhang, Michael F. Tweedle, Jean F. Desreux, and Vincent Jacques pp 6856 - 6866; DOI: 10.1021/ic025695e |
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[n.1.1]-(2,6)-Pyridinophanes: A New Ligand Type Imposing Unusual Metal Coordination Geometries Andrei N. Vedernikov, John C. Huffman, and Kenneth G. Caulton pp 6867 - 6874; DOI: 10.1021/ic020430l |
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Copper(I) Halide Complexes with 1,3-Propanebis(diphenylphosphine) and Heterocyclic Thione Ligands: Crystal and Electronic Structures (DFT) of [CuCl(pymtH)(dppp)], [CuBr(pymtH)(dppp)], and [Cu(-I)(dppp)]2 Paraskevas Aslanidis, Philip J. Cox, Savvas Divanidis, and Athanassios C. Tsipis pp 6875 - 6886; DOI: 10.1021/ic025896i |
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From One-dimensional Chain to Pentanuclear Molecule. Magnetism of Cyano-Bridged Fe(III)-Ni(II) Complexes Hui-Zhong Kou, Bei Chuan Zhou, Dai-Zheng Liao, Ru-Ji Wang, and Yadong Li pp 6887 - 6891; DOI: 10.1021/ic025927+ |
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Synthesis and Properties of Stereoregular Cyclic Polysilanols: cis-[PhSi(O)OH]4, cis-[PhSi(O)OH]6, and Tris-cis-tris-trans-[PhSi(O)OH]12 Olga I. Shchegolikhina, Yulia A. Pozdnyakova, Yulia A. Molodtsova, Sergey D. Korkin, Sergey S. Bukalov, Larissa A. Leites, Konstantin A. Lyssenko, Alexandr S. Peregudov, Norbert Auner, and Dimitris E. Katsoulis pp 6892 - 6904; DOI: 10.1021/ic020546h |
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Thermal Evolution of Carbonate Pillared Layered Hydroxides with (Ni, L) (L = Fe, Co) Based Slabs: Grafting or Nongrafting of Carbonate Anions? C. Vaysse, L. Guerlou-Demourgues, and C. Delmas pp 6905 - 6913; DOI: 10.1021/ic025542r |
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Adamantane-like Aluminum Amide-Phosphate from Alumazene Jiri Pinkas, Jiri Löbl, Dalibor Dastych, Marek Necas, and Herbert W. Roesky pp 6914 - 6918; DOI: 10.1021/ic0257625 |
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Inorganic Heterocyclic Bis(phosphines): Syntheses and Structures of a 1,2-Bis(diazasilaphosphetidino)ethane and Its Nickel, Molybdenum, and Rhodium Complexes Ingo Schranz, Graham R. Lief, Steven J. Midstokke, and Lothar Stahl pp 6919 - 6927; DOI: 10.1021/ic020524v |
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Theoretical Study of the Fe(phen)2(NCS)2 Spin-Crossover Complex with Reparametrized Density Functionals Markus Reiher pp 6928 - 6935; DOI: 10.1021/ic025891l |
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Protonation and Zn(II) Coordination by Dipyridine-Containing Macrocycles with Different Molecular Architecture. A Case of pH-Controlled Metal Jumping Outside-Inside the Macrocyclic Cavity Carlos Lodeiro, A. Jorge Parola, Fernando Pina, CarlaBazzicalupi, Andrea Bencini, Antonio Bianchi, Claudia Giorgi, Andrea Masotti, and Barbara Valtancoli pp 6936 - 6936; DOI: 10.1021/ic020662k |
Issue 26
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Lead as Its Own Luminescent Sensor Subodh K. Dutta and Marc W. Perkovic pp 6938 - 6940; DOI: 10.1021/ic0260724 |
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New Alkaline Earth Aluminum Hydride with One-Dimensional Zigzag Chains of [AlH6]: Synthesis and Crystal Structure of BaAlH5 Qing-An Zhang, Yumiko Nakamura, Ken-ich Oikawa, Takashi Kamiyama, and Etsuo Akiba pp 6941 - 6943; DOI: 10.1021/ic020388u |
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Influence of Nonplanarity and Extended Conjugation on Porphyrin Basicity Olga S. Finikova, Andrei V. Cheprakov, Patrick J. Carroll, Sergio Dalosto, and Sergei A. Vinogradov pp 6944 - 6946; DOI: 10.1021/ic0260522 |
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Highly Bulky and Electron-Rich Terminal Ruthenium Phosphido Complexes: New Donor Ligands for Palladium-Catalyzed Suzuki Cross-Couplings José Giner Planas and J. A. Gladysz pp 6947 - 6949; DOI: 10.1021/ic020589y |
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Stability and Structure in - and -Keggin Heteropolytungstates, [Xn+W12O40](8-n)-, X = p-Block Cation Wade A. Neiwert, Jennifer J. Cowan, Kenneth I. Hardcastle, Craig L. Hill, and Ira A. Weinstock pp 6950 - 6952; DOI: 10.1021/ic026023r |
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Identification of a Near-Linear Supramolecular Water Dimer, (H2O)2, in the Channel of an Inorganic Framework Material Sathi Manikumari, Vaddypally Shivaiah, and Samar K. Das pp 6953 - 6955; DOI: 10.1021/ic025803x |
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Intramolecular "Aryl-Metal Chelate Ring" ,-Interactions as Structural Evidence for Metalloaromaticity in (Aromatic ,'-Diimine)-Copper(II) Chelates: Molecular and Crystal Structure of Aqua(1,10-phenanthroline)(2-benzylmalonato)copper(II) Three-hydrate A. Castiñeiras, A. G. Sicilia-Zafra, J. M. González-Pérez, D. Choquesillo-Lazarte, and J. Niclós-Gutiérrez pp 6956 - 6958; DOI: 10.1021/ic026004h |
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Forty-Five Years of Chemical Discovery Including a Golden Quarter-Century John P. Fackler, Jr. pp 6959 - 6972; DOI: 10.1021/ic025734m |
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Electronic Spectra and Structures of d2 Molybdenum-Oxo Complexes. Effects of Structural Distortions on Orbital Energies, Two-Electron Terms, and the Mixing of Singlet and Triplet States Ryan E. Da Re and Michael D. Hopkins pp 6973 - 6985; DOI: 10.1021/ic020565r |
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Intra- and Intermolecular Second-Sphere Coordination Chemistry: Formation of Capsules, Half-Capsules, and Extended Structures with Hexaaquo- and Hexaamminemetal Ions Sean A. Dalrymple, Masood Parvez, and George K. H. Shimizu pp 6986 - 6996; DOI: 10.1021/ic025627s |
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Mass Effect on the Equienergetic High-Spin/Low-Spin States of Spin-Crossover in 4,4'-Bipyridine-Bridged Iron(II) Polymeric Compounds: Synthesis, Structure, and Magnetic, Mössbauer, and Theoretical Studies Nicolás Moliner, M. Carmen Muñoz, Sylvie Létard, Lionel Salmon, Jean-Pierre Tuchagues, Azzedine Bousseksou, and José Antonio Real pp 6997 - 7005; DOI: 10.1021/ic0203825 |
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Synthesis and X-ray Crystal Structure Determination of the First Copper(II) Complexes of Tetraazamacrocycle-Glyoxal Condensates Timothy J. Hubin, Nathaniel W. Alcock, Lawrence L. Seib, and Daryle H. Busch pp 7006 - 7014; DOI: 10.1021/ic020386+ |
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Reactivity Investigation of Dinuclear Vanadium(IV,V)-Citrate Complexes in Aqueous Solutions. A Closer Look into Aqueous Vanadium-Citrate Interconversions M. Kaliva, E. Kyriakakis, and A. Salifoglou pp 7015 - 7023; DOI: 10.1021/ic020323r |
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Polytypism in Columnar Group 14 Halide Salts: Structures of (Et2NH2)3Pb3X9·nH2O (X = Cl, Br) and (-alaninium)2SnI4 Roger D. Willett, Karen R. Maxcy, and Brendan Twamley pp 7024 - 7030; DOI: 10.1021/ic020455k |
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Use of Electrospray Mass Spectrometry (ESI-MS) for the Study of Europium(III) Complexation with Bis(dialkyltriazinyl)pyridines and Its Implications in the Design of New Extracting Agents Sonia Colette, Badia Amekraz, Charles Madic, Laurence Berthon, Gérard Cote, and Christophe Moulin pp 7031 - 7041; DOI: 10.1021/ic025637t |
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Kinetics and Mechanism of Chromate Reduction with Hydrogen Peroxide in Base Douglas A. Vander Griend, Joshua S. Golden, and Charles A. Arrington, Jr. pp 7042 - 7048; DOI: 10.1021/ic0257975 |
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Gas Phase Structure of O-Nitrobis(trifluoromethyl)hydroxylamine, (CF3)2NONO2: An Extremely Long O-N Bond Frank Trautner, Ralf Kirsch, Rolf Minkwitz, and Heinz Oberhammer pp 7049 - 7052; DOI: 10.1021/ic020415g |
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Interplay of Terminal Amino Group and Coordinating Side Chains in Directing Regioselective Cleavage of Natural Peptides and Proteins with Palladium(II) Complexes Neboj a M. Milovi and Nenad M. Kostipp 7053 - 7063; DOI: 10.1021/ic025640c |
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Structure and Dynamics of ND3BF3 in the Solid and Gas Phases: A Combined NMR, Neutron Diffraction, and Ab Initio Study Glenn H. Penner, Bruno Ruscitti, Julie Reynolds, and Ian Swainson pp 7064 - 7071; DOI: 10.1021/ic0203771 |
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Cage Compounds of Heterotrimetallic Mixed Phosphanediide/Silanolate Aggregates with an Alkaline Earth Metal-Centered Phosphorus Octahedron Matthias Westerhausen, Sabine Weinrich, Gernot Kramer, and Holger Piotrowski pp 7072 - 7076; DOI: 10.1021/ic0202413 |
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Stereoselectivity of the Secondary Isotope Effect in the Aquation of [Co(NH3)5Cl]2+ W. G. Jackson pp 7077 - 7080; DOI: 10.1021/ic020253o |
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Determination of Antiferromagnetic Exchange Coupling in the Tetrahedral Thiolate-Bridged Diferrous Complex [Fe2(SEt)6]2- Yiannis Sanakis, Sun Jae Yoo, Frank Osterloh, R. H. Holm, and Eckard Münck pp 7081 - 7085; DOI: 10.1021/ic0204629 |
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New Oxovanadium Bis(1,2-dithiolate) Compounds That Mimic the Hydrogen-Bonding Interactions at the Active Sites of Mononuclear Molybdenum Enzymes J. Jon A. Cooney, Michael D. Carducci, Anne E. McElhaney, Hugh D. Selby, and John H. Enemark pp 7086 - 7093; DOI: 10.1021/ic025856e |
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New Quaternary Bismuth Sulfides: Syntheses, Structures, and Band Structures of AMBiS4 (A = Rb, Cs; M = Si, Ge) Jiyong Yao, Bin Deng, Donald E. Ellis, and James A. Ibers pp 7094 - 7099; DOI: 10.1021/ic020429m |
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A New Two-Dimensional Molybdenum(V) Nickel Phosphate Built Up of [H18(Mo16O32)Ni16(PO4)26(OH)6(H2O)8]18- Wheels Charlotte du Peloux, Anne Dolbecq, Pierre Mialane, Jérôme Marrot, Eric Rivière, and Francis Sécheresse pp 7100 - 7104; DOI: 10.1021/ic0204880 |
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Silyl, Hydrido-Silylene, or Other Bonding Modes: Some Unusual Structures of [(dhpe)Pt(SiHR2)]+ (dhpe = H2P-CH2-CH2-PH2; R = H, Me, SiH3, Cl, OMe, NMe2) and [(dhpe)Pt(SiR3)]+ (R = Me, Cl) from DFT Calculations Maria Besora, Feliu Maseras, Agustí Lledós, and Odile Eisenstein pp 7105 - 7112; DOI: 10.1021/ic025911j |
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Synthesis, Structure, and Reactivity of Some Sterically Hindered (Silylamino)phosphines Remy C. Samuel, Ram P. Kashyap, Mariusz Krawiec, William H. Watson, and Robert H. Neilson pp 7113 - 7124; DOI: 10.1021/ic025951n |
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Metal-Promoted Aromatic Ring Amination and Deamination Reactions at a Diazo Ligand Coordinated to Rhodium and Ruthenium Chayan Das, Amit K. Ghosh, Chen-Hsiung Hung, Gene-Hsiang Lee, Shie-Ming Peng, and Sreebrata Goswami pp 7125 - 7135; DOI: 10.1021/ic020421c |
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Methyloxorhenium(V) Complexes with Two Bidentate Ligands: Syntheses and Reactivity Studies Xiaopeng Shan, Arkady Ellern, and James H. Espenson pp 7136 - 7142; DOI: 10.1021/ic025952f |
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Photoluminescence Switching of Azobenzene-Conjugated Pt(II) Terpyridine Complexes by Trans-Cis Photoisomerization Tomona Yutaka, Ichiro Mori, Masato Kurihara, Jun Mizutani, Naoto Tamai, Tsuyoshi Kawai, Masahiro Irie, and Hiroshi Nishihara pp 7143 - 7150; DOI: 10.1021/ic0260116 |
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Copper(II) Coordination to Ligands Immobilized on Photoluminescent Porous Silicon Corey M. Ottenberg, F. Crisp McDonald, Jr., Evan T. O'Donnell, Jr., Stephen A. Skrabal, and David P. White pp 7151 - 7158; DOI: 10.1021/ic025876g |
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Thermally Inert Metal Ammines as Light-Inducible DNA-Targeted Agents. Synthesis, Photochemistry, and Photobiology of a Prototypical Rhodium(III)-Intercalator Conjugate Colin G. Barry, Elizabeth C. Turney, Cynthia S. Day, Gilda Saluta, Gregory L. Kucera, and Ulrich Bierbach pp 7159 - 7169; DOI: 10.1021/ic025744n |
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Lead(II) Complexes with Macrocyclic Receptors Derived from 4,13-Diaza-18-crown-6 David Esteban, Fernando Avecilla, Carlos Platas-Iglesias, Jose Mahía, Andrés de Blas, and Teresa Rodríguez-Blas pp 7170 - 7170; DOI: 10.1021/ic0206342 |
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Bond Dissociation Energies and Structures of CuNO and Cu(NO)2 Konrad Koszinowski, Detlef Schröder, Helmut Schwarz, Max C. Holthausen, Joachim Sauer, Hideya Koizumi, and P. B. Armentrout pp 7170 - 7170; DOI: 10.1021/ic020678a |